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Unveiling transient material synthesis in dilute solutions and their solid morphology combining dDNP and MAS-DNP.

Objective

The silicate speciation process is of large scientific and industrial interest because determines the morphology and reactivity of the silica products and biological control of the silica morphology has generated an interest for novel mechanisms for biomimetic silica synthesis. These processes occur typically in very dilute solutions (in the mM range) and no general approach is currently used to report on both the liquid-state speciation and the solid-state atomic-level morphological characterization during the speciation process. As a result, an important gap in the current understanding needs to be addressed.
Here we propose to combine cutting edge dynamic nuclear polarization (DNP) in its two main branches, dissolution DNP and MAS-DNP, to investigate the silicon-based materials formation process. The project is original and of high impact and can currently be performed only at the host institution. Dissolution-DNP and MAS-DNP experiments will be used to elucidate the speciation in dilute solutions and the structural morphology at different stages during the oligomeric formation process of silicon-based materials. In this way, a complete information can be obtained. The immediate result can be envisaged either in an important expansion of the host group research activities into dissolution DNP, and the applicant acquisition of important and strategic skills in chemistry, spin physics, DNP and solid-state NMR. The medium-term goal during the course of this action is to apply the techniques to a broader range of silicon-based materials, and the applicant acquisition and implementation of new organizational and managerial skills.

Keywords

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Programme(s)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2017

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Coordinator

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 187 419,60
Address
BATIMENT CE 3316 STATION 1
1015 LAUSANNE
Switzerland

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Region
Schweiz/Suisse/Svizzera Région lémanique Vaud
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 187 419,60
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