Molecular materials for a new generation of artificial muscles

Información del proyecto

E-MOTION

Identificador del acuerdo de subvención: 101019522

DOI

10.3030/101019522

Fecha de la firma de la CE 10 Mayo 2021

Fecha de inicio 1 Octubre 2021

Fecha de finalización 31 Marzo 2027

Financiado con arreglo a

• EXCELLENT SCIENCE - European Research Council (ERC)

Coste total

€ 2 666 152,00

Aportación de la UE

€ 2 666 152,00

Coordinado por

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
France

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Publicaciones

Peer reviewed articles (29)

Soft Actuators Based on Spin-Crossover Particles Embedded in Thermoplastic Polyurethane

Autores: Yue Zan, Mario Piedrahita-Bello, Seyed E. Alavi, Gábor Molnár, Bertrand Tondu, Lionel Salmon, Azzedine Bousseksou
Publicado en: Advanced Intelligent Systems, 2023, ISSN 2640-4567
Editor: Wiley
DOI: 10.1002/aisy.202200432

Drastic Enhancement of Electrical Conductivity of Metal–Organic Frameworks Displaying Spin Crossover

Autores: Fayan Lai, Livia Getzner, Aurelian Rotaru, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Chemistry of Materials, Edición 37, 2025, Página(s) 636-643, ISSN 0897-4756
Editor: American Chemical Society
DOI: 10.1021/acs.chemmater.4c02468

Room temperature spin crossover properties in a series of mixed-anion Fe(NH2trz)3(BF4)2-x(SiF6)x/2 complexes

Autores: Xinyu Yang, Alejandro Enriquez-Cabrera, Kane Jacob, Yannick Coppel, Lionel Salmon, Azzedine Bousseksou
Publicado en: Dalton Transactions, 2024, ISSN 1477-9234
Editor: Royal Society of Chemistry
DOI: 10.1039/d4dt00267a

Spin crossover in mixed-anion Fe(NH2trz)3(BF4)(SiF6)0.5 crystalline rod-shaped particles: the strength of the solid–liquid post synthetic modification

Autores: Xinyu Yang, Alejandro Enriquez-Cabrera, Dorian Toha, Yannick Coppel, Lionel Salmon, Azzedine Bousseksou
Publicado en: Dalton Transactions, 2024, ISSN 1477-9226
Editor: Royal Society of Chemistry
DOI: 10.1039/d3dt02003g

Thermal hysteresis of stress and strain in spin-crossover@polymer composites: towards a rational design of actuator devices

Autores: José Elias Angulo-Cervera; Mario Piedrahita-Bello; Baptiste Martin; Seyed Ehsan Alavi; William Nicolazzi; Lionel Salmon; Gábor Molnár; Azzedine Bousseksou
Publicado en: Materials Advances, 2022, ISSN 2633-5409
Editor: Royal Society of Chemistry
DOI: 10.1039/d2ma00459c

Postsynthetic Integration of Silver Atoms into Spin Crossover Hofmann-Type Clathrates

Autores: Fayan Lai, Laure Vendier, Dominique Housset, Aurelian Rotaru, Lucie Routaboul, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Inorganic Chemistry, Edición 65, 2026, Página(s) 475-482, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.5c04594

Various Sizes and Shapes of Mixed-Anion Fe(NH2trz)3(BF4)2−x(SiF6)x/2@SiO2 Nanohybrid Particles Undergoing Spin Crossover Just Above Room Temperature

Autores: Xinyu Yang, Rafal Bielas, Vincent Collière, Lionel Salmon, Azzedine Bousseksou
Publicado en: Nanomaterials, Edición 15, 2025, Página(s) 90, ISSN 2079-4991
Editor: MDPI AG
DOI: 10.3390/nano15020090

Hofmann Clathrates: A “Blue Box” Approach to Modulate Spin‐Crossover Properties

Autores: Livia Getzner, Laure Vendier, Gábor Molnár, Aurelian Rotaru, Saioa Cobo, Azzedine Bousseksou
Publicado en: Angewandte Chemie International Edition, Edición 63, 2024, Página(s) e202412525 (1-7), ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202412525

Self-Healing Composite Polymers Based on Spin Crossover Materials for Multidirectional Preprogrammed Actuation

Autores: Alejandro Enriquez-Cabrera, Xinyu Yang, Seyed Ehsan Alavi, Lionel Salmon, Azzedine Bousseksou
Publicado en: ACS Applied Polymer Materials, Edición 6, 2024, Página(s) 9364-9374, ISSN 2637-6105
Editor: American Chemical Society
DOI: 10.1021/acsapm.4c02098

