Objective
In the present project the degree of linear polarization of fluorescence in molecular ions populated via the Auger decay of Raman regime resonantly excited inner-shells of the NO and CO molecules will be studied theoretically and experimentally for the first time. In the NO molecule we will focus on the Auger decay of the N*O and NO* resonances into the A state of the NO+ ion investigating the intensities and the degree of polarization of the individual NO+(A - X) fluorescence bands appears in the VUV range. In the CO molecule we will concentrate on the Auger decay of the C*O and CO* resonances into the A state of the CO+ ion analyzing the intensities and degree of polarization of the individual CO+(A - X) fluorescence bands appears in the visible fluorescence range. Experimental analysis of the degree of linear polarization of emitted fluorescence will be performed by means of the Photon-Induced Fluorescence Spectroscopy method utilizing synchrotron radiation. The configuration interaction approach based on the core and valence molecular orbitals obtained within the MO LCAO method and continuum molecular orbitals obtained within the Single Center technique will be applied in order to interpret the observed fluorescence spectra. It is expected, that angular distribution of the fluorescence emission can elucidate a strong interference between closely neighbouring vibronic (lifetime vibrational interference) and electronic (electronic state interference) states overlapping within their natural lifetime widths even in the cases with the condition of small interference (e.g. in the inner-shell N*O and C*O excitations), were the interference effects were not observed previously by measuring the Resonant Auger spectra.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
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Keywords
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
FP7-PEOPLE-2007-4-2-IIF
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Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
34125 Kassel
Germany
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.