Fuel from sunlight: Covalent organic frameworks as integrated platforms for photocatalytic water splitting and CO2 reduction

Project Information

COFLeaf

Grant agreement ID: 639233

DOI 10.3030/639233

Project closed

EC signature date 6 February 2015

Start date 1 September 2015

End date 31 August 2020

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 497 125,00

EU contribution € 1 497 125,00

Coordinated by

MAX-PLANCK-GESELLSCHAFT ZUR FORDERUNG DER WISSENSCHAFTEN EV
Germany

Publications

Peer reviewed articles (27)

Polymer photocatalysts for solar-to-chemical energy conversion

Author(s): Tanmay Banerjee, Filip Podjaski, Julia Kröger, Bishnu P. Biswal, Bettina V. Lotsch
Published in: Nature Reviews Materials, 2020, ISSN 2058-8437
Publisher: Nature publishing group
DOI: 10.1038/s41578-020-00254-z

Toward an Aqueous Solar Battery: Direct Electrochemical Storage of Solar Energy in Carbon Nitrides

Author(s): Filip Podjaski, Julia Kröger, Bettina. V. Lotsch
Published in: Advanced Materials, Issue 30/9, 2018, Page(s) 1705477, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.201705477

Optoelectronics Meets Optoionics: Light Storing Carbon Nitrides and Beyond

Author(s): Filip Podjaski, Bettina V. Lotsch
Published in: Advanced Energy Materials, 2020, Page(s) 2003049, ISSN 1614-6832
Publisher: Wiley-VCH Verlag
DOI: 10.1002/aenm.202003049

Carbon nitride-based light-driven microswimmers with intrinsic photocharging ability

Author(s): Varun Sridhar, Filip Podjaski, Julia Kröger, Alberto Jiménez-Solano, Byung-Wook Park, Bettina V. Lotsch, Metin Sitti
Published in: Proceedings of the National Academy of Sciences, Issue 117/40, 2020, Page(s) 24748-24756, ISSN 0027-8424
Publisher: National Academy of Sciences
DOI: 10.1073/pnas.2007362117

Tailor-Made Photoconductive Pyrene-Based Covalent Organic Frameworks for Visible-Light Driven Hydrogen Generation

Author(s): Linus Stegbauer, Sebastian Zech, Gökcen Savasci, Tanmay Banerjee, Filip Podjaski, Katharina Schwinghammer, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Advanced Energy Materials, 2018, Page(s) 1703278, ISSN 1614-6832
Publisher: Wiley-VCH Verlag
DOI: 10.1002/aenm.201703278

Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis

Author(s): Frederik Haase, Erik Troschke, Gökcen Savasci, Tanmay Banerjee, Viola Duppel, Susanne Dörfler, Martin M. J. Grundei, Asbjörn M. Burow, Christian Ochsenfeld, Stefan Kaskel & Bettina V. Lotsch
Published in: Nature Communications, 2018, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-018-04979-y

H 2 Evolution with Covalent Organic Framework Photocatalysts

Author(s): Tanmay Banerjee, Kerstin Gottschling, Gökcen Savasci, Christian Ochsenfeld, Bettina V. Lotsch
Published in: ACS Energy Letters, Issue 3/2, 2018, Page(s) 400-409, ISSN 2380-8195
Publisher: ACS
DOI: 10.1021/acsenergylett.7b01123

Structure–property–activity relationships in a pyridine containing azine-linked covalent organic framework for photocatalytic hydrogen evolution

Author(s): Frederik Haase, Tanmay Banerjee, Gökcen Savasci, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Faraday Discussions, Issue 201, 2017, Page(s) 247-264, ISSN 1359-6640
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7FD00051K

Thermodynamic Equilibria in Carbon Nitride Photocatalyst Materials and Conditions for the Existence of Graphitic Carbon Nitride g-C 3 N 4

