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500 million years of ocean pH and atmospheric CO2

Project description

Tracing CO2 through time by reconstructing Earth’s climate

As a vital greenhouse gas, CO2 influences climate and ocean acidity. This is crucial for Earth’s habitability. Present levels of 420 ppm, unseen for 3 million years, prompt questions about historical norms. The ERC-funded CarbonDIOs project aims to answer these questions by reconstructing ocean pH and atmospheric CO2 over 500 million years, from early complex life onward. Specifically, the project will use advances in geochemistry and employ boron isotope composition analysis of fossil shells to determine past ocean pH and atmospheric CO2. New techniques will estimate historical boron isotope composition and correct biological imprints. This research promises to unveil a comprehensive record of CO2’s impact, offering insights into its historical and future role in Earth’s climate system.

Objective

CO2 is an important greenhouse gas and building block for life. It plays a major role in regulating Earth's environment, maintaining planetary habitability, and influencing both ocean acidity and global climate. Anthropogenic carbon emissions have raised CO2 levels to their current concentration of 420 ppm, last seen 3 million years ago. Is this high? Was Pre-Industrial CO2 low? If we want to place CO2 changes in context and understand how Earth’s environment and climate will respond to changing CO2, we need to look into Earth’s geological past. My project provides a novel way to reconstruct ocean pH and atmospheric CO2 over the last 500 million years, from the dawn of complex multi-cellular life. This will permit us to quantify pH and CO2 during key periods of Earth's history, providing fundamental insights into CO2’s past and future role in driving climate, environment and life on our planet.
The CO2 molecule is acidic and freely exchanges between the ocean and atmosphere, resulting in a close coupling of ocean pH and atmospheric CO2. If ocean pH is known, atmospheric CO2 can be reconstructed. Recent advances in geochemistry make it possible to constrain pH from the boron isotope composition (δ11B) of fossil shells. The principles of this pH-meter are well-understood and rooted in the laws of thermodynamics. However, to calculate pH from fossil δ11B, two parameters are needed: (i) knowledge of boron isotope composition of seawater (δ11Bsw) and (ii) organisms’ biological imprint on δ11B (‘vital effects’). Here, I propose novel approaches to reconstruct past δ11Bsw from fluid inclusions and apatite, and to calibrate vital effects on ‘living fossils’. Armed with this knowledge, and aided by advanced robotics and computation, I will create an iconic 500-million-year record of ocean pH and atmospheric CO2 from fossil brachiopods. This will provide a step change in our understanding of CO2 and its role in Earth’s climate and habitability, past, present and future.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

(opens in new window) ERC-2025-STG

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Host institution

THE UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS
Net EU contribution
€ 2 497 282,00
Address
NORTH STREET 66 COLLEGE GATE
KY16 9AJ ST ANDREWS
United Kingdom
Region
Scotland Eastern Scotland Clackmannanshire and Fife
Activity type
Higher or Secondary Education Establishments
Links
Total cost
€ 2 497 282,00

Beneficiaries (1)