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Atomic-layer additive manufacturing for solar cells

Project description

Additive manufacturing with atomic resolution for solar cells

Atomic-layer additive manufacturing (ALAM) will be a thing. This is the scope of the EU funded ALAMS project, namely for the prototyping of solar cells in large arrays of microdevices. ALAM concept combines the principles of additive manufacturing (3D printing) with the atomic resolution achieved by the thin coating technique of atomic layer deposition (ALD). The prototype centres around a printhead that delivers the ALD precursors to the gas phase in the vicinity of the substrate surface, with a microfluidic element delivering a lateral resolution on the order of micrometres. The project will apply the ALAM concept to this specific case study; however, the concept is valid beyond the confines of photovoltaics – possibly improving additive manufacturing and microelectromechanical systems, too.

Objective

"The ALAMS project will provide the first application of ""atomic-layer additive manufacturing"" (ALAM), namely for the prototyping of solar cells in large arrays of microdevices. The ALAM concept combines the principles of additive manufacturing (3D printing) with the atomic resolution achieved by the thin coating technique atomic layer deposition (ALD). In ALD, atomic-level control is achieved by judiciously designing the surface reaction chemistry of molecular precursors at near-room temperature for it to become self-limiting. This renders experimental use of ALD very robust to a wide range of parameter variations, since the film growth occurs in a cyclic, layer-by-layer mode. This advantage will be exploited towards 3D printing, an area of application that ALD has never been used for until we built the first ALAM prototype in November
2019. This prototype centers around a printhead that delivers the ALD precursors to the gas phase in the vicinity of the substrate surface, with a microfluidic element delivering a lateral resolution on the order of micrometers. The motion of the printhead with respect to the substrate allows the user to ‘print’ lines and structures of arbitrarily chosen geometries, whereby each pass over a given point of the substrate adds to it exactly the amount of material corresponding to one ALD monolayer, that is, a thickness typically on the order of an atom, or 0.1 nanometer (depending on the exact ALD reaction used). After developing the ALD chemistry needed for ALAM of the materials required to generate photovoltaic stacks, the ALAMS PoC project will apply it to a case study, namely the rapid prototyping of solar cell microdevices in large arrays. The ALAM concept, however, is valid beyond the confines of photovoltaic research. Its commercial potential stems from its position at the convergence of two highly modern, fast-growing markets, namely, additive manufacturing ('3D printing') and microelectromechanical systems (MEMS)."

Keywords

Host institution

FRIEDRICH-ALEXANDER-UNIVERSITAET ERLANGEN-NUERNBERG
Net EU contribution
€ 150 000,00
Address
SCHLOSSPLATZ 4
91054 Erlangen
Germany

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Region
Bayern Mittelfranken Erlangen, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data

Beneficiaries (1)