Author(s): Tiago Botari, William Paul Huhn, Vincent Wing-hei Lau, Bettina V. Lotsch, Volker Blum
Published in: Chemistry of Materials, Issue 29/10, 2017, Page(s) 4445-4453, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.7b00965

Urea-Modified Carbon Nitrides: Enhancing Photocatalytic Hydrogen Evolution by Rational Defect Engineering

Author(s): Vincent Wing-hei Lau, Victor Wen-zhe Yu, Florian Ehrat, Tiago Botari, Igor Moudrakovski, Thomas Simon, Viola Duppel, Elise Medina, Jacek K. Stolarczyk, Jochen Feldmann, Volker Blum, Bettina V. Lotsch
Published in: Advanced Energy Materials, Issue 7/12, 2017, Page(s) 1602251, ISSN 1614-6832
Publisher: Wiley-VCH Verlag
DOI: 10.1002/aenm.201602251

Single-Site Photocatalytic H 2 Evolution from Covalent Organic Frameworks with Molecular Cobaloxime Co-Catalysts

Author(s): Tanmay Banerjee, Frederik Haase, Gökcen Savasci, Kerstin Gottschling, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Journal of the American Chemical Society, Issue 139/45, 2017, Page(s) 16228-16234, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.7b07489

Sustained Solar H 2 Evolution from a Thiazolo[5,4- d ]thiazole-Bridged Covalent Organic Framework and Nickel-Thiolate Cluster in Water

Author(s): Bishnu P. Biswal, Hugo A. Vignolo-González, Tanmay Banerjee, Lars Grunenberg, Gökcen Savasci, Kerstin Gottschling, Jürgen Nuss, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Journal of the American Chemical Society, Issue 141/28, 2019, Page(s) 11082-11092, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b03243

Molecular Insights into Carbon Dioxide Sorption in Hydrazone-Based Covalent Organic Frameworks with Tertiary Amine Moieties

Author(s): Kerstin Gottschling, Linus Stegbauer, Gökcen Savasci, Nathan A. Prisco, Zachariah J. Berkson, Christian Ochsenfeld, Bradley F. Chmelka, Bettina V. Lotsch
Published in: Chemistry of Materials, Issue 31/6, 2019, Page(s) 1946-1955, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.8b04643

Structural Insights into Poly(Heptazine Imides): A Light Storing Carbon Nitride Material for Dark Photocatalysis

Author(s): Hendrik Schlomberg, Julia Kröger, Gökcen Savasci, Maxwell W. Terban, Sebastian Bette, Igor Moudrakovski, Viola Duppel, Filip Podjaski, Renée Siegel, Jürgen Senker, Robert E. Dinnebier, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Chemistry of Materials, 2019, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b02199

Sub-stoichiometric 2D covalent organic frameworks from tri- and tetratopic linkers

Author(s): Tanmay Banerjee, Frederik Haase, Stefan Trenker, Bishnu P. Biswal, Gökcen Savasci, Viola Duppel, Igor Moudrakovski, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Nature Communications, Issue 10/1, 2019, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-019-10574-6

Solar-Driven Reduction of Aqueous Protons Coupled to Selective Alcohol Oxidation with a Carbon Nitride–Molecular Ni Catalyst System

Author(s): Hatice Kasap, Christine A. Caputo, Benjamin C. M. Martindale, Robert Godin, Vincent Wing-hei Lau, Bettina V. Lotsch, James R. Durrant, Erwin Reisner
Published in: Journal of the American Chemical Society, Issue 138/29, 2016, Page(s) 9183-9192, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6b04325

A tunable azine covalent organic framework platform for visible light-induced hydrogen generation

Author(s): Vijay S. Vyas, Frederik Haase, Linus Stegbauer, Gökcen Savasci, Filip Podjaski, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Nature Communications, Issue 6, 2015, Page(s) 8508, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/ncomms9508

