Circular Thermoset Materials: How to exploit Precision Engineered Macromolecules in their Bottom-up Design?

Project Information

CiMaC

Grant agreement ID: 101021081

DOI 10.3030/101021081

EC signature date 3 June 2021

Start date 1 November 2021

End date 31 October 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 2 482 500,00

EU contribution € 2 482 500,00

Coordinated by

UNIVERSITEIT GENT
Belgium

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Open Research Data Pilot (1)

Data management plan

Publications

Peer reviewed articles (31)

Resorcinol-derived vitrimers and their flax fiber-reinforced composites based on fast siloxane exchange

Author(s): Tapas Debsharma, Stéphanie Engelen, Ives De Baere, Wim Van Paepegem, Filip E. Du Prez
Published in: Macromolecular rapid communications, 2023, ISSN 1022-1336
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/marc.202300020

Enabling the Reprocessability and Debonding of Epoxy Thermosets Using Dynamic Poly(β‐Amino Amide) Curing Agents

Author(s): Loc Tan Nguyen, Stephan Maes, Filip E. Du Prez
Published in: Advanced Functional Materials, 2024, ISSN 1616-301X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.202419240

Interlaminar fracture toughness behaviour of a repairable glass-fibre-reinforced vitrimer for wind-energy applications

Author(s): Virginia Amfilochiou, Tapas Debsharma, Ives De Baere, Filip Du Prez, Wim Van Paepegem
Published in: Composites Part B: Engineering, Issue 291, 2025, Page(s) 112023, ISSN 1359-8368
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.compositesb.2024.112023

Combining vinylogous urethane and β-amino ester chemistry for dynamic material design

Author(s): Christian Taplan; Joshua Holloway; Filip Du Prez
Published in: POLYMER CHEMISTRY, Issue 8, 2022, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2py00026a

Scalable design of uniform oligourethanes for impact study of chain length, sequence and end groups on thermal properties

Author(s): Jens Van Hoorde, Nezha Badi, Filip E. Du Prez
Published in: Polymer Chemistry, Issue 15, 2024, Page(s) 4319-4326, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4py01001a

Characterising different molecular landscapes in dynamic covalent networks

Author(s): Filip Van Lijsebetten; Kevin De Bruycker; Evelyne Van Ruymbeke; Johan M. Winne; Filip E. Du Prez
Published in: Chemical Science, Vol. 13, no.43, p. 12865-12875 (2022), Issue 2, 2022, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc05528g

Uniform soluble support for the large-scale synthesis of sequence-defined macromolecules

Author(s): Irene De Franceschi; Chiel Mertens; Nezha Badi; Filip Du Prez
Published in: POLYMER CHEMISTRY, Issue 4, 2022, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2py00883a

How molecular architecture defines quantum yields

Author(s): Fred Pashley-Johnson, Rangika Munaweera, Sheikh I. Hossain, Steven C. Gauci, Laura Delafresnaye, Hendrik Frisch, Megan L. O’Mara, Filip E. Du Prez, Christopher Barner-Kowollik
Published in: Nature Communications, Issue 15, 2024, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-024-50366-1

Telechelic sequence-defined oligoamides: their step-economical synthesis, depolymerization and use in polymer networks

Author(s): Irene De Franceschi; Nezha Badi; Filip E. Du Prez
Published in: CHEMICAL SCIENCE, Issue 1, 2024, Page(s) 2805 - 2816, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc04820a

β-Amino amide based covalent adaptable networks with high dimensional stability

Author(s): Loc Tan Nguyen; Francesca Portone; Filip E. Du Prez
Published in: Polymer Chemistry, Issue 2, 2024, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3py01175e

Vinylogous Urea—Urethane Vitrimers: Accelerating and Inhibiting Network Dynamics through Hydrogen Bonding

Author(s): Stéphanie Engelen; Neil D. Dolinski; Chuqiao Chen; Elina Ghimire; Charlie A. Lindberg; Alex E. Crolais; Natsumi Nitta; Johan M. Winne; Stuart J. Rowan; Filip E. Du Prez
Published in: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Issue 2, 2024, Page(s) e202318412, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.

Masked primary amines for a controlled plastic flow of vitrimers

Author(s): Filip Van Lijsebetten; Kevin De Bruycker; Johan M. Winne; Filip E. Du Prez
Published in: ACS MACRO LETTERS, Issue 1, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/acsmacrolett.2c00255

<i>N</i>-Sulfonyl Urethanes to Design Polyurethane Networks with Temperature-Controlled Dynamicity

Author(s): Stephan Maes; Filip Van Lijsebetten; Johan M. Winne; Filip E. Du Prez
Published in: Macromolecules, Issue 1, 2023, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.2c02456

Sustainable design of vanillin-based vitrimers using vinylogous urethane chemistry

Author(s): Stéphanie Engelen; Aleksandra Alicja Wróblewska; Kevin De Bruycker; Resat Aksakal; Vincent Ladmiral; Sylvain Caillol; Filip E. Du Prez
Published in: POLYMER CHEMISTRY, Issue 2, 2022, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2py00351a

Enhanced Viscosity Control in Thermosets Derived from Epoxy and Acrylate Monomers Based on Thermoreversible Aza-Michael Chemistry

Author(s): Stéphanie Engelen; Filip Van Lijsebetten; Resat Aksakal; Johan M. Winne; Filip E. Du Prez
Published in: Macromolecules, Issue 1, 2023, Page(s) 7055-7064, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.3c01198

