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Switchable Coacervate Adhesives to Engineer Coating Adhesion and Release

Project description

Breaking barriers in sustainable adhesion

Traditional coatings often face a difficult trade-off between adhesion and removability: they are either easy to peel but too weak, or permanently bonded and require toxic, destructive processes to remove, preventing effective recycling. Supported by the Marie Skłodowska-Curie Actions programme, the SWITCHCOAT project aims to address this by developing a dual-layer system with ‘switchable’ adhesive strength. By using a specialised coacervate adhesive layer protected by a liquid-repellent top coat, the system will provide strong bonding during use and allow easy release through controlled dehydration. Beyond engineering these layers, the project will use advanced microscopy to elucidate the molecular interactions underpinning this performance. Ultimately, SWITCHCOAT seeks to enable recyclable substrates and reduce environmental impacts across diverse industries, including biomedicine.

Objective

Conventional coatings face a fundamental trade-off between adhesion and removability: peelable layers sacrifice bonding strength, while coatings with permanent adhesion require toxic, costly, or destructive removal processes. This limitation not only hinders substrate recyclability but also increases environmental impact and processing costs.
The SWITCHCOAT project aim to break this barrier by developing a dual-layer coating system with switchable adhesive strength using a novel coacervate adhesive layer that is strongly anchored to substrates. The coacervate adhesive layer design will allow debonding through dehydration and include a top liquid-repellent layer (LRC) that both protects the coacervate layer and provides functionality. I will focus the coacervate layer design with a tailored affinity linked to LRC and both for hydrophobic and hydrophilic substrates. Interfacial adhesion between the substrate, coacervate, and LRC layers will be quantitatively measured using Scanning Droplet Adhesion Microscopy (SDAM), which allows both force measurements and visualization of interface dynamics during bonding and debonding. Complementary Photo-Induced Force IR spectroscopy (PiF-IR) will provide spatially resolved and molecular-level insights into interfacial interactions. I will then evaluate the physicochemical stability. Finally, I will explore the controlled dehydration condition for on-demand removal.
The anticipated outcome of SWITCHCOAT is a sustainable coating technology capable of delivering strong bonding during use (>10 J/m²) while allowing on-demand debonding (<1 J/m²). This innovation enables recyclable substrates, reduces environmental impact, and advances high-performance coating applications across diverse industries (e.g. biomedicine), while providing a mechanistic understanding of multilayer adhesion by linking molecular-scale interactions to macroscopic adhesion. It has broad relevance to soft materials, surface and interfacial science.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-MSCA-2025-PF

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Coordinator

AALTO KORKEAKOULUSAATIO SR
Net EU contribution
€ 226 276,80
Address
OTAKAARI 1
02150 Espoo
Finland
Region
Manner-Suomi Helsinki-Uusimaa Helsinki-Uusimaa
Activity type
Higher or Secondary Education Establishments
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Total cost
No data