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High-Throughput Co-Design of Catalysts and Organic Electrolytes for CO2-to-C2H4 Electrosynthesis

Objective

HTCo-Des will develop a systematic high-throughput (HT) platform to co-design non-aqueous electrolyte microenvironments and Cu-based high-entropy electrocatalysts (HEEs) for CO2-to-C2H4 conversion in parallel membrane-electrode-assembly (MEA) cells. The integrated HT workflow will accelerate discovery cycles, enforce standardisation and calibration, and minimise human bias through automation, generating reproducible, uncertainty-quantified structure-property maps of solvent/proton-donor-mediated interfacial effects to guide rational Cu-based HEEs design. The project will deliver the first quantitative design rules linking solvent-proton-donor chemistry and alloy composition to *CO coverage, *OCCO stabilisation, hydrogenation kinetics, and suppression of the hydrogen evolution reaction (HER). Factorial experiments will yield kinetic fingerprints (Tafel slopes, apparent activation energies, reaction orders) and degradation maps from accelerated stress tests, enabling predictive control of selectivity and durability. Complementary ex-situ and in-situ studies, together with rigorous electrochemical benchmarking, will establish electronic-structure/structure-property relationships that explain why specific HEEs and microenvironments favour C-C coupling. Under optimised conditions we target ≥85% faradaic efficiency to C2H4 and ≥100 mA cm-2 C2H4 partial current density sustained for ≥150 h, with ≤10% loss in C2H4 FE and ≤100 mV rise in cell voltage. These outcomes will advance CO2 electrolysis performance, bringing the technology closer to practical deployment and supporting decarbonisation of the chemical industry.

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Programme(s)

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Topic(s)

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 260 347,92
Address
SOUTH KENSINGTON CAMPUS EXHIBITION ROAD
SW7 2AZ London
United Kingdom

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Region
London Inner London — West Westminster
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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