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BIOinspired photocatalytic POLymersomes for compartmentalized solar Energy conversion

Project description

A green blueprint for turning sunlight into fuel

For decades, scientists have tried to mimic plants by using sunlight, water and carbon dioxide to create clean fuel. While this ‘artificial photosynthesis’ approach is a brilliant idea, it has been difficult to master because most photocatalytic systems are inefficient and struggle to control the complex chemical reactions required to make it work. The ERC-funded BIOPOLE project is taking a new approach, inspired by the internal structure of chloroplast in photosynthetic organisms. Instead of a single large reaction space, it uses tiny polymer shells (miniature reactors) to separate different parts of the process. By carefully arranging these components, BIOPOLE can guide electrons and reactions with much higher precision. This process promises to turn sunlight into sustainable fuels and chemicals.

Objective

The transition to sustainable fuel and chemical production using renewable energy sources is paramount to curb CO2 emissions and decrease reliance on fossil fuels. In this context, artificial photosynthesis (AP) offers a promising approach to mimic natural photosynthesis (NP) to store solar energy into chemical bonds, driving the conversion of water and CO2 into renewable products. However, current photocatalytic AP systems are constrained by low efficiency, limited product selectivity, specially going beyond the 2 electron CO2 reduction, and poor control of cross-reactivity in solution.

BIOPOLE introduces an innovative compartmentalized approach to AP by mimicking the spatial layout of thylakoid membranes -which separate oxidation and reduction reactions to minimize cross-reactivity- arranging catalysts, photosensitizers and mediators across artificial membranes. Using polymeric vesicles (polymersomes) as bioinspired photocatalytic microreactors BIOPOLE will compartmentalize redox chemistry to ultimately drive the electrons from the oxidation of water to reduce CO2, offering an efficient and stable platform for solar fuel and chemical production. This project aspires to address key challenges in AP, developing novel advanced photocatalytic polymersomes with controlled membrane properties and functionalization, achieving precise separation of reaction centres, enhanced charge separation, and efficient solar-to-fuel conversion. Using photocatalytic polymersomes as simplified models of natural thylakoids to produce solar fuels and chemicals harnessing light as driving force, BIOPOLE will contribute to the understanding of reactivity at the aqueous interface of polymeric membranes and electron/proton transfer between compartments. Ultimately, BIOPOLE’s unique bioinspired polymersome-based approach promises to advance the design and conceptual development of artificial photosynthetic systems and provide a transformative platform for sustainable fuel production.

Fields of science (EuroSciVoc)

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Keywords

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Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

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(opens in new window) ERC-2025-STG

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Host institution

UNIVERSITAT ROVIRA I VIRGILI
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 1 499 998,00
Address
CARRER DE ESCORXADOR
43003 TARRAGONA
Spain

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Region
Este Cataluña Tarragona
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 1 499 998,00

Beneficiaries (1)

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