Excited-state antiaromaticity relief in photoactive amine–boranes promotes transfer hydrogenation to electron-poor olefins
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Author(s):
Enrique M. Arpa
Published in:
Physical Chemistry Chemical Physics, Issue 27, 2025, ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
DOI:
10.1039/D5CP02226F
Importance of Polar Effects in Halogen-Atom Transfer from Alkyl Iodides to α-Aminoalkyl Radicals. A Kinetic and Computational Evaluation of the Role of Structural and Medium Effects
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Author(s):
Jacopo Mancini, Chiara Stavagna, Francesco Pileri, Giovanni Lonardi, Enrique M. Arpa, Marco Galeotti, Sergio Sisti, Fabio Juliá, Michela Salamone, Daniele Leonori, Massimo Bietti
Published in:
JACS Au, Issue 6, 2026, ISSN 2691-3704
Publisher:
American Chemical Society (ACS)
DOI:
10.1021/JACSAU.5C00920
Excited-state configuration controls the ability of nitroarenes to act as energy transfer catalysts
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Author(s):
Martin Rihtaršič, Byeongseok Kweon, Piotr T. Błyszczyk, Alessandro Ruffoni, Enrique M. Arpa, Daniele Leonori
Published in:
Nature Catalysis, Issue 8, 2025, ISSN 2520-1158
Publisher:
Springer Science and Business Media LLC
DOI:
10.1038/S41929-025-01453-Z
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes
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Author(s):
Javier Corpas, Eva Rivera-Chao, Enrique M. Arpa, Miguel Gomez-Mendoza, Yuri Katayama, Victor A. de la Peña O’Shea, Céline Bouchel, Clément Jacob, Pierre-Georges Echeverria, Alessandro Ruffoni, Daniele Leonori
Published in:
Chem, Issue 11, 2025, ISSN 2451-9294
Publisher:
Elsevier BV
DOI:
10.1016/J.CHEMPR.2024.10.009
Excited-state configuration of nitroarenes enables oxidative cleavage of aromatics over alkenes
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Author(s):
Wesley J. Olivier, Piotr Błyszczyk, Enrique M. Arpa, Kenshiro Hitoshio, Miguel Gomez-Mendoza, Víctor de la Peña O’Shea, Isabelle Marchand, Thomas Poisson, Alessandro Ruffoni, Daniele Leonori
Published in:
Science, Issue 387, 2025, ISSN 0036-8075
Publisher:
American Association for the Advancement of Science (AAAS)
DOI:
10.1126/SCIENCE.ADS3955
Photochemical permutation of meta-substituted phenols
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Author(s):
Maialen Alonso, Giovanni Lonardi, Enrique M. Arpa, Baptiste Roure, Alessandro Ruffoni, Daniele Leonori
Published in:
Nature Communications, Issue 16, 2025, ISSN 2041-1723
Publisher:
Springer Science and Business Media LLC
DOI:
10.1038/S41467-025-62549-5