Carbanions as Functional Groups and Building Blocks for Novel Reagents, Catalysts and Materials

Project Information

CarbFunction

Grant agreement ID: 101086951

DOI

10.3030/101086951

EC signature date 23 February 2023

Start date 1 July 2023

End date 30 June 2028

Funded under

• European Research Council (ERC)

Total cost

€ 2 000 000,00

EU contribution

€ 2 000 000,00

Coordinated by

RUHR-UNIVERSITAET BOCHUM
Germany

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Other (2)

Ligand Exchange at Carbon: Synthetic Entry to Elusive Species and Versatile Reagents

Author(s): Felix Krischer; Viktoria H. Gessner
Published in: JACS Au, 2024
Publisher: ACS
DOI: 10.1021/jacsau.4c00112

Phosphinoyl-Substituted Ketenyl Anions: Synthesis and Substituent Effects on the Structural Properties

Author(s): Mike Jörges; Sunita Mondal; Manoj Kumar; Prakash Duari; Felix Krischer; Julian Löffler; Viktoria H. Gessner
Published in: Organometallics, 2024
DOI: 10.1021/acs.organomet.3c00530

Peer reviewed articles (10)

The Cyanoketene Anion [NC3O]-

Author(s): Felix Krischer; Varre S. V. S. N. Swamy; Kai-Stephan Feichtner; Robert J. Ward; Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, 2024, ISSN 1521-3773
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ANIE.202403766

Harnessing Organopotassium Reagents for Cross-Coupling with YPhos-Pd Catalysts: Opportunities, Applications, and Challenges

Author(s): Daniel Knyszek, Julian Löffler, David E. Anderson, Eva Hevia, Viktoria H. Gessner
Published in: Journal of the American Chemical Society, 2025, ISSN 1520-5126
Publisher: American Chemical Society (ACS)
DOI: 10.1021/JACS.4C18073

Isolation and Structure Elucidation of the Heterocumulene Anions [NCC-L]− (L=CO, CS, N2)

Author(s): Quentin Le Dé, Yihao Zhang, Lili Zhao, Felix Krischer, Kai-Stephan Feichtner, Gernot Frenking, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, 2025, ISSN 1521-3773
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ANIE.202422496

Base-stabilized acyclic amino(ylidyl)silylenes: electron-rich donors for the stabilization of silicon-element multiple bonds

Author(s): Felix Krischer; Stephan Mayer; Lennart Hensle; Daniel Knyszek; Heidar Darmandeh; Viktoria H. Gessner
Published in: Chemical Science, 2025, ISSN 2041-6539
Publisher: The Royal Society of Chemistry
DOI: 10.1039/D5SC01812A

Increasing the Donor Strength of Alkenylphosphines by Twisting the C=C Double Bond

Author(s): Cheng‐Han Yu, Yu‐Wen Hsiao, Julian Löffler, Nicolas Kaiser, Bo‐Hong Huang, Chao‐Hsien Lee, Chen‐Hsun Hung, Jiun‐Shian Shen, Glenn P. A. Yap, Viktoria H. Gessner, Tiow‐Gan Ong
Published in: Angewandte Chemie International Edition, Issue 64, 2025, ISSN 1433-7851
Publisher: Wiley
DOI: 10.1002/ANIE.202416764

Carbon-Based Weakly Coordinating Anions: Molecular Design, Synthesis and Applications

Author(s): Leif Kelling, Julian Eßer, Daniel Knyszek, Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, 2024, ISSN 1521-3773
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ANIE.202405936

Rethinking carbanion chemistry from donor substituents to weakly coordinating carbanions

Author(s): Arpan Das; Quentin Le Dé; Viktoria H. Gessner
Published in: Nature Reviews Chemistry, 2025, ISSN 2397-3358
Publisher: Springer Nature
DOI: 10.1038/S41570-025-00725-3

Impact of the Substitution Pattern in N–heterocyclic Olefin-Substituted Phosphines on Palladium Catalysis

Author(s): Nicolas Kaiser, Aya Alhaddad, Julian Löffler, Viktoria H. Gessner
Published in: Advanced Synthesis & Catalysis, 2025, ISSN 1615-4169
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ADSC.202500270

Coordination chemistry of a weakly coordinating carbanion

Author(s): Leif Kelling, Viktoria H. Gessner
Published in: Polyhedron, 2024, ISSN 1873-3719
Publisher: Elsevier Ltd.
DOI: 10.1016/J.POLY.2024.117283

PPh3/Isocyanide and N2/Isocyanide Exchange: Pathways to Isolable Alkali Metal Keteniminyl Anions

Author(s): Sunita Mondal; Yihao Zhang; Kai-Stephan Feichtner; Arpan Das; Lili Zhao; Gernot Frenking; Viktoria H. Gessner
Published in: Angewandte Chemie International Edition, 2025, ISSN 1521-3773
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ANIE.202504325