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Enhanced Biomass Valorisation by Engineering of Polyoxometalate Catalysts

Project description

A new way to turn waste into valuable products

Biogenic waste can be converted into useful products such as fuels and chemicals. Funded by the European Research Council, the BioValCat project aims to revolutionise this process. Using renewable feedstocks like plant matter and agricultural waste, it will convert biogenic waste into fuels and chemicals while reducing environmental impact. Based on a recent discovery that polyoxometalate (POM) catalysts can be manipulated to enhance efficiency and yield, the project aims to develop a scalable, safe and economic process for the oxidation of biomass to valuable carboxylic acid esters. By using methanol as a (co)solvent, the POM catalysts suppress undesired total oxidation to CO2 under oxidative conditions. BioValCat has the potential to create a circular economy and contribute to a more sustainable future.

Objective

This project builds on a recent and ground-breaking discovery of the PI in the field of homogeneously catalysed, selective biomass valorisation. Materials technologies that promise improved catalytic performance are of utmost interest for a more sustainable chemical industry. Manipulating molecular catalysts like polyoxometalates (POM) in solution by tuning the solvent properties and gas atmospheres introduces a new paradigm in homogeneous-catalysed biomass valorisation technologies.
It has been found that by using methanol as a (co)solvent, POM catalysts can completely suppress undesired total oxidation to CO2 under oxidative conditions. This drastically enhances the carbon efficiency from biomass to close to 100% yield. Remarkably, this manipulating effect could be explained with the formation of a new vanadyl-methanolate-complex in methanol-aqueous solutions having a methanol content of at least 10%.
The proposed BioValCat project aims for developing this potentially disruptive technology towards an industrial viable biomass valorisation process by laying the foundations for a scalable, safe and economic process for the oxidation of biomass to valuable carboxylic acid esters. The project is structured according to the key challenges that have to be mastered in order to achieve this ambitious goal: a) Investigations to identify the nature of the POM-solvent interactions; b) Understanding and revealing the key organic mechanisms in solution; c) Development of novel POM catalysts specifically optimised to perform in aqueous-alcoholic solvent mixtures; d) Extension of the substrate and product scope to industrially viable biomass feedstock; e) Process development, with special emphasis on safety aspects, process intensification as well as product isolation and catalyst recovery.
With the proposed project the PI aims for paving the scientific route to novel, low-cost biomass utilisation technologies with great promise for decentralised valorisation of biogenic waste.

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Topic(s)

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Call for proposal

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(opens in new window) ERC-2022-COG

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Host institution

UNIVERSITY OF HAMBURG
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 996 625,00
Address
MITTELWEG 177
20148 Hamburg
Germany

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Region
Hamburg Hamburg Hamburg
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 996 625,00

Beneficiaries (1)

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