Recycling Environmentally Persistent Fluorocarbons with Metathesis and Shuttle Catalysis

Project Information

FluoroCycle

Grant agreement ID: 101001071

DOI

10.3030/101001071

EC signature date 20 January 2021

Start date 1 October 2021

End date 30 September 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 000 000,00

EU contribution

€ 2 000 000,00

Coordinated by

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
United Kingdom

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (8)

Dyotropic Rearrangement of an Iron–Aluminium Complex

Author(s): Benedek Stadler, Nikolaus Gorgas, Stuart J. Elliott, Mark R. Crimmin
Published in: Angewandte Chemie, Issue 136, 2024, ISSN 0044-8249
Publisher: Wiley-VCH
DOI: 10.1002/ange.202408257

Au(I) Catalyzed HF Transfer: Tandem Alkyne Hydrofluorination and Perfluoroarene Functionalization.

Author(s): Daniel Mulryan; Jack Rodwell; Nicholas A. Phillips; Mark R. Crimmin
Published in: ACS Catalysis, Issue 12, 2022, Page(s) 3411-3419, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c05474

A Continuous Flow Process for the Defluorosilylation of HFC-23 and HFO-1234yf

Author(s): Sarah L. Patrick, James A. Bull, Philip W. Miller, Mark R. Crimmin
Published in: Organic Letters, Issue 26, 2024, Page(s) 8605-8609, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.4c03274

Vinylic C–H Activation of Styrenes by an Iron–Aluminum Complex

Author(s): Nikolaus Gorgas; Benedek Stadler; Andrew J. P. White; Mark R. Crimmin
Published in: J. Am. Chem. Soc., Issue 2, 2024, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c14281

Catalytic HF Shuttling between Fluoroalkanes and Alkynes

Author(s): Shannon E. S. Farley, Daniel Mulryan, Feriel Rekhroukh, Andreas Phanopoulos, Mark Crimmin
Published in: Angew. Chem. Int. Ed., 2024, ISSN 1521-3773
Publisher: Wiley-VCH
DOI: 10.1002/anie.202317550

Defluorination of HFCs by a magnesium reagent

Author(s): Daniel J. Sheldon; Joseph M. Parr; Mark R. Crimmin
Published in: Dalton Trans., Issue 1, 2024, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4dt00636d

Double Deprotonation of CH3CN by an Iron-Aluminium Complex

Author(s): Benedek Stadler, Nikolaus Gorgas, Andrew White, Mark Crimmin
Published in: Angew. Chem. Int. Ed., 2023, ISSN 1521-3773
Publisher: Wiley-VCH
DOI: 10.1002/anie.202219212

Room Temperature Defluorination of Poly(tetrafluoro)ethylene by a Magnesium Reagent

Author(s): Daniel Sheldon; Joseph Parr; Mark Crimmin
Published in: J. Am. Chem. Soc., Issue 145, 2023, Page(s) 10486-10490, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c02526

Non-peer reviewed articles (2)

Boron, Aluminium, and Gallium Fluorides as Catalysts for the Defluorofunctionalisation of Electron-Deficient Arenes: The Role of NaBArF4 Promoters

Author(s): Wenbang Yang, Andrew White, Mark Crimmin
Published in: chemRxiv, 2024, ISSN 2573-2293
Publisher: chemRxiv
DOI: 10.26434/chemrxiv-2024-dqlqf

Fluoroalkenes from the Defluoroalkylation of Trifluoromethane

Author(s): Hodan Warsame, Sarah Patrick, James Bull, Philip W. Miller, Mark Crimmin
Published in: chem, 2024, ISSN 2573-2293
Publisher: chemRxiv
DOI: 10.26434/chemrxiv-2024-v6xtr