Livrables
We will develop a webpage easy to comprehend for the public society
Press releases/media actions 2Second press releases and media actions performed.
Press releases/media actions 3Third press releases and media actions performed.
Educational VideoWe will produce a short video clip with the help of computer graphics that demonstrate how LIGHTCAP will utilize and store the light energy that is so far disregarded by siliconbased solar cells and batteriescapacitors and which are the stateoftheart scientific methods implemented to reach these goals In this way the audience will get insight into very fundamental and scientific aspects whilst getting an overview over the project idea
Press releases/media actionsAdditionally each partner will contribute to the publication of news as Press Releases at the beginning of the project and for important results feature articles and RadioTelevision Broadcasting on a local and national level but at least oncetwice a year continuously searching for opportunities to promote the project main goals and results at the European levelFirst press releases and media actions performed
In order to target a concentration of 1-3 M of the nanoinks, the introduction of the bulky functional groups on the periphery of the GQDs will also be prepared.
Nanoinks with optimized propertiesThis deliverable deals with the the production of the fundamental materials and their hybrid coupling The materials will be produced in such a way that optical properties are optimized learning from the results from WP1
Report on preparation of the GQDs that functionalized with amino groupsIn this deliverable GQDs with functionalized with amino groups will be prepared and optimzed towards their improved optoelectronic properties A major aspect will be to match the energy levels with the nanoparticles and to ensure stability in solution
Report on preparation of the GQDs that functionalized with pyrrole groupsIn this deliverable GQDs with functionalized with pyrrole groups will be prepared and optimzed towards their improved optoelectronic properties. A major aspect will be to match the energy levels with the nanoparticles and to ensure stability in solution.
Dense nanoparticle inksDensification of nanoparticle inks to 1-3 M is aimed and requires the work on the surface ligands or functional groups to ensure a stable solution while avoiding agglomeration. The stability in several different solvents as well as salts will be studied
Mesoporous structures and thin filmsThin films will be produced by deposition methods based on liquid processing from nanoparticle colloidal suspensions (spin coating, dip coating). Surface control of the nanocrystals and anchoring groups of the molecules are essential to obtain novel grafting methods. Mesoporous structures or thin films will be produced through aerosol methods or chemical deposition of pre-formed nano-species, respectively, in order to generate high porosity and specific surface area transparent photoactive materials with a tunable interface. Methods will be developed to incorporate plasmonic or photoactive species within the mesopores or locate them on the surface, in order to control electron flow or catalytic processes.
Hybrid interaction extractedThe optical properties of the prefabricated (nano)structures will be assessed by different spectroscopy techniques. Importance is devoted to the extraction of fundamental hybrid interaction at the liquid-liquid, liquid-solid and solid-solid interface. This task is of major importance as it will deliver the foundation for understanding multiple charge transfer reactions and their limiting factors. We will implement transient absorption spectroscopy with a temporal resolution from hundreds of femtoseconds to pico-, nano- and where necessary microseconds, to unravel charge carrier dynamics immediately after excitation with spectrally resolved probe to extract carrier relaxation pathways, timescales and efficiencies. These experiments will be performed on many different samples and hybrid combinations for a systematic understanding of the several different factors of materials, surfactants, functional groups, energy separation etc. influencing multiple charge transfer reactions. These results will be supported by several other complementary techniques, such as steady state UV-vis-NIR absorption/transmission and photoluminescence (PL) spectroscopy, scattering, dark field or confocal scanning microscopy, PL quantum yield, Raman spectroscopy/microscopy; as well as ultrafast measurements time resolved photoluminescence.
Optimized optoelectronic properties extractedIn order to proceed with the characterization of the electrodes their electric properties will be studied using various setups based on electrical probe stations operating in ambient condition and at low temperatures. These systems will allow the determination of various optoelectronic properties such as conductivity, photocurrent and detectivity, majority carriers and carrier mobilities, etc. To characterize the charge carrier injection properties in solution and solid-state we will combine spectroelectrochemical methods with common electrochemical tuning and several different optoelectronic tools such as (dark/illuminated) Kelvin Probe Microscopy, standard IV curves, impedance spectroscopy and CV curves etc.
The photoactive compartment will consist of a 0D NCPC-based electrolyte. The GQD dispersion acting as catholyte is selected on the basis of the optical photoelectrochemical performance elucidated in WP2. Such structures serve as first demonstrators for the light driven charge storage of multiple charges and will be coupled to respective counter electrodes and or proper electrolytes (see below).