Elastic Properties of the Iron(II)–Triazole Spin Crossover Complexes [Fe(Htrz)2trz]BF4 and [Fe(NH2trz)3]SO4

Autores: Damian Paliwoda, Laure Vendier, Livia Getzner, Frederico Alabarse, Davide Comboni, Baptiste Martin, Seyed Ehsan Alavi, Mario Piedrahita Bello, Lionel Salmon, William Nicolazzi, Gábor Molnár, Azzedine Bousseksou
Publicado en: Crystal Growth & Design, 2023, ISSN 1528-7483
Editor: American Chemical Society
DOI: 10.1021/acs.cgd.2c01396

Pressure Tuning of Coupled Structural and Spin State Transitions in the Molecular Complex [Fe(H2B(pz)2)2(phen)]

Autores: Damian Paliwoda, Laure Vendier, William Nicolazzi, Gábor Molnár, Azzedine Bousseksou
Publicado en: Inorganic Chemistry, 2022, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c02286

Raman scattering and X-ray diffraction study of the temperature- and pressure-induced multistep spin transition in the complex {Fe^II(AnPy)₂[Ag^I(CN)₂]₂}·NO₂bz

Autores: Yasmine Remili, Maryam Nasimsobhan, Rubén Turo-Cortés, Laure Vendier, Carlos Bartual-Murgui, Gábor Molnár, Azzedine Bousseksou, José Antonio Real
Publicado en: Physical Chemistry Chemical Physics, Edición 27, 2025, Página(s) 21593-21603, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d5cp02831k

Electron-Transfer-Induced Structural Modification in a Thermochromic Hofmann Clathrate Derivative

Autores: Livia Getzner, Yasmine Remili, Zakaria Ziani, Laure Vendier, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Inorganic Chemistry, Edición 63, 2024, Página(s) 23503-23508, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c04155

Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks

Autores: Livia Getzner, Damian Paliwoda, Laure Vendier, Latévi Max Lawson-Daku, Aurelian Rotaru, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Nature Communications, Edición 15, 2024, ISSN 2041-1723
Editor: Nature Publishing Group
DOI: 10.1038/s41467-024-51385-8

Molecular mechanics simulations of lattice dynamical properties of the spin crossover complex [Fe(pyrazine)][Ni(CN)4]

Autores: Shiteng Mi, Alaa Fahs, Gabor Molnar, William Nicolazzi, Azzedine Bousseksou
Publicado en: Chemical Physics Letters, 2023, ISSN 0009-2614
Editor: Elsevier BV
DOI: 10.1016/j.cplett.2022.140232

Disentangling Surface Energy and Surface/Interface Stress Effects in Spin Crossover Nanomaterials

Autores: Alaa Fahs, Shiteng Mi, William Nicolazzi, Gábor Molnár, Azzedine Bousseksou
Publicado en: Advanced Physics Research, 2023, ISSN 2751-1200
Editor: John Wiley & Sons, Inc.
DOI: 10.1002/apxr.202200055

Pressure-Induced Unexpected Stabilization of the High-Spin State of Iron(II) in a Metal–Organic Framework

Autores: Livia Getzner, Yasmine Remili, Damian Paliwoda, Samuel Gallego-Parra, Joao Elias Figueiredo Soares Rodrigues, Christoph J. Sahle, Radoslaw Kaminski, Yanling Li, Laure Vendier, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Journal of the American Chemical Society, Edición 147, 2025, Página(s) 46497-46504, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.5c16808

Redox-Active Ligand Platforms for Spin-Crossover Materials: Influence of Halogen Substitution in Pt(II) and Ni(II) Hofmann-Type Frameworks

Autores: Livia Getzner, Konul Amraliyeva, Yasmine Remili, Laure Vendier, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Inorganic Chemistry, Edición 64, 2025, Página(s) 21742-21748, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.5c04117

Electrical Sensing of Molecular Spin State Switching in a Spin Crossover Complex Using an Organic Field‐Effect Transistor

Autores: Yuteng Zhang, Seyed Ehsan Alavi, Ion Soroceanu, Dennis Wanyoike Kamau, Aurelian Rotaru, Isabelle Séguy, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou
Publicado en: Advanced Electronic Materials, 2024, Página(s) 2400590, ISSN 2199-160X
Editor: Wiley
DOI: 10.1002/aelm.202400590

Anisotropic spin-crossover composite actuators displaying pre-programmed movements

