Atomically Dispersed Heterobimetallic Catalysts for Cooperative C-H Bonds Activation

Project Information

DUO

Grant agreement ID: 101041762

DOI

10.3030/101041762

EC signature date 15 March 2022

Start date 1 November 2022

End date 31 October 2027

Funded under

• European Research Council (ERC)

Total cost

€ 1 499 826,00

EU contribution

€ 1 499 826,00

Coordinated by

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
France

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Publications

Peer reviewed articles (10)

Synthesis of Perdeuterated Pentane and THF Under Mild Conditions by Silica‐Supported Ta/M (M = Co, Ir) Heterobimetallic Catalysts

Author(s): Andrey V. Pichugov, Abdelhak Lachguar, Vincent Maurel, Serge Gambarelli, Jean‐Marie Mouesca, Laurent Veyre, Chloé Thieuleux, Clément Camp
Published in: Angewandte Chemie International Edition, Issue 65, 2026, ISSN 1433-7851
Publisher: Wiley
DOI: 10.1002/ANIE.202522721

Highly Selective and Efficient Perdeuteration of n‐Pentane via H/D Exchange Catalyzed by a Silica‐Supported Hafnium‐Iridium Bimetallic Complex

Author(s): Andrey V. Pichugov; Léon Escomel; Sébastien Lassalle; Julien Petit; Ribal Jabbour; David Gajan; Laurent Veyre; Emiliano Fonda; Anne Lesage; Chloé Thieuleux; Clément Camp
Published in: Angewandte Chemie International Edition, 2024, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/ANGE.202400992

Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations

Author(s): Zachary Dubrawski, Iker Del Rosal, Erwann Jeanneau, Laurent Maron, Chloé Thieuleux, Clément Camp
Published in: Chemical Science, 2025, ISSN 2041-6520
Publisher: Royal Society of Chemistry (RSC)
DOI: 10.1039/D5SC03465E

Cooperative activation of carbon–hydrogen bonds by heterobimetallic systems

Author(s): Abdelhak Lachguar; Andrey V. Pichugov; Till Neumann; Zachary Dubrawski; Clément Camp
Published in: Dalton Transactions, 2024, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/D3DT03571A

Visible-light driven H ₂ reductive elimination unlocks reactivity in polyhydrido niobium iridium clusters

Author(s): Zachary Dubrawski; Samy Aïssiou; Erwann Jeanneau; Chloé Thieuleux; Clément Camp
Published in: Dalton Transactions, 2026, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/D5DT02432C

Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron–Iridium Clusters

Author(s): Zachary Dubrawski, Billie Shearman, Naïme Soulé, Erwann Jeanneau, Chloé Thieuleux, Clément Camp
Published in: Organometallics, 2025, ISSN 0276-7333
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACS.ORGANOMET.5C00301

π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation

Author(s): A. Lachguar; I. Del Rosal; L. Maron; E. Jeanneau; L. Veyre; C. Thieuleux; C. Camp
Published in: Journal of the American Chemical Society, 2024, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/JACS.4C02172

Catalytic H/D exchange of (hetero)arenes with early–late polyhydride heterobimetallic complexes: impact of transition metal pairs

Author(s): Abdelhak Lachguar; Till Neumann; Andrey V. Pichugov; Erwann Jeanneau; Laurent Veyre; Chloé Thieuleux; Clément Camp
Published in: Dalton Transactions, 2025, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4DT03171G

Inorganic Chemistry

Author(s): Till Neumann; Iker Del Rosal; Laurent Maron; Erwann Jeanneau; Vincent Maurel; Serge Gambarelli; Jean-Marie Mouesca; Chloé Thieuleux; Clément Camp
Published in: Inorganic Chemistry, 2025, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/ACS.INORGCHEM.5C02380

CO2 cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Author(s): A. Lachguar; C. Z. Ye; S. Kelly; E. Jeanneau; L. Veyre; C. Thieuleux; J. Arnold*; C. Camp*
Published in: Chemical Communications, 2024, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4CC02207F