Proof-of-concept light-driven single system multi-charge transfer electrodes (only solid)The 0D NCPC-based electrode is coupled to a standard catholyte and standarad electrodes used to carry out the redox reactions in electrolytes based on redox active small organic molecules such as viologens, antraquinones, phenazynes, etc. The electrochemical measurements will be performed using potentiostat/galvanostat stations. The electrode/electrolyte couple of each cell compartment will be first investigated through cyclic voltammetry measurements in a three-electrode cell configuration using proper reference electrodes and counter electrodes, depending on the nature of the solvent of the electrolyte The polarization curve analysis will be performed on the whole cells under light in order to understand the rate capability of the energy storage.
Proof-of-concept light-driven hybrid multiple-charge transfer electrode (solid-liquid)In the first flow cell architecture the 0D NCPC-based electrode is coupled to the GQDs dispersion (acting as the catholyte). The other compartment will be based on electrodes used to carry out the redox reactions in electrolytes based on redox active small organic molecules such as viologens, antraquinones, phenazynes, etc. This will be assembled to photo-electrochemical H-cell with electrolyte input/output ports, as well as compact no-gap serpentine architecture. The polarization curve analysis will be performed on the whole cells under light in order to understand the rate capability of the energy storage. High-frequency resistance of the system will be measured by electrochemical impedance spectroscopy to exclude possible series resistance effects, thus determining iR-corrected polarization curves specifically resulting by kinetic losses. Galvanostatic charge discharge measurements of the systems will be carried out at different current densities, which will be selected on the basis of the polarization curve results. Solar-driven charge will be investigated by coupling a light source to the flow cell and illuminating the transparent electrode while monitoring the obtained photocurrent and photovoltage. Experiments with electrolytes having different concentration of redox-active materials and being initially charged at different states of charge (SOC) will be performed to investigated the efficiency of the solar-driven flow batteries as a function of the electrolyte composition. The light storage efficiency will be calculated as the ratio between the stored energy density in the system and the energy of the incident light. Additionally, coulombic efficiency (i.e., the ratio between discharge capacity and the charge capacity), the voltage efficiency (i.e., the ration between the average voltage during discharging and the average voltage during charging), as well as the energy efficiency (i.e., the product between the coulombic efficiency and the voltage efficiency), will be determined by the charge/discharge curve analysis. For the overall flow-driven system, the “overall” energy conversion efficiency will be determined by the product between the charge storage efficiency and the energy efficiency. In order to observe the intrinsic properties and electrode performance, it is essential to elucidate the electron transport at the electrode/nanomaterial interface for examples by using local AFM based technologies. We will additionally implement nanomanipulators to extract the electronic characteristics and any other microscope to study very locally and with micrometer precision the device characteristics. Lastly, AFM mapping of electrical analysis, such as I-V curves and impedance spectroscopy will additionally give information on the electrode characteristics. Long-term experiments will be performed by galvanostatic experiments
