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Metallic Thermoelectrics: High Thermoelectric Performance through Tuning of Electronic Scattering

Project description

Rethinking thermoelectric materials

Thermoelectric materials can turn heat directly into electricity and thus provide very promising solutions for energy generation and refrigeration. However, current thermoelectric semiconductors find limited real-world applications as they suffer from low power output and poor mechanical stability. The ERC-funded METHEL project proposes a different approach that exploits metals as thermoelectric materials, despite their traditionally weak thermoelectric response. Researchers plan to increase the thermoelectric efficiency of metals by precisely tuning how electrons scatter between energy bands, a mechanism largely unexplored so far. Scientists will improve performance by using widely available materials and controlling how electric charges move through them. This approach could lead to more robust and efficient thermoelectric devices, opening new possibilities for future energy and cooling technologies.

Objective

Thermoelectric (TE) materials directly transform thermal into electrical energy and vice versa, making them promising for a plethora of applications in refrigeration or power generation. However, state-of-the-art semiconductors in the focus of current research did not make the leap into broad applications due to low power density and poor mechanical properties. Metallic systems would be superior in this regard, but remained largely neglected by the TE community over the past decades due to their small TE effect.

This fundamental research project focuses on realizing high TE performance in metals via tuning of electronic interband scattering – an innovative enhancement principle cardinally different from those applied so far in semiconductors. Using this paradigm, we want to realize
- unprecedented TE power factors
- metallic TE with superior functional properties from highly abundant, cheap materials
- tight control of energy-dependent electronic transport by scattering off topological flat bands

Despite enormous efforts for decades, largely focusing on a reduction of thermal conductivity in semiconductors, these intriguing research issues remain unsolved calling for a novel concept.

We tackle these issues by focusing on metals, where the lattice thermal conductivity is irrelevant compared to the electronic contribution (Wiedemann-Franz law), thus confining the multi-parameter optimization problem to a sole enhancement of the Seebeck coefficient S. The latter we achieve by selectively reducing the mobility of holes (or electronic carriers) by interband scattering from localized states, leveraged by tuning of electronic bandwidth and geometrical frustration – concepts introduced from correlated electron physics. Promoted by the PI’s versatile expertise in studying charge transport in solids, METHEL explores high-performance metallic TE by the synergistic combination of synthesis, spectroscopy, microscopy and high-throughput computational materials screening.

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Topic(s)

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Funding Scheme

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HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

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(opens in new window) ERC-2025-COG

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Host institution

TECHNISCHE UNIVERSITAET WIEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 2 960 146,00
Address
KARLSPLATZ 13
1040 Wien
Austria

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Region
Ostösterreich Wien Wien
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 2 960 146,00

Beneficiaries (1)

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