Accelerating photoredox catalysis in continuous-flow systems

Informations projet

Photo4Future

N° de convention de subvention: 641861

DOI 10.3030/641861

Projet clôturé

Date de signature de la CE 14 Novembre 2014

Date de début 1 Janvier 2015

Date de fin 31 Decembre 2018

Financé au titre de

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Coût total € 2 248 434,36

Contribution de l’UE € 2 248 434,36

Coordonné par

TECHNISCHE UNIVERSITEIT EINDHOVEN
Netherlands

Livrables

Other (2)

Schools

The schools will be seperately organized. More details can be found in the training program

Recruitment ESRs

Hiring complete

Websites, patent fillings, videos etc. (1)

Scientific papers, conferences

Papers and presentations will be disseminated as soon as the students obtained results

Documents, reports (5)

PhD dissertation

Ph.D. title will be granted.

ETHICS - report on ethical issues

A report on the ethical issues must be submitted to REA The applicant must 1) confirm that the ethical standards and guidelines of Horizon2020 will be rigorously applied, regardless of the country in which the research is carried out. 2) the applicant must provide details on the material which could be imported to/exported from EU and provide the adequate authorisations when needed.

ETHICS: authorizations for nanotechnology use

University of Cordoba and CNRS Bordeaux will provide authorizations for nanotechnology use in month 6 as a deliverable. In addition, they will provide the documents with regard to safety classifications of the laboratory. The staff will receive adequate training in storing, handling and disposing of nanomaterials. For new nanocatalysts, we will provide adequate risk assessments.

ETHICS - report on ethical issues part II

A report on the ethical issues must be submitted to REA The applicant must 1) confirm that the ethical standards and guidelines of Horizon2020 will be rigorously applied, regardless of the country in which the research is carried out. 2) the applicant must provide details on the material which could be imported to/exported from EU and provide the adequate authorisations when needed.

Interim report

report published

Publications

Peer reviewed articles (36)

An accessible visible-light actinometer for the determination of photon flux and optical pathlength in flow photo microreactors

Auteurs: Anca Roibu, Senne Fransen, M. Enis Leblebici, Glen Meir, Tom Van Gerven, Simon Kuhn
Publié dans: Scientific Reports, Numéro 8/1, 2018, ISSN 2045-2322
Éditeur: Nature Publishing Group
DOI: 10.1038/s41598-018-23735-2

Design and characterization of visible-light LED sources for microstructured photoreactors

Auteurs: Anca Roibu, Rishi Bharadwaj Morthala, M. Enis Leblebici, Dorota Koziej, Tom Van Gerven, Simon Kuhn
Publié dans: Reaction Chemistry & Engineering, Numéro 3/6, 2018, Page(s) 849-865, ISSN 2058-9883
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c8re00165k

Scalability of Visible-Light-Induced Nickel Negishi Reactions: A Combination of Flow Photochemistry, Use of Solid Reagents, and In-Line NMR Monitoring

Auteurs: Irini Abdiaj, Clemens R. Horn, Jesus Alcazar
Publié dans: The Journal of Organic Chemistry, 2018, ISSN 0022-3263
Éditeur: American Chemical Society
DOI: 10.1021/acs.joc.8b02358

Bi 2 O 2 CO 3 Growth at Room Temperature: In Situ X-ray Diffraction Monitoring and Thermal Behavior

Auteurs: René Moré, Michael Olah, S. Esmael Balaghi, Philipp Jäker, Sebastian Siol, Ying Zhou, Greta R. Patzke
Publié dans: ACS Omega, Numéro 2/11, 2017, Page(s) 8213-8221, ISSN 2470-1343
Éditeur: ACS Publications
DOI: 10.1021/acsomega.7b01359

Visible-Light Photocatalytic Difluoroalkylation-Induced 1, 2-Heteroarene Migration of Allylic Alcohols in Batch and Flow

Auteurs: Xiao-Jing Wei, Timothy Noël
Publié dans: The Journal of Organic Chemistry, Numéro 83/18, 2018, Page(s) 11377-11384, ISSN 0022-3263
Éditeur: American Chemical Society
DOI: 10.1021/acs.joc.8b01624

Visible-Light Photocatalytic Decarboxylation of α,β-Unsaturated Carboxylic Acids: Facile Access to Stereoselective Difluoromethylated Styrenes in Batch and Flow

Auteurs: Xiao-Jing Wei, Wout Boon, Volker Hessel, Timothy Noël
Publié dans: ACS Catalysis, Numéro 7/10, 2017, Page(s) 7136-7140, ISSN 2155-5435
Éditeur: American Chemical Society
DOI: 10.1021/acscatal.7b03019

Continuous-Flow Hydrogenation of Methyl Levulinate Promoted by Zr-Based Mesoporous Materials

Auteurs: Noelia Lázaro, Ana Franco, Weiyi Ouyang, Alina Balu, Antonio Romero, Rafael Luque, Antonio Pineda
Publié dans: Catalysts, Numéro 9/2, 2019, Page(s) 142, ISSN 2073-4344
Éditeur: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal9020142

Every photon counts: understanding and optimizing photon paths in luminescent solar concentrator-based photomicroreactors (LSC-PMs)

