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Innovative Process Loops and Materials for Electrified Brine Valorization

Objective

Desalination brines are usually discarded or treated using costly, chemical- and energy-intensive methods, leading to loss of critical metals and high emissions. BrinE-Loop introduces an electrified, closed-loop system that generates its own reagents for brine treatment, minimizing external chemical use. For the first time, this project will also demonstrate the use of desalination brine as a reagent to selectively recover lithium from battery black mass containing lithium iron phosphate (LFP).

BrinE-Loop integrates interoperable electrochemical processes that treat brine as a resource. Electrodialysis with monovalent-selective membranes separates divalent- and monovalent-rich streams; ion-selective redox flow desalination separates magnesium; and electrochemical lithium ion pumping captures lithium selectively. The monovalent-rich stream feeds a chlor-alkali reactor, whose anodic products are internally captured and utilized as redox mediators to selectively dissolve lithium from LFP black mass. The cathodic alkali hydroxides serve as reagents to remove divalent ions by precipitation. Hydrogen from the chlor-alkali step is consumed by a fuel-cell deionization reactor that deionizes lithium halide streams, forming LiOH and acid as key products. The acid is reused to release CO2 from brines, which is then internally converted into lithium carbonate and calcium carbonate.

BrinE-Loop’s defining innovation is the complete internal reuse of all electrochemical co-products (acid, alkali, hydrogen, halogens, and CO2), transforming desalination brines from waste into a valuable source of reagents. This approach turns a major waste stream into high-value critical minerals and industrial chemicals, cutting environmental impact while generating new revenue.

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-EIC - HORIZON EIC Grants

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Call for proposal

(opens in new window) HORIZON-EIC-2025-PATHFINDERCHALLENGES-01

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Coordinator

POLITECHNIKA WROCLAWSKA
Net EU contribution
€ 779 728,44
Address
WYBRZEZE WYSPIANSKIEGO 27
50-370 Wroclaw
Poland
Region
Makroregion południowo-zachodni Dolnośląskie Miasto Wrocław
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data

Participants (4)