Autores: Mario Piedrahita-Bello, Xinyu Yang, Seyed Ehsan Alavi, Gábor Molnár, Lionel Salmon, Azzedine Bousseksou
Publicado en: Sensors and Actuators B: Chemical, 2023, ISSN 0925-4005
Editor: Elsevier BV
DOI: 10.1016/j.snb.2023.134147

Elucidating the Correlation Between the Redox Potential, Spin State, and Crystal Structure in a Series of Ferrous Complexes with Redox‐Active Ligands

Autores: Livia Getzner, Yasmine Remili, Zakaria Ziani, Laure Vendier, William Nicolazzi, Aurelian Rotaru, Haizhu Yu, Gábor Molnár, Saioa Cobo, Azzedine Bousseksou
Publicado en: Angewandte Chemie International Edition, 2025, ISSN 1433-7851
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202506965

Acoustic Emissions from Spin Crossover Complexes

Autores: Sarah Mahmoud Mohamed Kamel, Lajos Daróczi, László Z. Tóth, Dezső, L. Beke, Gerardo Gutiérrez-Juárez, Saioa Cobo, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou
Publicado en: Journal of Materials Chemistry C, 2024, ISSN 2050-7534
Editor: Royal Society of Chemistry
DOI: 10.1039/d4tc00495g

Design and development of a self-sensing control for spin crossover based soft electrothermal actuators

Autores: Bhawnath Tiwari, Adelais Trapali, Gábor Molnár, Lionel Salmon, Azzedine Bousseksou
Publicado en: Smart Materials and Structures, Edición 35, 2026, Página(s) 015043, ISSN 0964-1726
Editor: Institute of Physics Publishing
DOI: 10.1088/1361-665x/ae34ff

All-atom molecular dynamics simulation of the [Fe(pyrazine)][Ni(CN)4] spin-crossover complex. II. Spatiotemporal study of a bimorph actuator

Autores: Shiteng Mi, Gábor Molnár, Karl Ridier, William Nicolazzi, and Azzedine Bousseksou
Publicado en: Physical Review B, 2024, ISSN 2469-9969
Editor: American Physical Society
DOI: 10.1103/physrevb.109.054104

Stress-coupled spin state switching in a spin crossover composite modulates current in an organic semiconductor

Autores: Yuteng Zhang, Aurelian Rotaru, Thomas Ranquet, Xinyu Yang, Yue Zan, Benjamin Reig, Isabelle Séguy, Lionel Salmon, Gábor Molnár, Azzedine Bousseksou
Publicado en: Journal of Materials Chemistry C, Edición 13, 2025, Página(s) 18905-18912, ISSN 2050-7534
Editor: Royal Society of Chemistry
DOI: 10.1039/d5tc02153g

Dynamical Mechanical Analysis and Micromechanics Simulations of Spin-Crossover@Polymer Particulate Composites: Toward Soft Actuator Devices

Autores: Seyed Ehsan Alavi, Baptiste Martin, Yue Zan, Xinyu Yang, Mario Piedrahita-Bello, William Nicolazzi, Jean-François Ganghoffer, Lionel Salmon, Gábor Molnár, and Azzedine Bousseksou
Publicado en: Chemistry of Materials, 2023, ISSN 0897-4756
Editor: American Chemical Society
DOI: 10.1021/acs.chemmater.3c00293

Effects of the surface energy and surface stress on the phase stability of spin crossover nano-objects: a thermodynamic approach

Autores: Shiteng Mi , Karl Ridier, Gábor Molnár, William Nicolazzi, Azzedine Bousseksou
Publicado en: Nanoscale, 2024, ISSN 2040-3372
Editor: Royal Society of Chemistry
DOI: 10.1039/d4nr00477a

Spin crossover particle shielding upon grinding in thermoplastic polyurethane composites

Autores: Adelais Trapali, Jean-François Meunier, Michel Baltas, Lionel Salmon, Azzedine Bousseksou
Publicado en: Chemical Communications, Edición 61, 2025, Página(s) 16190-16193, ISSN 1359-7345
Editor: Royal Society of Chemistry
DOI: 10.1039/d5cc04205d

All-atom molecular dynamics simulation of the [Fe(pyrazine)] [Ni(CN)4] spin-crossover complex. I. Thermally induced spin transition in the bulk material

Autores: Shiteng Mi, Gábor Molnár, Karl Ridier, William Nicolazzi, and Azzedine Bousseksou
Publicado en: Physical Review B, 2024, ISSN 2469-9969
Editor: American Institute of Physics
DOI: 10.1103/physrevb.109.054103