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Chlorine isotope fractionation in Earth's mantle and crust - Experimental investigation on their role in magmatic ore formation processes and deep volatile cycling

Project description

Chlorine cycling in Earth's mantle and crust

Although the Earth's deep chlorine (Cl) cycle is poorly understood, it is known that a substantial quantity of Cl is brought into the mantle via subduction. However, a significant fraction is returned as Cl-rich brines, although high concentrations of Cl in parts of the mantle are witnessed in diamonds. Hence, Cl-rich brines likely play central roles in transporting elements to form magmatic ore deposits. The EU-funded ExCliso project will perform high pressure-temperature experiments to investigate the deep Cl cycle, focusing on Cl partitioning and δ37Cl stable isotope fractionation between fluids, melts and relevant mantle phases. Results will help quantify the Earth's deep halogen cycle while providing constraints to test hypotheses on magmatic ore deposit formation from a new perspective.

Objective

The Earth’s deep chlorine (Cl) cycle remains poorly understood. A major amount of Cl is brought into the mantle by subduction, but a significant fraction is returned as Cl-rich brines, although high concentrations of Cl in parts of the mantle are attested to by inclusions in diamonds. Cl-rich brines likely play central roles in transporting elements to form magmatic ore deposits. The proposed research will investigate the deep Cl cycle from an experimental perspective, focusing on Cl partitioning and δ37Cl stable isotope fractionation between fluids, melts and relevant mantle phases. The high pressure-temperature experiments will be performed at the Australian National University, Australia and the University of Frankfurt, Germany, with Cl analyses and isotope fractionation enabled by state-of the-art instruments (SHRIMP in Canberra and SIMS in Heidelberg, Germany). These innovative experiments will help quantify the Earth’s deep halogen cycle, while also providing constrains to test hypotheses on magmatic ore deposit formation from a perspective that is significantly different from those currently available. During his Diploma (University of Mainz), PhD, and post doctoral studies (University of Münster; Sorbonne Université Paris) the applicant used a wide range of analytical and experimental methods, while gaining a profound knowledge of halogens, isotope fractionation, and phase equilibria of mantle and crust. He thus brings a wealth of theoretical, experimental and analytical experience to the project, which will compliment the expertise that he aims to acquire in ion microprobe techniques. Both the ANU and the University of Frankfurt would benefit from the applicant’s research experience, which will be applied to a novel research direction. In return the applicant would greatly benefit from gaining ion probe analysis skills and deepening his knowledge about experiment petrology and ore geology at two of the world’s leading institutions in these fields.

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MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2020

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Coordinator

JOHANN WOLFGANG GOETHE-UNIVERSITAET FRANKFURT AM MAIN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 270 876,48
Address
THEODOR W ADORNO PLATZ 1
60323 FRANKFURT AM MAIN
Germany

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Region
Hessen Darmstadt Frankfurt am Main, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 270 876,48

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