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Total synthesis of Cacospongionolide

Objective

Marine natural products have long served as a rich source of bioactive compounds, inspiring the discovery of anti-inflammatory and cytotoxic drugs. The pharmaceutical success of of different marine-derived metabolites such as ziconotide, trabectedin, and lurbinectedin, together with many others ongoing clinical trials, underscores the potential of marine scaffolds in drug development. Within this context, the Cacospongionolide family of marine sesterterpenoids is particularly attractive due to its unique molecular framework and promising cytotoxic and anti-inflammatory properties. However, sustainable access to these rare metabolites remains a major bottleneck, reinforcing the importance of innovative synthetic approaches. Pd-PHOTOMARINE addresses the total synthesis of this marine metabolite through two key innovations: (1) a novel Pd-catalyzed C–H activation strategy for the construction of the sterically congested decalin fragment, and (2) a photoredox-mediated Giese-type addition for the late-stage coupling of the eastern and western fragments. Together, these methodologies provide scalable and versatile solutions to long-standing synthetic hurdles, offering a platform applicable to other complex natural products.
The complementary expertise of the host group, led by Prof. Olivier Baudoin in Pd-catalyzed C–H activation, and of Dr. Matteo Balletti in photocatalysis and visible-light radical chemistry, creates a highly synergistic framework for collaboration. This integration of skills not only secures the feasibility of the project and enhances its innovative potential, but also maximizes the reciprocal transfer of knowledge between both parties.

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Topic(s)

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

UNIVERSITAT BASEL
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 292 118,88
Address
PETERSPLATZ 1
4051 Basel
Switzerland

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Region
Schweiz/Suisse/Svizzera Nordwestschweiz Basel-Stadt
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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