Project description
A high-resolution ‘movie’ of innovative photovoltaics’ dynamics via ultrafast electron microscopy
Solar energy will play an essential role in the green energy transition. The technology exploiting it has progressed tremendously in the nearly seven decades since the first practical silicon solar cell was demonstrated. Non-centrosymmetric ferroelectric perovskites have gained considerable interest for next-generation photovoltaics, but the exact mechanisms behind their giant photovoltaic response are not known. With the support of the Marie Skłodowska-Curie Actions Programme, the SpaceTimeFerro project will harness ultrafast electron pulses in a femtosecond electron microscope for nanometre spatial and femtosecond temporal resolutions. The resulting high-resolution ‘movie’ of the evolving electromagnetic field will reveal the origin of the anomalous bulk photovoltaic effect in perovskite ferroelectric oxides.
Objective
Giant bulk photovoltaic effect in non-centrosymmetric ferroelectric materials is currently gaining tremendous research interest due to its above-bandgap photovoltage and the observed output voltage is around 3-4 orders of magnitude higher than the Si-solar cells. Hence, the ferroelectric photovoltaic response is considered the next-generation photovoltaic device. However, researchers currently lack a profound understanding of the exact mechanism of the bulk photovoltaic effect, and the proposed mechanisms are contradictory to each other. This, in turn, restricts the progress of the field towards efficient solar cells. The difficult part of finding the exact mechanism is due to ultrafast carrier dynamics and atomic relaxation times are of the order of ≈ 0.1 to 10 femtoseconds, which made it experimentally inaccessible. At present, the excellent infrastructure and facilities of my host institute dealing with the ultrafast carrier dynamics can record the meticulous dynamics in space-time resolution and hence can provide the exact mechanism towards the above bandgap photovoltage in the ferroelectric system. Therefore, through this project, we are going to investigate the origin of the anomalous bulk photovoltaic effect in perovskite ferroelectric oxides by “filming” the ultrafast photo-absorption and subsequent photo-excited carrier relaxation dynamics with femtosecond time resolution and nanometre spatial resolution using laser-driven electron microscopy. In contrast to the spectroscopic approach, ultrafast electron pulses in a femtosecond electron microscope or diffraction apparatus can provide nanometre spatial and femtosecond temporal resolutions at the same time and hence can provide a movie of evolving electromagnetic field in space and time. Based on the data generated, a comprehensive physical mechanism will be put forth, which will act as guidance for the selection and design of future ferroelectric systems for an improved photovoltaic response.
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CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences physical sciences optics microscopy
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Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)
Programme(s)
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Multi-annual funding programmes that define the EU’s priorities for research and innovation.
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HORIZON.1.2 - Marie Skłodowska-Curie Actions (MSCA)
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Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
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Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships
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Call for proposal
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(opens in new window) HORIZON-MSCA-2021-PF-01
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78464 Konstanz
Germany
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