Dark Photocatalysis: Storage of Solar Energy in Carbon Nitride for Time-Delayed Hydrogen Generation

Author(s): Vincent Wing-hei Lau, Daniel Klose, Hatice Kasap, Filip Podjaski, Marie-Claire Pignié, Erwin Reisner, Gunnar Jeschke, Bettina V. Lotsch
Published in: Angewandte Chemie International Edition, Issue 56/2, 2017, Page(s) 510-514, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201608553

Soft Photocatalysis: Organic Polymers for Solar Fuel Production

Author(s): Vijay S. Vyas, Vincent Wing-hei Lau, Bettina V. Lotsch
Published in: Chemistry of Materials, Issue 28/15, 2016, Page(s) 5191-5204, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.6b01894

Tuning the stacking behaviour of a 2D covalent organic framework through non-covalent interactions

Author(s): F. Haase, K. Gottschling, L. Stegbauer, L. S. Germann, R. Gutzler, V. Duppel, V. S. Vyas, K. Kern, R. E. Dinnebier, B. V. Lotsch
Published in: Mater. Chem. Front., 2017, ISSN 2052-1537
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6QM00378H

Short‐Range Structural Correlations in Amorphous 2D Polymers

Author(s): Patrick Alexa, Christina Oligschleger, Pascal Gröger, Claudius Morchutt, Vijay Vyas, Bettina V. Lotsch, J. Christian Schön, Rico Gutzler, Klaus Kern
Published in: ChemPhysChem, Issue 20/18, 2019, Page(s) 2340-2347, ISSN 1439-4235
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.201900326

Enhancing hydrogen evolution activity of Au(111) in alkaline media through molecular engineering of a 2D polymer

Author(s): Patrick Alexa, Juan Manuel Lombardi, Paula Abufager, Heriberto Fabio Busnengo, Doris Grumelli, Vijay S. Vyas, Frederik Haase, Bettina V. Lotsch, Rico Gutzler, Klaus Kern
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201915855

Ionothermal Synthesis of Imide‐Linked Covalent Organic Frameworks

Author(s): Johannes Maschita, Tanmay Banerjee, Gökcen Savasci, Frederik Haase, Christian Ochsenfeld, Bettina Valeska Lotsch
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202007372

Rational Design of Covalent Cobaloxime-COF Hybrids for Enhanced Photocatalytic Hydrogen Evolution

Author(s): Kerstin Gottschling, Gökcen Savasci, Hugo A. Vignolo-González, Sandra Schmidt, Philipp Mauker, Tanmay Banerjee, Petra Rovó, Christian Ochsenfeld, Bettina V. Lotsch
Published in: Journal of the American Chemical Society, 2020, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c02155

Total scattering reveals the hidden stacking disorder in a 2D covalent organic framework

Author(s): Alexander M. Pütz, Maxwell W. Terban, Sebastian Bette, Frederik Haase, Robert E. Dinnebier, Bettina V. Lotsch
Published in: Chemical Science, 2020, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc03048a

Near–atomic-scale observation of grain boundaries in a layer-stacked two-dimensional polymer

Author(s): Haoyuan Qi, Hafeesudeen Sahabudeen, Baokun Liang, Miroslav Položij, Matthew A. Addicoat, Tatiana E. Gorelik, Mike Hambsch, Manuel Mundszinger, SangWook Park, Bettina V. Lotsch, Stefan C. B. Mannsfeld, Zhikun Zheng, Renhao Dong, Thomas Heine, Xinliang Feng, Ute Kaiser
Published in: Science Advances, Issue 6/33, 2020, Page(s) eabb5976, ISSN 2375-2548
Publisher: Science Advances
DOI: 10.1126/sciadv.abb5976

Solving the COF trilemma: towards crystalline, stable and functional covalent organic frameworks

Author(s): Frederik Haase, Bettina V. Lotsch
Published in: Chemical Society Reviews, 2020, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cs01027h