Clip-off Chemistry: Design and Synthesis of New Materials via Programmable Disassembly of Reticular Materials

Project Information

CLIPOFF-CHEM

Grant agreement ID: 101019003

DOI

10.3030/101019003

EC signature date 7 June 2021

Start date 1 October 2021

End date 30 September 2027

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 505 645,00

EU contribution

€ 2 505 645,00

Coordinated by

FUNDACIO INSTITUT CATALA DE NANOCIENCIA I NANOTECNOLOGIA
Spain

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (13)

Isoreticular Synthesis of Mesoporous Metal‐Organic Polyhedra with Permanent Porosity to Gas and Water

Author(s): Alba Cortés‐Martínez, Pilar Fernández‐Seriñán, Cornelia von Baeckmann, Caterina Caules, Laura Hernández‐López, María Susana Gutiérrez Gómez, Yunhui Yang, Roberto Sánchez‐Naya, José A. Suárez del Pino, Judith Juanhuix, Inhar Imaz, Arnau Carné‐Sánchez, Daniel Maspoch
Published in: Angewandte Chemie International Edition, Issue 64, 2025, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202505682

Modulation of the Dynamics of a Two-Dimensional Interweaving Metal–Organic Framework through Induced Hydrogen Bonding

Author(s): Pilar Fernández-Seriñán; Kornel Roztocki; Vahid Safarifard; Vincent Guillerm; Sabina Rodríguez-Hermida; Judith Juanhuix; Inhar Imaz; Ali Morsali; Daniel Maspoch
Published in: Inorg. Chem., Issue 63, 2024, Page(s) 5552-5558, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c04522

Excision in Two Dimensions: Synthesis of 2D Metal–Organic Nanosheets via Clip-off Chemistry

Author(s): Pilar Fernández-Seriñán, Partha Samanta, Inhar Imaz, Daniel Maspoch
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 45849-45854, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.5c16242

Merging and Clipping Nets for the Synthesis of Three- and Two-Merged Net Metal–Organic Frameworks

Author(s): Yunhui Yang, Pilar Fernández-Seriñán, Borja Ortín-Rubio, Partha Samanta, Felipe Gándara, Davide M. Proserpio, Dongsik Nam, Judith Juanhuix, Inhar Imaz, Daniel Maspoch
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 1344-1355, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c15936

Linker desymmetrisation unlocks new topologies, defective clusters, and catalytic activity in zirconium- and rare-earth metal–organic frameworks

Author(s): Borja Ortín-Rubio, Yunhui Yang, Emilio Borrego-Marin, Jaume Rostoll-Berenguer, Carlos Vila, Judith Juanhuix, Inhar Imaz, Jorge A. R. Navarro, Daniel Maspoch
Published in: Chemical Science, Issue 16, 2025, Page(s) 21600-21613, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d5sc05365j

Excision of organic macrocycles from covalent organic frameworks

Author(s): Roberto Sánchez-Naya, Juan Pablo Cavalieri, Jorge Albalad, Alba Cortés-Martínez, Kaiyu Wang, Carles Fuertes-Espinosa, Teodor Parella, Sara Fiori, Esteve Ribas, Aitor Mugarza, Xavi Ribas, Jordi Faraudo, Omar M. Yaghi, Inhar Imaz, Daniel Maspoch
Published in: Science, Issue 388, 2025, Page(s) 1318-1323, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.adw4126

Synthesis of metal–organic cages via orthogonal bond cleavage in 3D metal–organic frameworks

Author(s): S. Ruiz-Relaño, D. Nam, J. Albalad, A. Cortés-Martínez, J. Juanhuix, I. Imaz, D. Maspoch
Published in: J. Am. Chem. Soc., Issue 146, 2024, Page(s) 26603-26608, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c09431

Isoreticular Contraction of Metal–Organic Frameworks Induced by Cleavage of Covalent Bonds

Author(s): Yunhui Yang; Pilar Fernández-Seriñán; Inhar Imaz; Felipe Gándara; Marcel Handke; Borja Ortín-Rubio; Judith Juanhuix; Daniel Maspoch
Published in: J. Am. Chem. Soc., Issue 145, 31, 2023, Page(s) 17398-17405, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c05469

Retrosynthetic Analysis Applied to Clip‐off Chemistry: Synthesis of Four Rh(II)‐Based Complexes as Proof‐of‐Concept

Author(s): Anna Broto‐Ribas; Sara Ruiz‐Relaño; Jorge Albalad; Yunhui Yang; Felipe Gándara; Judith Juanhuix; Inhar Imaz; Daniel Maspoch
Published in: Angew. Chem. Int. Ed., Issue 62, 2023, Page(s) e202310354, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202310354

A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker

Author(s): Borja Ortín-Rubio; Cristina Perona-Bermejo; José A. Suárez del Pino; Francisco J. Carmona; Felipe Gándara; Jorge A. R. Navarro; Judith Juanhuix; Inhar Imaz; Daniel Maspoch
Published in: Chem. Commun., Issue 59, 2023, Page(s) 7803-7806, ISSN 1742-2183
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3cc01831h

Isolation of the secondary building unit of a 3D Metal−Organic Framework through Clip-Off Chemistry, and its reuse to synthesize new frameworks by dynamic covalent chemistry

Author(s): D. Nam, J. Albalad, R. Snchez-Naya, S. Ruiz Relao, A. Cortés-Martínez, Y. Yang, J. Juanhuix, I. Imaz, D. Maspoch
Published in: J. Am. Chem. Soc., Issue 146, 2024, Page(s) 27255-27261, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c09077

Clip-off Chemistry: Synthesis by programmed disassembly of reticular materials

Author(s): Y. Yang, A. Broto-Ribas, B. Ortín-Rubio, I. Imaz, F. Gándara, A. Carné-Sánchez, V. Guillerm, S. Jurado, F. Busqué, J. Juanhuix, D. Maspoch
Published in: Angew. Chem. Int. Ed., Issue 61, 2022, Page(s) e202111228, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202111228

Net-clipping as a top-down approach for the prediction of topologies of MOFs built from reduced-symmetry linkers

Author(s): Borja Ortín-Rubio; Jaume Rostoll-Berenguer; Carlos Vila; Davide M. Proserpio; Vincent Guillerm; Judith Juanhuix; Inhar Imaz; Daniel Maspoch
Published in: Chem. Sci., Issue 14, 2023, Page(s) 12984, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc04406h