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Selective sustainable hydrodeoxygenation of bioaromatics

Objective

The depletion of fossil resources and the requirement to significantly reduce our CO2 footprint made the production of chemicals from non-edible biorenewable feedstocks an intensive contemporary research field. Remarkably, amongst the bioderived chemicals available, bioaromatics are still scarce. A typical feature of biobased platform molecules is their high oxygen content, which is in sharp contrast with current base chemicals obtained via a classical petrochemical approach. While petrochemical industry requires efficient and selective oxidation protocols, biorenewables on the other hand require the reverse, i.e. efficient and selective reduction reactions, necessitating new reaction development. Chemical and (bio)catalytic processes on biorenewable resources (e.g. wood, cloves, gallnuts) deliver a variety of oxygenated arenes (guaiacols, syringols, catechols, pyrogallols). Hydrodeoxygenation (HDO) reactions on these biobased arene building blocks can give access to functional chemicals suitable for the chemical industry. Though extensively researched, selective HDO on these oxygenated arenes is still poorly developed. Therefore, the main objective of this proposal is to develop selective HDO in catechols, guaiacols, pyrogallols, and syringols. Our approach involves sustainable activation of Ar-OH and Ar- (OH)2 with a renewable and cheap reactant, and subsequent reduction with a renewable reductant. As catalysts readily available and cheap base metals will be explored rather than scarce and expensive precious transition metals. Both homogeneous and heterogeneous catalysis will be evaluated.

Fields of science (EuroSciVoc)

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Programme(s)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) HORIZON-MSCA-2021-PF-01

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Coordinator

UNIVERSITEIT ANTWERPEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 186 304,00
Address
PRINSSTRAAT 13
2000 Antwerpen
Belgium

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Region
Vlaams Gewest Prov. Antwerpen Arr. Antwerpen
Activity type
Higher or Secondary Education Establishments
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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