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Performance evaluation of solar energy driven photo electrochemical oxidation in hybrdization with constructed wetlands for per- and polyfluoroalkyl substances removal and treated water reusability

Project description

A new solution for the removal of PFAS from wastewater

Wastewater treatment is key to reducing environmental damage that affects regions worldwide, especially areas neighbouring industrial and urban centres. Unfortunately, most current wastewater treatment solutions are unable to handle the volume of wastewater and often cannot remove key substances, such as per- and polyfluoroalkyl substances (PFAS). The EU-funded PECO-WET project is developing an efficient solar-driven photoelectrochemical oxidation (PEO) solution, combined with constructed wetlands (CW), to enable the removal of PFAS from wastewater. The project will use the PEO to improve PFAS degradation efficiency and conditions for the CWs, allowing them to more efficiently and reliably achieve natural polishing and contaminant removal.

Objective

This proposal aims to develop a novel low-cost, solar-driven photo-electrochemical oxidation (PEO) coupled with constructed wetlands (CWs) for the removal of per- and polyfluoroalkyl substances (PFAS) from wastewater. The central innovation is the integration of using a nitrogen-doped laser-induced graphene (N-LIG) based Fe–Ni layered double hydroxide (LDH) photoanode along with native Coimbra species for CWs. The PEO step not only ensures efficient PFAS degradation but also enhances biodegradability index of transformation products, creating a favorable influent quality for CWs to achieve natural polishing. This synergy enables reliable contaminant removal while reducing energy and operational costs through the use of solar energy and local natural systems. The treated water will be safely reused for irrigation, landscaping, and other non-potable applications, directly supporting circular water economy principles. By reducing the toxicity and persistence of PFAS before CW treatment, the system extends the lifetime and efficiency of natural wetlands while minimizing sludge production and chemical demand. The low-cost PEO process, coupled with CW units, provides a viable pathway for scale-up and real-world application. This approach is adaptable to decentralised wastewater treatment, industrial discharges as well as municipal reuse projects. The reliance on this proposal aims to develop a low-cost, solar-driven PFAS treatment system as a natural polishing step. The hybrid process enhances PFAS degradation, enables safe water reuse for irrigation and landscaping, and supports sustainable technologies to support scalability and commercialization for real-world wastewater treatment applications.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

(opens in new window) HORIZON-WIDERA-2025-TALENTS-01

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Coordinator

UNIVERSIDADE DE COIMBRA
Net EU contribution
€ 191 343,12
Address
PACO DAS ESCOLAS
3004-531 Coimbra
Portugal
Activity type
Higher or Secondary Education Establishments
Links
Total cost
No data

Partners (1)