ExhibitOur handson exhibit isfundamental to convey the main objectives and open questions to the general public at large but in particular also to deliver an informal education to young people raising their awareness of nowadays energy problem and triggering their interest into science and technology
Release of the second Data Management Plan
Data Management Plan 3Release of the final Data Management Plan
Data management planThe management of the data that will be collected processed andor generated within LIGHTCAP will be defined in the data management plan DMP to ensure the efficient data and knowledge integration and reuse By balancing openness and protection of scientific information in particular where commercialization and IPRs are important we will decide on data which can be made public by publishing the data on platforms such as Zenodo Confidential data will be made accessible among LIGHTCAP participants and probable collaborators An online platform eg Cloud services accessible by all participants will be established Open access to all peerreviewed scientific publications arising from LIGHTCAP will be ensured by choosing either selfarchiving green open access or open access publishing gold open access We will provide an online repository for the deposition of all articles before alongside or after publication and will be linked to our web page Release of the first Data Management Plan
Publications
Auteurs:
Aaron M. Ross, Silvio Osella, Veronica R. Policht, Meng Zheng, Michele Maggini, Fabio Marangi, Giulio Cerullo, Teresa Gatti, and Francesco Scotognella
Publié dans:
J. Phys. Chem. C, 2022, ISSN 1932-7455
Éditeur:
ACS
DOI:
10.1021/acs.jpcc.1c10570
Auteurs:
Zhang, Panpan; Wang, Mingchao; Liu, Yannan; Fu, Yubin; Gao, Mingming; Wang, Gang; Wang, Faxing; Wang, Zhiyong; Chen, Guangbo; Yang, Sheng; Liu, Youwen; Dong, Renhao; Yu, Minghao; Lu, Xing; Feng, Xinliang
Publié dans:
Journal of the American Chemical Society, Numéro 33, 2023, ISSN 0002-7863
Éditeur:
American Chemical Society
DOI:
10.1021/jacs.2c12684
Auteurs:
Grieco, Rebecca; Luzanin, Olivera; Alván, Diego; Liras, Marta; Dominko, Robert; Patil, Nagaraj; Bitenc, Jan; marcilla, rebeca
Publié dans:
Faraday discussions, str. 1-13 : Ilustr., 16 Aug. 2023, Numéro 250, 2024, ISSN 1364-5498
Éditeur:
Royal Society of Chemistry
DOI:
10.1039/d3fd00132f
Auteurs:
Dimitris Tsikritzis; Konstantinos Chatzimanolis; Nikolaos Tzoganakis; Sebastiano Bellani; Marilena Isabella Zappia; Gabriele Bianca; Nicola Curreli; Joka Buha; Ilka Kriegel; Nikolas Antonatos; Zdeněk Sofer; Miron Krassas; Konstantinos Rogdakis; Francesco Bonaccorso; Emmanuel Kymakis
Publié dans:
Sustainable Energy and Fuels, Numéro 31, 2022, Page(s) 5345-5359, ISSN 2398-4902
Éditeur:
Royal Society of Chemistry
DOI:
10.1039/d2se01109c
Auteurs:
Bianca, Gabriele; Zappia, Marilena Isabella; Bellani, Sebastiano; Ghini, Michele; Curreli, Nicola; Buha, Joka; Galli, Valerio; Prato, Mirko; Soll, Aljoscha; Sofer, Zdeněk; Lanzani, Guglielmo; Kriegel, Ilka; Bonaccorso, Francesco
Publié dans:
Advanced Materials Interfaces, Numéro 32, 2022, ISSN 2196-7350
Éditeur:
Wiley
DOI:
10.1002/admi.202201635
Auteurs:
