Objective
An important requirement on homogenous-catalytically active species is the hemilability of a ligand. Concentrating on late transition metals this will be fulfilled by ligands containing hard Lewis bases. The objective of the following research project will be the synthesis of mono- as well as bimetallic platinum compounds with bidentate hybridligands possessing one hard and one soft Lewis base donor. The advantage of using such bidentate ligand systems is that it will be bound strongly to the metal even if the hard donor function is temporarily not coordinated. Therefore the coordination chemistry of hetero-fictionalized oxazolines will be studied. Their chemistry with late transition metals is a fast developing research topic, but the coordination at platinum centres in particular has - with some rare exceptions -not been examined till today. The whole project is composed of two related parts: The first part concentrates on coordinating fictionalized oxazoline ligands in mononuclear platinum(II) complexes. The synthesis of square-planare complexes with at least one silyl group at the platinum will be investigated and their properties in terms of insertion of alkenes/alkynes into the Pt-Si-bond will be studied. The second part aims at bimetallic iron-platinum complexes with the bidentate ligands bridging the two metal centres. Again at the platinum being a silyl group insertion reactions with regard to catalytic applications (silylation reactions) will be studied.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences inorganic chemistry transition metals
- natural sciences chemical sciences catalysis
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
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Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
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Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
67070 STRASBOURG
France
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.