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Ultrafast broadband sensitive magneto-chiroptical microscopy to track the consequences of symmetry breaking in solution-processable semiconductors

Project description

Advancing chiral semiconductors for next-generation electronics

Chiral solution-processable semiconductors, a new class of materials that enable circularly polarised light (CPL) emission and spin control at room temperature without magnetic fields, could transform optoelectronics. However, progress is limited by the lack of methods to study the mechanisms behind this technology. The ERC-funded MACHIRO project aims to develop a revolutionary ultrafast broadband magneto-chiroptical microscope to map the Stokes vector of light polarisation emitted by chiral materials with diffraction-limited spatial and femtosecond temporal resolution. This solution will allow for direct and accurate tracking of key mechanisms and processes, provide universal design rules for this field, and pave the way for discovering a vast range of insights across various fields and sectors.

Objective

Chiral solution-processable semiconductors are a new class of materials that could revolutionize optoelectronics by enabling circularly polarized light (CPL) emission and spin control without external magnetic fields at room temperature. This could enhance the efficiency of displays, solar cells, holography, cryptography, and biomedical imaging, while opening new possibilities in quantum information processing. However, current trial-and-error approaches, limited by the absence of suitable techniques to probe mechanisms, prevent systematic breakthroughs in designing chiral materials with strong CPL emission and spin polarization.

MACHIRO will overcome these limitations. We will develop the first ultrafast broadband magneto-chiroptical microscope to map the Stokes vector of light polarization emitted from chiral materials with diffraction-limited spatial and femtosecond-temporal resolution. This will enable us to directly track the interplay between charge, spin, and light polarization in time and space, to mechanistically understand how CPL and spin polarization arise from structural chirality imprint on the excited state.

We will use this new tool to study a range of i) heavy-element containing chiral halide perovskite semiconductors, as well as ii) purely molecular twisted materials with much less spin orbit coupling. We will systematically vary dimensionality (3D bulk to 0D quantum dots), hierarchical level of chirality, helical pitch and addition magnetic impurities, while always monitoring the role of local disorder through mapping. Thus, we will identify dominant loss channels and arrive at a unified mechanism of how light and spin polarization are connected.

Finally, we will integrate insights across all materials, establishing universal design rules for using chirality to control spin and light simultaneously, enabling next-generation solution-processable spin-optoelectronic technologies with unprecedented energy efficiency.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

(opens in new window) ERC-2025-STG

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Host institution

ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE
Net EU contribution
€ 2 173 004,00
Address
BATIMENT CE 3316 STATION 1
1015 Lausanne
Switzerland
Region
Schweiz/Suisse/Svizzera Région lémanique Vaud
Activity type
Higher or Secondary Education Establishments
Links
Total cost
€ 2 173 060,00

Beneficiaries (1)