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Solar energy Harvesting via Intelligent Nanosuspension Electroactive electrolytes

Project description

Photorechargeable solar flow batteries

The rapid growth in global energy demand, combined with the need to decarbonise energy systems, makes it necessary to develop efficient, scalable and sustainable technologies for storing renewable solar energy. Supported by the Marie Skłodowska-Curie Actions programme, the SHINE project will develop a new generation of intrinsic photorechargeable solar redox flow batteries in which specially engineered redox-active polymer electrolyte nanosuspensions, sensitised with rare-earth ions, directly harvest sunlight and store it as chemical energy without the need for external photoelectrodes. By combining advanced synthesis, in situ spectroelectrochemical analysis and prototype validation, the project aims to overcome current limitations in stability, charging speed and scalability while delivering a more efficient, low-cost and durable solar energy storage technology to support large-scale renewable energy integration.

Objective

The dual challenges of achieving net-zero emissions and satisfying surging global energy demands highlight the urgent need for advanced renewable energy storage solutions. Solar redox flow batteries (SRFBs) represent smart solutions for simultaneously harvesting and storing solar energy. Nonetheless, their reliance on external semiconducting electrodes for light-induced charge generation hinders their performance due to electrode instability, slow photocharging kinetics, and restricted scalability. To fully unlock the potential of these technologies, SHINE will introduce intrinsic photorechargeable systems in which the redox-active electrolytes themselves act as light-harvesting media, capable of converting sunlight into stored chemical energy without the need for external photoelectrodes. Our approach centers on the synthesis and engineering of a novel class of quantum-dot-sized conducting polymer nanosuspensions electrolytes sensitized with rare-earth (RE³⁺) ions, via acid-assisted polymerization. These photoactive electrolytes will leverage the unique optical properties of RE³⁺ ions to efficiently capture sunlight and directly transfer the harvested energy to the redox-active polymer nanoparticles. Through an interdisciplinary methodology combining advanced chemical synthesis, in-situ spectroelectrochemical characterization, and prototype testing, this research will simultaneously: 1) Guarantee the efficient integration of eco-friendly, low-cost, polymer electrolytes in SRFB technologies. 2) Understand the fundaments of the obtained photo-induced energy transfers. 3) Deliver a scalable and cost-effective SRFB technology that outperforms current systems in energy density and cycle stability, enabling a more efficient, integrated, and sustainable strategy for large-scale solar energy storage that directly supports the EU's green energy transition.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

USTAV MAKROMOLEKULARNI CHEMIE AV CRVVI
Net EU contribution
€ 191 918,16
Address
HEYROVSKEHO NAM 1888 2
162 06 PRAHA 6
Czechia
Region
Praha Česko
Activity type
Research Organisations
Links
Total cost
No data

Partners (1)