Project description DEENESFRITPL Natural catalysts for improved solar fuel cells Harnessing solar energy to produce sustainable forms of fuel such as hydrogen requires photocatalysts that can efficiently use visible light to split water molecules through water electrolysis. Similarly, for oxygen reduction into water, a crucial step for producing electricity in fuel cells, efficient catalysts are required to expedite the reaction with minimal energy losses. Funded by the European Research Council, the Cu4Energy project will explore natural catalysts like the copper enzyme Laccase, given its fast operation and low energy requirements. Researchers will associate catalyst structure with catalytic activity and analyse the energy landscape of the reaction cycle. Project findings are expected to enhance fundamental understanding and deliver highly active copper catalysts for oxygen splitting and reduction reactions. Show the project objective Hide the project objective Objective Water oxidation (WO) and oxygen reduction (OR) are crucial reactions to produce and to consume solar fuels. It is important that WO and OR occur with very high catalytic rates with only a very small thermodynamic driving force (i.e. a small overpotential). In these terms, natural catalysts perform significantly better than the artificial systems. Especially the copper enzyme Laccase operates fast at a low overpotential. In principle one could use the same design principles used in the enzymatic systems to produce artificial catalysts for OR and WO. It is envisioned that for the most ideal OR and WO catalysts:1. all redox reactions within the catalytic cycle should occur as close as possible to the thermodynamic potential where OR and WO become accessible.2. Equilibria that are not coupled to redox reactions need to be biased for product formation.3. Proton shuttles are necessary to manage proton transfer concerted with electron-transfer and electron-transfer coupled to O–O bond cleavage or O–O bond formation. In this proposal molecular copper catalysts for OR and WO are studied by means of a combined electrochemical and computational approach, taking in account the design principles above. Experiments will be carried out wherein the structure of the catalyst is linked to the observed catalytic activity and the potential energy surface of the catalytic cycle. The proposal is in particular focused on the rate-determining step of the catalytic reaction, as improvements here will directly lead to enhanced catalytic rates. A functional model system of Laccase will be designed to study the rate limiting proton-and-electron-coupled O–O bond scission reaction, which is the rate limiting step in OR by Laccase. The aim of the proposal is to significantly increase of fundamental understanding of the design principles for molecular OR and WO catalysts and to deliver new and very active molecular copper catalysts for OR and WO at the end of the project. Fields of science natural scienceschemical sciencesorganic chemistryorganic reactionsnatural scienceschemical scienceselectrochemistryelectrolysisnatural sciencesphysical sciencesthermodynamicsnatural scienceschemical sciencescatalysisnatural sciencesbiological sciencesbiochemistrybiomoleculesproteinsenzymes Programme(s) H2020-EU.1.1. - EXCELLENT SCIENCE - European Research Council (ERC) Main Programme Topic(s) ERC-StG-2014 - ERC Starting Grant Call for proposal ERC-2014-STG See other projects for this call Funding Scheme ERC-STG - Starting Grant Coordinator UNIVERSITEIT LEIDEN Net EU contribution € 1 500 000,00 Address Rapenburg 70 2311 EZ Leiden Netherlands See on map Region West-Nederland Zuid-Holland Agglomeratie Leiden en Bollenstreek Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Other funding € 0,00 Beneficiaries (1) Sort alphabetically Sort by Net EU contribution Expand all Collapse all UNIVERSITEIT LEIDEN Netherlands Net EU contribution € 1 500 000,00 Address Rapenburg 70 2311 EZ Leiden See on map Region West-Nederland Zuid-Holland Agglomeratie Leiden en Bollenstreek Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Other funding € 0,00
