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Synthesis of Novel Oxide Materials

Project description

Rational design of novel metastable nickel-oxygen thin films

Oxygen-intercalated and highly oxidised layered nickelates are a new family of materials realised through the topochemical oxidation of a special type of nickelate thin films. These metastable compounds are promising for high-temperature superconductivity and energy applications. With the support of the Marie Skłodowska-Curie Actions programme, the SONOMA project aims to employ topochemical oxidation with ozone and other soft chemical methods to stabilise nickelates in unusually high oxidation states. At the interface between solid-state chemistry and thin-film physics, SONOMA will then characterise the structural and electronic properties of these nickel-oxygen materials at extreme valences. Resulting insights could support rational design and lay the groundwork for applications in superconductivity, catalysis and ion-based electronics.

Objective

This project will pioneer new synthetic strategies to access oxygen-intercalated and highly oxidized layered nickelates, a class of metastable compounds with strong potential for high-temperature superconductivity and energy applications. Building on my expertise in thin-film synthesis and advanced characterization, I will employ topochemical oxidation with ozone and complementary soft-chemical methods to stabilize nickelates in unusually high oxidation states. Structural and electronic properties will be mapped using state-of-the-art diffraction, spectroscopy, and transport techniques, advancing fundamental understanding of correlated electron systems. The fellowship will be hosted at the University of Oxford under the supervision of Prof. Michael Hayward, an international leader in soft-chemistry synthesis, ensuring a strong two-way transfer of knowledge between solid-state chemistry and thin-film physics. The project will deliver new scientific insights into nickel–oxygen hybridization at extreme valences, expand the design principles for metastable oxides, and open pathways for applications in superconductivity, catalysis, and ion-based electronics. Results will be disseminated through high-impact publications, international conferences, and open-science practices. The fellowship will also enhance my career development through interdisciplinary training, mentoring, and leadership opportunities, positioning me as a leading independent researcher at the interface of physics, chemistry, and materials science.

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Topic(s)

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF OXFORD
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 260 347,92
Address
WELLINGTON SQUARE UNIVERSITY OFFICES
OX1 2JD Oxford
United Kingdom

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Region
South East (England) Berkshire, Buckinghamshire and Oxfordshire Oxfordshire
Activity type
Higher or Secondary Education Establishments
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Total cost

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