Direct restoration of photocurable cross-linkers for repeated light-based 3D printing of covalent adaptable networks

Author(s): Loc Tan Nguyen, Filip E. Du Prez
Published in: Materials Horizons, Issue 11, 2024, Page(s) 6408-6415, ISSN 2051-6347
Publisher: RSC
DOI: 10.1039/d4mh00823e

Suppressing Creep and Promoting Fast Reprocessing of Vitrimers with Reversibly Trapped Amines

Author(s): Filip Van Lijsebetten; Kevin De Bruycker; Yann Spiesschaert; Johan M. Winne; Filip E. Du Prez
Published in: Angew. Chem. Int. Ed, Issue 1, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202113872

A Highly Dynamic Covalent Polymer Network without Creep: Mission Impossible?

Author(s): Filip Van Lijsebetten; Tapas Debsharma; Johan M. Winne; Filip E. Du Prez
Published in: Angew. Chemie, Issue 1, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202210405

Thermomechanical characterisation of reprocessable, siloxane-based, glass-fibre-reinforced vitrimers

Author(s): Virginia Amfilochiou, Tapas Debsharma, Ives De Baere, Lode Daelemans, Filip Du Prez, Wim Van Paepegem
Published in: Composites Part B: Engineering, Issue 276, 2024, Page(s) 111354, ISSN 1359-8368
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.compositesb.2024.111354

Aza-Michael Chemistry for PDMS-Based Covalent Adaptable Elastomers: Design and Dual Role of the Silica Filler

Author(s): Loc Tan Nguyen, Chiel Mertens, Filip E. Du Prez
Published in: Macromolecules, Issue 57, 2024, Page(s) 4817-4825, ISSN 0024-9297
Publisher: American Chemical Society
DOI: 10.1021/acs.macromol.4c00023

Thermoswitchable catalysis to inhibit and promote plastic flow in vitrimers

Author(s): Filip Van Lijsebetten; Stephan Maes; Johan M. Winne; Filip E. Du Prez
Published in: Chemical Science, Issue 2, 2024, Page(s) 2041-6520, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc00417e

Epoxy Adhesives with Reversible Hardeners: Controllable Thermal Debonding in Bulk and at Interfaces

Author(s): Filip Van Lijsebetten; Tim Maiheu; Johan M. Winne; Filip E. Du Prez
Published in: Advanced Materials, Issue 2, 2023, ISSN 1521-4095
Publisher: Wiley
DOI: 10.1002/adma.202300802

Recyclable vitrimer epoxy coatings for durable protection

Author(s): Filip Van Lijsebetten; Stéphanie Engelen; Erwin Bauters; Wim Van Vooren; Maarten M.J. Smulders; Filip E. Du Prez
Published in: EUROPEAN POLYMER JOURNAL, Issue 1, 2022, ISSN 0014-3057
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.eurpolymj.2022.111426

Exploring the dual dynamic synergy of transesterification and siloxane exchange in vitrimers

Author(s): Sami Fadlallah, Filip Van Lijsebetten, Tapas Debsharma, Vincent Scholiers, Florent Allais, Filip E. Du Prez
Published in: European Polymer Journal, Issue 213, 2024, Page(s) 113117, ISSN 0014-3057
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.eurpolymj.2024.113117

Fast Dynamic Siloxane Exchange Mechanism for Reshapable Vitrimer Composites

Author(s): Tapas Debsharma; Virginia Amfilochiou; Aleksandra Alicja Wróblewska; Ives De Baere; Wim Van Paepegem; Filip E. Du Prez
Published in: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Issue 7, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c03518

Sequencing of Uniform Multifunctional Oligoesters via Random Chain Cleavages.

Author(s): Matthieu Soete; Filip Du Prez
Published in: Angew. Chem. Int Ed., Issue 2, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202202819

Polyisoprene-based pressure-sensitive adhesives with dynamic crosslinks

Author(s): Tim Maiheu, Jonas Debuyck, Filip Van Lijsebetten, Aitor Hernández, Filip E. Du Prez
Published in: European Polymer Journal, Issue 210, 2024, Page(s) 112998, ISSN 0014-3057
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.eurpolymj.2024.112998

Discrete, self-immolative <i>N</i>-substituted oligourethanes and their use as molecular tags

Author(s): Matthieu Soete; Jens Van Hoorde; Filip Du Prez
Published in: POLYMER CHEMISTRY, Issue 3, 2022, ISSN 1759-9954
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2py00630h

Debondable Epoxy-Acrylate Adhesives using β-Amino Ester Chemistry

Author(s): Tim Maiheu, Erica Laguzzi, Andrew T. Slark, Filip E. Du Prez
Published in: ACS Applied Materials &amp; Interfaces, Issue 16, 2024, Page(s) 64050-64057, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.4c15346

Reading Information Stored in Synthetic Macromolecules

Author(s): Matthieu Soete; Chiel Mertens; Nezha Badi; Filip E. Du Prez
Published in: Journal of the American Chemical Society, Issue 1, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c10316

Activated Phenyl Ester Vitrimers

Author(s): Stéphanie Engelen, Bram Daelman, Johan M. Winne, Filip E. Du Prez
Published in: Macromolecular Rapid Communications, 2024, ISSN 1022-1336
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/marc.202400790