Objective
This proposal addresses a clearly urgent need to develop novel homogeneous catalysts for the asymmetric hydrogenation of ketones with hydrogen gas, as a green, energy- and cost-efficient alternative to the currently used protocols. Instead of precious metals, we attempt to utilize transition metal complexes based on environmentally benign, inexpensive and non-toxic iron. First examples in the asymmetric hydrogenation using iron complexes are a promising indication that efficient systems might in principle become viable with further catalyst development and by careful selection of ligands and reaction conditions. Based on an extensive initial catalyst screening, well-defined complexes of two different classes will be designed and synthetized: 1) Complexes of general formula [Fe(P-P)(N-N)X2], which feature two bidentate ligands structurally related to the known PNNP tetradentate systems; 2) Piano-stool Fe complexes containing pendant H-donor groups as well as strongly electron-donating chiral carbene ligands. Recognizing and addressing the expected challenges, mainly related to transitioning from precious metals such as ruthenium or rhodium to a first row alternative will largely contribute to the basic scientific knowledge in this field.
The most promising catalysts will be subsequently applied in the transformation of biomass-derived ketones originating from the oxidative disassembly of lignin, therefore this proposal offers various multidisciplinary aspects while relying on solid background in classical asymmetric catalysis. In case of success this research will contribute to the transition towards a sustainable society in multiple ways.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences organic chemistry ketones
- natural sciences chemical sciences inorganic chemistry transition metals
- natural sciences chemical sciences catalysis
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
FP7-PEOPLE-2013-IEF
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Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Coordinator
9712CP Groningen
Netherlands
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.