Paramagnetic Materials Studied by ultra-fast ssNMR Spectroscopy

Información del proyecto

ParaMAS

Identificador del acuerdo de subvención: 101111472

DOI

10.3030/101111472

Proyecto cerrado

Fecha de la firma de la CE 19 Julio 2023

Fecha de inicio 1 Septiembre 2023

Fecha de finalización 31 Agosto 2025

Financiado con arreglo a

• Marie Skłodowska-Curie Actions (MSCA)

Coste total

Sin datos

Aportación de la UE

€ 211 754,88

Coordinado por

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
France

Periodic Reporting for period 1 - ParaMAS (Paramagnetic Materials Studied by ultra-fast ssNMR Spectroscopy)

Período documentado: 2023-09-01 hasta 2025-08-31

Resumen del contexto y de los objetivos generales del proyecto

Materials containing paramagnetic transition-metal ions are crucial for modern technologies involving energy transport, storage, and conversion. While these paramagnetic ions strongly impact material performance, studying their exact local structure and geometry is notoriously difficult, with conventional structural techniques often failing to provide atomic-scale insights.
The ParaMAS project aims to develop and apply new solid-state nuclear magnetic resonance (NMR) methods under ultra-fast magic-angle spinning (MAS), enabling the characterization of nuclei in close proximity to paramagnetic ions. The NMR signals of such nuclei encode very detailed local structural information about the paramagnetic ions, and as such provide the missing atomic-scale structural information needed to link the local environment to the functional properties of energy-relevant materials-

Trabajo realizado desde el comienzo del proyecto hasta el final del período abarcado por el informe y los principales resultados hasta la fecha

During the two-year project, ParaMAS designed and optimized amplitude- and frequency-modulated radiofrequency pulses tailored to allow for broadband inversion at very short irradiation times. This has been instrumental to fully leverage the advantages that are offered by ultra-fast MAS and exploit its full potential in paramagnetic NMR, as well as offsetting the sensitivity penalty due to the small active rotor volumes. This, in combination with MAS at 160 kHz, has amongst others produced the first high-resolution 19F NMR spectrum of F atoms directly bonded to a paramagnetic Fe3+ centre in anti-ferromagnetic FeF3. Furthermore, these pulses were integrated in two-dimensional magic-angle turning experiments, that has allowed us to observe and resolve 1H signals in organo-metallic catalysts, neither of which were possible previously.
In addition to that, the deeper understanding developed for broadband excitation concepts has resulted in exciting new insights in the related field of Pt single-atom catalysts.

Avances que van más allá del estado de la técnica e impacto potencial esperado (incluida la repercusión socioeconómica y las implicaciones sociales más amplias del proyecto hasta la fecha)

Prior to ParaMAS, solid-state NMR studies of nuclei in very close proximity to paramagnetic centres were considered practically impossible. The project demonstrated that high-resolution solid-state NMR data for such sites can be obtained using ultra-fast MAS combined with advanced rf-pulse designs.
This moves the boundaries of detectability in NMR spectroscopy, offering a toolbox for the structural characterization of paramagnetic materials, in particular with high paramagnetic-ion density. The methods will not only impact battery and catalyst research but also benefit a wide range of fields, from solid-state chemistry to materials physics by enabling structural insights into systems previously out of reach.