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Content archived on 2024-06-16

Hybrid hydrogen - carbon dioxide separation systems

Objective

The main goal of this project is the development of a hybrid membrane/ Pressure Swing Adsorption (PSA) H2/CO2 separation process, which will be a part of a fossil fuel de-carbonization process used for the pre-combustion CO2 capture. Methane steam reformin g is currently the major route for hydrogen production and will be employed as a model case. High purity hydrogen (99.99+%) is usually recovered from the reformate by using a PSA process. A typical PSA waste gas stream (CO2~55%, H2~35%, CH4 & CO~ 15%) is not usually recycled since it has to be recompressed to the PSA feed pressure for recovering only a small fraction of the recycled hydrogen. Furthermore, it cannot be used for CO2 sequestration since it contains significant amounts of H2 and CH4. A hybr id process is expected to combine the high throughput and H2 product purity of a PSA process with the lower operating costs of a membrane process. It is expected to enhance the overall H2 recovery and provide an H2-free CO2 stream ready for capture and seq uestration. To achieve this goal in the proposed R&D project, the following scientific tasks have been identified: *Generation of transport and adsorption data for H2/CO2 multicomponent mixtures (CH4, H2O, CO) for well characterized membrane and sorben t materials *Development and improvement of membrane and PSA separation models *Design and optimization of membrane, PSA and hybrid separation systems using the improved models developed *Component design for the manufacture of a lab-scale hybrid separatio n system prototype *Assessment of the hybrid separation process sustainability and impact on the environment based on a life cycle analysis approach The following possible innovations are foreseen as an outcome of this project: *H2 recovery improvement *Si mplification of PSA operation (reduction of steps) without loss of recovery and product purity *Co-production of high purity H2 and CO2 streams *Development of improved membrane and sorbent materials

Fields of science (EuroSciVoc)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

FP6-2004-ENERGY-3
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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

STREP - Specific Targeted Research Project

Coordinator

FOUNDATION FOR RESEARCH AND TECHNOLOGY HELLAS
EU contribution
No data
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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Participants (6)

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