Design, Synthesis, Characterization and Catalytic Application of Silyliumylidene Ions

Project Information

SILION

Grant agreement ID: 637394

DOI 10.3030/637394

Project closed

EC signature date 13 March 2015

Start date 1 December 2015

End date 31 May 2021

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 499 942,00

EU contribution € 1 499 942,00

Coordinated by

TECHNISCHE UNIVERSITAET MUENCHEN
Germany

Publications

Peer reviewed articles (21)

DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds

Author(s): Richard Holzner, Dominik Reiter, Philipp Frisch, Shigeyoshi Inoue
Published in: RSC Advances, Issue 10/6, 2020, Page(s) 3402-3406, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9ra10628f

An Air‐Stable Heterobimetallic Si 2 M 2 Tetrahedral Cluster

Author(s): Gizem Dübek, Franziska Hanusch, Dominik Munz, Shigeyoshi Inoue
Published in: Angewandte Chemie International Edition, Issue 59/14, 2020, Page(s) 5823-5829, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201916116

Three-Coordinate Boron(III) and Diboron(II) Dications

Author(s): Daniel Franz, Tibor Szilvási, Alexander Pöthig, Franziska Deiser, Shigeyoshi Inoue
Published in: Chemistry - A European Journal, Issue 24/17, 2018, Page(s) 4283-4288, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201800609

S–H Bond Activation in Hydrogen Sulfide by NHC-Stabilized Silyliumylidene Ions

Author(s): Amelie Porzelt, Julia Schweizer, Ramona Baierl, Philipp Altmann, Max Holthausen, Shigeyoshi Inoue
Published in: Inorganics, Issue 6/2, 2018, Page(s) 54, ISSN 2304-6740
Publisher: MDPI
DOI: 10.3390/inorganics6020054

Chalcogen-atom transfer and exchange reactions of NHC-stabilized heavier silaacylium ions

Author(s): Debotra Sarkar, Daniel Wendel, Syed Usman Ahmad, Tibor Szilvási, Alexander Pöthig, Shigeyoshi Inoue
Published in: Dalton Transactions, Issue 46/46, 2017, Page(s) 16014-16018, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7DT03998K

Advances in Phosphasilene Chemistry

Author(s): Vitaly Nesterov, Nora C. Breit, Shigeyoshi Inoue
Published in: Chemistry - A European Journal, Issue 23/50, 2017, Page(s) 12014-12039, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201700829

Synthesis and Reactivity of Functionalized Silicon(II) Compounds: Iminosilylene, Phosphinosilylene, Hydrosilylene, and Related Compounds

Author(s): Prasenjit Bag, Syed Usman Ahmad, Shigeyoshi Inoue
Published in: Bulletin of the Chemical Society of Japan, Issue 90/3, 2017, Page(s) 255-271, ISSN 0009-2673
Publisher: Chemical Society of Japan/Nippon Kagakukai
DOI: 10.1246/bcsj.20160284

Applications of N-heterocyclic imines in main group chemistry

Author(s): Tatsumi Ochiai, Daniel Franz, Shigeyoshi Inoue
Published in: Chem. Soc. Rev., Issue 45/22, 2016, Page(s) 6327-6344, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6CS00163G

Advances in the development of complexes that contain a group 13 element chalcogen multiple bond

Author(s): Daniel Franz, Shigeyoshi Inoue
Published in: Dalton Trans., Issue 45/23, 2016, Page(s) 9385-9397, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6DT01413E

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

Author(s): Tatsumi Ochiai, Tibor Szilvási, Daniel Franz, Elisabeth Irran, Shigeyoshi Inoue
Published in: Angewandte Chemie International Edition, Issue 55/38, 2016, Page(s) 11619-11624, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201605636

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines

Author(s): Tatsumi Ochiai, Tibor Szilvási, Shigeyoshi Inoue
Published in: Molecules, Issue 21/9, 2016, Page(s) 1155, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules21091155

Aluminum Hydrides Stabilized by N-Heterocyclic Imines as Catalysts for Hydroborations with Pinacolborane

Author(s): Daniel Franz, Lorenz Sirtl, Alexander Pöthig, Shigeyoshi Inoue
Published in: Zeitschrift für anorganische und allgemeine Chemie, Issue 642/22, 2016, Page(s) 1245-1250, ISSN 0044-2313
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/zaac.201600313

NHCs in Main Group Chemistry

Author(s): Vitaly Nesterov, Dominik Reiter, Prasenjit Bag, Philipp Frisch, Richard Holzner, Amelie Porzelt, Shigeyoshi Inoue
Published in: Chemical Reviews, Issue 118/19, 2018, Page(s) 9678-9842, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.8b00079

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Author(s): Philipp Frisch, Shigeyoshi Inoue
Published in: Chemical Communications, Issue 54/97, 2018, Page(s) 13658-13661, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc07754a

The Road Travelled: After Main-Group Elements as Transition Metals

Author(s): Catherine Weetman, Shigeyoshi Inoue
Published in: ChemCatChem, Issue 10/19, 2018, Page(s) 4213-4228, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201800963

Facile Access to Dative, Single, and Double Silicon−Metal Bonds Through M−Cl Insertion Reactions of Base‐Stabilized Si II Cations

Author(s): Philipp Frisch, Tibor Szilvási, Shigeyoshi Inoue
Published in: Chemistry – A European Journal, Issue 26/28, 2020, Page(s) 6271-6278, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202000866

Transition Metal Carbonyl Complexes of an N-Heterocyclic Carbene Stabilized Silyliumylidene Ion

Author(s): Philipp Frisch, Tibor Szilvási, Amelie Porzelt, Shigeyoshi Inoue
Published in: Inorganic Chemistry, Issue 58/21, 2019, Page(s) 14931-14937, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b02772

Reactivity of an NHC-stabilized pyramidal hydrosilylene with electrophilic boron sources

Author(s): Gizem Dübek, Daniel Franz, Carsten Eisenhut, Philipp J. Altmann, Shigeyoshi Inoue
Published in: Dalton Transactions, Issue 48/17, 2019, Page(s) 5756-5765, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt00608g

NHC-Stabilized Silyl-Substituted Chlorosilylene

Author(s): Gizem Dübek, Franziska Hanusch, Shigeyoshi Inoue
Published in: Inorganic Chemistry, Issue 58/23, 2019, Page(s) 15700-15704, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b02670

NHC‐Stabilised Silyliumylidene Ions

Author(s): Samuel L. Powley, Shigeyoshi Inoue
Published in: The Chemical Record, Issue 19/11, 2019, Page(s) 2179-2188, ISSN 1527-8999
Publisher: John Wiley & Sons Inc.
DOI: 10.1002/tcr.201800188

NHC-stabilized silyl-substituted silyliumylidene ions

Author(s): Philipp Frisch, Shigeyoshi Inoue
Published in: Dalton Transactions, Issue 48/28, 2019, Page(s) 10403-10406, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt02010a

Non-peer reviewed articles (2)

Small Molecule Activation by Two‐Coordinate Acyclic Silylenes

Author(s): Shiori Fujimori, Shigeyoshi Inoue
Published in: European Journal of Inorganic Chemistry, Issue 2020/33, 2020, Page(s) 3131-3142, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202000479

Coordination Chemistry of Silicon

Author(s): Shigeyoshi Inoue
Published in: Inorganics, Issue 7/1, 2019, Page(s) 7, ISSN 2304-6740
Publisher: MDPI
DOI: 10.3390/inorganics7010007