Feste, PD, Crisci, M, Barbon, F, Tajoli, F, Salerno, M, Drago, F, Prato, M, Gross, S, Gatti, T, Lamberti, F
Publié dans:
APPLIED SCIENCES, 2021, ISSN 2076-3417
Éditeur:
MDPI
DOI:
10.3390/app11052016
Auteurs:
Dr. M. R. Ajayakumar, Dr. Ji Ma, Prof. Dr. Xinliang Feng
Publié dans:
European Journal of Organic Chemistry, 2022, ISSN 1099-0690
Éditeur:
WILEY-V C H VERLAG GMBH
DOI:
10.1002/ejoc.202101428
Auteurs:
Teresa Gatti, Francesco Lamberti, Raffaello Mazzaro, Ilka Kriegel, Derck Schlettwein, Francesco Enrichi, Nicolò Lago, Eleonora Di Maria, Gaudenzio Meneghesso, Alberto Vomiero, Silvia Gross
Publié dans:
Advanced Energy Materials, 2021, ISSN 1614-6840
Éditeur:
WILEY-V C H VERLAG GMBH
DOI:
10.1002/aenm.202101041
Auteurs:
Fabian Schmitz, Raphael Neisius, Jonas Horn, Joachim Sann, Derck Schlettwein, Marina Gerhard, Teresa Gatti
Publié dans:
Nanotechnology, 2021, ISSN 1361-6528
Éditeur:
IOP Publishing Ltd
DOI:
10.1088/1361-6528/ac54df
Auteurs:
Michele Ghini, Nicola Curreli, Matteo B. Lodi, Nicolò Petrini, Mengjiao Wang, Mirko Prato, Alessandro Fanti, Liberato Manna, Ilka Kriegel
Publié dans:
Nature Communcations, 2022, ISSN 2041-1723
Éditeur:
Nature Publishing Group
DOI:
10.1038/s41467-022-28140-y
Auteurs:
Matteo Crisci; Felix Boll; Leonardo Merola; Jonas Johannes Pflug; Zheming Liu; Jaime Gallego; Francesco Lamberti; Teresa Gatti
Publié dans:
Crossref, Numéro 3, 2022, ISSN 2296-2646
Éditeur:
Frontiers
DOI:
10.3389/fchem.2022.1000910
Auteurs:
Quy Ong, Xufeng Xu, Francesco Stellacci
Publié dans:
Analitical Chemistry, Numéro 96, 2024, Page(s) 2567-2573, ISSN 0003-2700
Éditeur:
American Chemical Society
DOI:
10.1021/acs.analchem.3c05006
Auteurs:
Pedraza, Eduardo; de la Cruz, Carlos; Mavrandonakis, Andreas; Ventosa, Edgar; Rubio-Presa, Rubén; Sanz, Roberto; Senthilkumar, Sirugaloor Thangavel; Navalpotro, Paula; Marcilla, Rebeca
Publié dans:
Advanced Energy Materials, Numéro 13 (39), 2023, ISSN 1614-6840
Éditeur:
Wiley-VCH GmbH
DOI:
10.1002/aenm.202301929
Auteurs:
Michele Ghini, Andrea Rubino, Andrea Camellini, Ilka Kriegel
Publié dans:
Nanoscale Advances, 2021, ISSN 2516-0230
Éditeur:
ROYAL SOC CHEMISTRY
DOI:
10.1039/d1na00656h
Auteurs:
Marilena I. Zappia, Gabriele Bianca, Sebastiano Bellani, Nicola Curreli, Zdeněk Sofer, Michele Serri, Leyla Najafi, Marco Piccinni, Reinier Oropesa-Nuñez, Petr Marvan, Vittorio Pellegrini, Ilka Kriegel, Mirko Prato, Anna Cupolillo, Francesco Bonaccorso
Publié dans:
J. Phys. Chem. C, 2021, ISSN 1932-7455
Éditeur:
ACS
DOI:
10.1021/acs.jpcc.1c03597
Auteurs:
Silvio Osella, Mengjiao Wang, Enzo Menna, Teresa Gatti
Publié dans:
Optical Materials: X, 2021, ISSN 2590-1478
Éditeur:
Elsevier
DOI:
10.1016/j.omx.2021.100100
Auteurs:
Jin-Jiang Zhang, Ji Ma, Fupin Liu, Lin-Song Cui, Yubin Fu, Lin Yang, Alexey A. Popov, Jan J. Weigand, Junzhi Liu, and Xinliang Feng
Publié dans:
Organic Letters, 2022, ISSN 1523-7052
Éditeur:
AMER CHEMICAL SOC
DOI:
10.1021/acs.orglett.2c00033
Auteurs:
Michele Ghini, Nicola Curreli, Andrea Camellini, Mengjiao Wang, Aswin Asaithambi, Ilka Kriegel
Publié dans:
Nanoscale, 2021, ISSN 2040-3372
Éditeur:
ROYAL SOC CHEMISTRY
DOI:
10.1039/d0nr09163d
Auteurs:
Xufeng Xu, Quy Ong, Ting Mao, Paulo Jacob Silva, Seishi Shimizu, Luca Rebecchi, Ilka Kriegel, Francesco Stellacci
Publié dans:
ADVANCED MATERIALS INTERFACES, 2022, ISSN 2196-7350
Éditeur:
WILEY
DOI:
10.1002/admi.202200600
Auteurs:
Gabriele Bianca, Chiara Trovatello, Attilio Zilli, Marilena Isabella Zappia, Sebastiano Bellani, Nicola Curreli, Irene Conticello, Joka Buha, Marco Piccinni, Michele Ghini, Michele Celebrano, Marco Finazzi, Ilka Kriegel, Nikolas Antonatos, Zdeněk Sofer, and Francesco Bonaccorso
