Objective Considerable effort is currently being devoted to the miniaturization of electronic devices to the nanometer scale, ideally affording systems that operate on a molecular level. Chemist’s contribution to this research area has thus far concentrated on the preparation of organic OR inorganic materials. For example, purely metallic GaAs and GaP nanowires have been constructed for semiconductor applications. While these materials show excellent electron mobility properties, their tuning potential is rather low. In contrast, organic semiconductors such as conjugated oligomers or polymers display promising properties, though their electron carrier properties are intrinsically lower than that of metallic materials. Organometallic species comprising tunable organic ligand moieties and transition metal centers featuring an enhanced electron mobility may combine the advantages of purely inorganic and organic materials and are therefore expected to be particularly useful as molecular units for the fabrication of new electronic devices. The proposed research aims at identifying molecular switches based on mono- and multimetallic complexes and at their implementation in electronically active devices, thus creating intelligent materials. While organometallic chemistry dominates the highly synthetic first part of the project, the characterization and application of self-assemblies in molecular electronics clearly requires an interdisciplinary approach. Fields of science natural scienceschemical sciencesinorganic chemistryorganometallic chemistrynatural scienceschemical sciencespolymer sciencesnatural sciencesphysical scienceselectromagnetism and electronicssemiconductivity Keywords carbene complexes molecular electronics molecular switches self-assembled monolayers Programme(s) FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) Topic(s) PEOPLE-2007-2-1.IEF - Marie Curie Action: "Intra-European Fellowships for Career Development" Call for proposal FP7-PEOPLE-2007-2-1-IEF See other projects for this call Funding Scheme MC-IEF - Intra-European Fellowships (IEF) Coordinator UNIVERSITE DE FRIBOURG Address Avenue de l europe 20 1700 Fribourg Switzerland See on map Region Schweiz/Suisse/Svizzera Espace Mittelland Fribourg / Freiburg Activity type Higher or Secondary Education Establishments Administrative Contact Martin Albrecht (Prof.) Links Contact the organisation Opens in new window Website Opens in new window EU contribution € 178 163,71