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A perovskite sustainable photovoltaic system based on device healing and recycling.

Project description

Self-healing solar cells for a sustainable future

Climatic challenges demand a timely shift to carbon-free energy. However, relying solely on current solar technologies risks creating an e-waste crisis due to limited reparability and recyclability. With this in mind, the ERC-funded PhoenixPV project focuses on metal halide perovskite (HaP) solar cells, which match commercial performance but suffer from instability and hazardous by-products. The project turns these drawbacks into advantages by designing self-healing cells that can reverse damage and safely capture toxins. Using high-throughput ageing tests and real-time monitoring, it aims to slow degradation and restore solar cell performance. This approach has the goal of extending HaP solar cells’ lifespan and pave the way for repairable photovoltaic systems.

Objective

PhoenixPV aims to develop a sustainable, reparable photovoltaic system using metal halide perovskites (HaP). Climatic challenges require an urgent abrupt growth of carbon-free energy sources, which will unlikely be sustainable if it is solely based on present photovoltaic systems. Their limited reparability and recyclability threaten a mid-term e-waste problem that will damage the environment and menace their social implementation, restraining overall sustainability. While HaP solar cells have demonstrated performance matching the best commercial counterparts, their stability is compromised due to their ionic and chemically dynamic nature, which also leads to potentially hazardous by-products.

Our approach will use these drawbacks in our favor. The chemically dynamic nature, rooted in a low formation energy and ionic properties, can be used as leverage to design intrinsic self-healing strategies and extrinsic post-synthetic treatments, reversing degradation defects and restoring initial performance. Concurrently, these properties will be used to capture the toxic by-products in case of operational accidents and design material separation methods for efficient and safe end-of-life recycling.
PhoenixPV will elucidate the reversible and irreversible reactions using a high-throughput aging characterization system that enables the parallel evaluation of a large number of devices under independently controlled degradation stressors. Beyond conventional efficiency, the system will integrate in-operando characterization techniques such as impedance spectroscopy, to monitor device health and design the necessary healing actions.

While current research aims to slow degradation routes, PhoenixPV seeks to reverse them, extending the effective lifetime of HaP solar cells, reducing associated waste, and establishing a sustainable photovoltaic system. This project holds the key to accelerating HaP commercialization through the design of innovative photovoltaic usage schemes.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

(opens in new window) ERC-2024-COG

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Host institution

AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS
Net EU contribution
€ 2 271 091,00
Address
CALLE SERRANO 117
28006 Madrid
Spain
Region
Comunidad de Madrid Comunidad de Madrid Madrid
Activity type
Research Organisations
Links
Total cost
€ 2 271 091,00

Beneficiaries (1)