Publié dans:
ACS Applied Materials and Interfaces, 2022, ISSN 1944-8244
Éditeur:
American Chemical Society
DOI:
10.1021/acsami.2c07704
Auteurs:
Matteo Crisci, Paolo Dolcet, Jijin Yang, Marco Salerno, Péter Bélteky, Ákos Kukovecz, Francesco Lamberti, Stefano Agnoli, Silvio Osella, Silvia Gross, and Teresa Gatti
Publié dans:
JOURNAL OF PHYSICAL CHEMISTRY C, 2021, ISSN 1932-7455
Éditeur:
ACS
DOI:
10.1021/acs.jpcc.1c09221
Auteurs:
Fupeng Wu, Dr. Ji Ma, Dr. Federico Lombardi, Dr. Yubin Fu, Dr. Fupin Liu, Zhijie Huang, Renxiang Liu, Dr. Hartmut Komber, Dr. Dimitris I. Alexandropoulos, Dr. Evgenia Dmitrieva, Dr. Thorsten G. Lohr, Noel Israel, Dr. Alexey A. Popov, Dr. Junzhi Liu, Prof. Dr. Lapo Bogani, Prof. Dr. Xinliang Feng
Publié dans:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, ISSN 1521-3773
Éditeur:
WILEY-V C H VERLAG GMBH
DOI:
10.1002/anie.202202170
Auteurs:
Felix Boll; Matteo Crisci; Leonardo Merola; Francesco Lamberti; Bernd Smarsly; Teresa Gatti
Publié dans:
Crossref, Numéro 1, 2023, ISSN 2699-9412
Éditeur:
Wiley
DOI:
10.1002/aesr.202300121
Auteurs:
Fabian Schmitz, Jonas Horn, Nicola Dengo, Alexander E. Sedykh, Jonathan Becker, Elena Maiworm, Péter Bélteky, Ákos Kukovecz, Silvia Gross, Francesco Lamberti, Klaus Müller-Buschbaum, Derck Schlettwein, Daniele Meggiolaro, Marcello Righetto, and Teresa Gatti
Publié dans:
Chemistry of Materials, 2021, ISSN 1520-5002
Éditeur:
AMER CHEMICAL SOC
DOI:
10.1021/acs.chemmater.1c01182
Auteurs:
Andrea Rubino, Andrea Camellini, Ilka Kriegel
Publié dans:
Optical Materials: X, 2021, ISSN 2590-1478
Éditeur:
Elsevier
DOI:
10.1016/j.omx.2021.100081
Auteurs:
Francesco Lamberti, Fabian Schmitz, Wei Chen, Zhubing He, Teresa Gatti
Publié dans:
SOLAR RRL, 2021, ISSN 2367-198X
Éditeur:
WILEY-V C H VERLAG GMBH
DOI:
10.1002/solr.202100514
Auteurs:
Lin Yang, Ji Ma, Wenhao Zheng, Silvio Osella, Jörn Droste, Hartmut Komber, Kun Liu, Steffen Böckmann, David Beljonne, Michael Ryan Hansen, Mischa Bonn, Hai I. Wang, Junzhi Liu, Xinliang Feng
Publié dans:
Advanced Science, 2022, ISSN 2198-3844
Éditeur:
WILEY
DOI:
10.1002/advs.202200708
Auteurs:
Davood Sabaghi; Zhiyong Wang; Preeti Bhauriyal; Qiongqiong Lu; Ahiud Morag; Daria Mikhailovia; Payam Hashemi; Dongqi Li; Christof Neumann; Zhongquan Liao; Anna Maria Dominic; Ali Shaygan Nia; Renhao Dong; Ehrenfried Zschech; Andrey Turchanin; Thomas Heine; Minghao Yu; Xinliang Feng
Publié dans:
Nature Communications, Numéro 22, 2023, Page(s) 760, ISSN 2041-1723
Éditeur:
Nature Publishing Group
DOI:
10.1038/s41467-023-36384-5
Auteurs:
Paula Navalpotro; Santiago E. Ibañez; Eduardo Pedraza; Rebeca Marcilla
Publié dans:
Energy Storage Materials, Numéro 56, 2023, Page(s) 403-411, ISSN 2405-8297
Éditeur:
Elsevier
DOI:
10.1016/j.ensm.2023.01.033
Auteurs:
Aswin Asaithambi, Nastaran Kazemi Tofighi, Nicola Curreli, Manuela De Franco, Aniket Patra, Nicolò Petrini, Dmitry Baranov, Liberato Manna, Francesco Di Stasio, Ilka Kriegel
Publié dans:
Advanced Optical Materials, 2022, ISSN 2195-1071
Éditeur:
WILEY-V C H VERLAG GMBH
DOI:
10.1002/adom.202200638
Auteurs:
Kalyan Biswas, Lin Yang, Ji Ma, Ana Sánchez-Grande, Qifan Chen, Koen Lauwaet, José M. Gallego, Rodolfo Miranda, David Écija, Pavel Jelínek, Xinliang Feng, José I. Urgel
Publié dans:
NANOMATERIALS, 2022, ISSN 2079-4991
Éditeur:
MDPI
DOI:
10.3390/nano12020224
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