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RoHS compliant, high luminescence, heterostructure nanocrystals for near infrared LEDs and bioimaging.

Objective

Colloidal nanocrystals (NCs) that absorb and emit in the near-infrared (NIR) region are of paramount importance in the field of optoelectronics (LEDs, LASERs, solar cells, telecommunication) and biological imaging. However, most of the NIR emitting NCs are based on heavy metals (Pb, Cd, Hg) which are highly toxic and are restricted from widespread use by the European regularity concerns. Therefore, the development of NIR emitting environmentally friendly (Cd/Pb/Hg- free) NCs are of interest. NIRLUMIN proposes a strategy to develop high NIR (1-1.35um) luminescent, stable AInTe2/(Ga/In)2S3/Zn(S/Se) core/shell/shell (CSS) NC heterostructures with controlled bandgap and size in which the outer shells will protect the surface of the core and enhance the photoluminescence quantum yield by passivating the dangling bonds and surface traps while the intermediate layer will stop diffusion to prevent the undesirable bandgap enhancement. Further, the advantages of these NCs will be directly translated into device performance in the LED. For biological imaging, these nanostructures will be over-coated with a ceramic-type alumina shell and transferred to the aqueous phase. The whole work will be conducted in five major steps. (i) Synthesis of CSS NCs, characterization and study of their structural and photophysical properties (ii) Surface functionalization to investigate the surface ligand chemistry on their optical and electrical properties and to make the NCs compatible for devices and bio-application (iii) Cytotoxicity study and bio-imaging using the Alumina coated NCs. (iv) Optoelectronic characterization, to understand the optical and electronic characteristics of the NCs on film. Finally (v) fabrication of LED using these NCs as an active layer and optimization to achieve an efficient NIR emission.

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Keywords

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Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2022-PF-01

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Coordinator

TECHNISCHE UNIVERSITAET DRESDEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 189 687,36
Address
HELMHOLTZSTRASSE 10
01069 DRESDEN
Germany

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Region
Sachsen Dresden Dresden, Kreisfreie Stadt
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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