Highly Reactive Low-valent Aluminium Complexes and their Application in Synthesis and Catalysis

Project Information

ALLOWE

Grant agreement ID: 101001591

DOI

10.3030/101001591

EC signature date 18 December 2020

Start date 1 June 2021

End date 31 May 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 997 750,00

EU contribution

€ 1 997 750,00

Coordinated by

TECHNISCHE UNIVERSITAET MUENCHEN
Germany

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Publications

Peer reviewed articles (8)

Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species

Author(s): Xufang Liu, Arseni Kostenko, Matthew M. D. Roy, Tobias Weng, Shigeyoshi Inoue
Published in: Nature Communications, Issue 16, 2025, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-025-63460-9

Synthesis, Isolation, and Reactivity of an Aluminum Triiodide Supported by an NHC/cAAC‐Based Carbodicarbene Ligand

Author(s): Yueer Zhu, Fiona J. Kiefer, Shigeyoshi Inoue
Published in: Zeitschrift für anorganische und allgemeine Chemie, Issue 652, 2026, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.202500190

Isolation of Cyclic Aluminium Polysulfides by Stepwise Sulfurization.

Author(s): Shigeyoshi Inoue; Huihui Xu; Catherine Weetman; Franziska Hanusch
Published in: Chemistry A European Journal, 2022, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202104042

Dialumene as a Dimeric or Monomeric Al Synthon for C–F Activation in Monofluorobenzene

Author(s): Xufang Liu, Shicheng Dong, Jun Zhu, Shigeyoshi Inoue
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 23591-23597, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c08171

An Aluminium Telluride with a Terminal Al=Te Bond and its Conversion to an Aluminium Tellurocarbonate by CO2 Reduction

Author(s): Huihui Xu, Arseni Kostenko, Catherine Weetman, Shiori Fujimori, Shigeyoshi Inoue
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202216021

Dearomatization of C₆ Aromatic Hydrocarbons by Main Group Complexes

Author(s): Huaiyuan Zhu; Shiori Fujimori; Arseni Kostenko; Shigeyoshi Inoue
Published in: Wiley, 2023, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202301973

Synthesis of Alumanyl Silyl Coinage Metal Complexes and their Reactivity Toward CO₂

Author(s): Johannes Voigtland, Moritz Ludwig, Sebastian Stigler, Shigeyoshi Inoue
Published in: ChemistryEurope, 2025, ISSN 2751-4765
Publisher: Wiley
DOI: 10.1002/ceur.202500216

Direct access to a neutral alumene via CO reduction by a dialane and further CO homologation

Author(s): John A. Kelly, Arseni Kostenko, Shigeyoshi Inoue
Published in: Nature Synthesis, Issue 4, 2025, Page(s) 1577-1586, ISSN 2731-0582
Publisher: Springer Science and Business Media LLC
DOI: 10.1038/s44160-025-00874-9

Non-peer reviewed articles (1)

Dialumene-Mediated Production of Phosphines through P4 Reduction

Author(s): Huihui Xu, Matthew Roy, Arseni Kostenko, John Kelly, Shiori Fujimori, Shigeyoshi Inoue
Published in: Angewandte Chemie International Edition, 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202404532