Auteurs: Dario Cambié, Fang Zhao, Volker Hessel, Michael G. Debije, Timothy Noël
Publié dans: Reaction Chemistry & Engineering, Numéro 2/4, 2017, Page(s) 561-566, ISSN 2058-9883
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c7re00077d

Solar Photochemistry in Flow

Auteurs: Dario Cambié, Timothy Noël
Publié dans: Topics in Current Chemistry, Numéro 376/6, 2018, ISSN 2365-0869
Éditeur: Springer International Publishing
DOI: 10.1007/s41061-018-0223-2

De novo Design of Organic Photocatalysts: Bithiophene Derivatives for the Visible-light Induced C−H Functionalization of Heteroarenes

Auteurs: Cecilia Bottecchia, Raúl Martín, Irini Abdiaj, Ettore Crovini, Jesús Alcazar, Jesús Orduna, María Jesús Blesa, José R. Carrillo, Pilar Prieto, Timothy Noël
Publié dans: Advanced Synthesis & Catalysis, 2018, ISSN 1615-4150
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.201801571

Photocatalytic Modification of Amino Acids, Peptides, and Proteins

Auteurs: Cecilia Bottecchia, Timothy Noël
Publié dans: Chemistry - A European Journal, Numéro 25/1, 2019, Page(s) 26-42, ISSN 0947-6539
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201803074

Visible-Light-Mediated Selective Arylation of Cysteine in Batch and Flow

Auteurs: Cecilia Bottecchia, Maarten Rubens, Smita B. Gunnoo, Volker Hessel, Annemieke Madder, Timothy Noël
Publié dans: Angewandte Chemie International Edition, Numéro 56/41, 2017, Page(s) 12702-12707, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201706700

Visible-Light-Induced Nickel-Catalyzed Negishi Cross-Couplings by Exogenous-Photosensitizer-Free Photocatalysis

Auteurs: Irini Abdiaj, Alberto Fontana, M. Victoria Gomez, Antonio de la Hoz, Jesús Alcázar
Publié dans: Angewandte Chemie International Edition, Numéro 57/28, 2018, Page(s) 8473-8477, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201802656

Visible-Light-Induced Trifluoromethylation of Highly Functionalized Arenes and Heteroarenes in Continuous Flow

Auteurs: Jesus Alcazar, Timothy Noёl, Irini Abdiaj, Cecilia Bottecchia
Publié dans: Synthesis, Numéro 49/22, 2017, Page(s) 4978-4985, ISSN 0039-7881
Éditeur: Georg Thieme Verlag
DOI: 10.1055/s-0036-1588527

Designer hydrogenated wrinkled yolk@shell TiO 2 architectures towards advanced visible light photocatalysts for selective alcohol oxidation

Auteurs: Abolfazl Ziarati, Alireza Badiei, Rafael Luque, Weiyi Ouyang
Publié dans: Journal of Materials Chemistry A, Numéro 6/19, 2018, Page(s) 8962-8968, ISSN 2050-7488
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c8ta02012d

Enhancing photocatalytic performance of TiO2 in H2 evolution via Ru co-catalyst deposition

Auteurs: Weiyi Ouyang, Mario J. Muñoz-Batista, Anna Kubacka, Rafael Luque, Marcos Fernández-García
Publié dans: Applied Catalysis B: Environmental, Numéro 238, 2018, Page(s) 434-443, ISSN 0926-3373
Éditeur: Elsevier BV
DOI: 10.1016/j.apcatb.2018.07.046

Highly Active Catalytic Ruthenium/TiO 2 Nanomaterials for Continuous Production of γ-Valerolactone

Auteurs: Chunping Xu, Weiyi Ouyang, Mario J. Muñoz-Batista, Marcos Fernández-García, Rafael Luque
Publié dans: ChemSusChem, Numéro 11/15, 2018, Page(s) 2604-2611, ISSN 1864-5631
Éditeur: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.201800667

Continuous Flow Conversion of Biomass-Derived Methyl Levulinate into γ-Valerolactone Using Functional Metal Organic Frameworks

Auteurs: Weiyi Ouyang, Deyang Zhao, Yantao Wang, Alina M. Balu, Christophe Len, Rafael Luque
Publié dans: ACS Sustainable Chemistry & Engineering, Numéro 6/5, 2018, Page(s) 6746-6752, ISSN 2168-0485
Éditeur: American Chemical Society
DOI: 10.1021/acssuschemeng.8b00549

Towards industrial furfural conversion: Selectivity and stability of palladium and platinum catalysts under continuous flow regime

Auteurs: Weiyi Ouyang, Alfonso Yepez, Antonio A. Romero, Rafael Luque
Publié dans: Catalysis Today, Numéro 308, 2018, Page(s) 32-37, ISSN 0920-5861
Éditeur: Elsevier BV
DOI: 10.1016/j.cattod.2017.07.011

Facile mechanochemical modification of g-C3N4 for selective photo-oxidation of benzyl alcohol

Auteurs: Kenneth Cerdan, Weiyi Ouyang, Juan C. Colmenares, Mario J. Muñoz-Batista, Rafael Luque, Alina M. Balu
Publié dans: Chemical Engineering Science, Numéro 194, 2019, Page(s) 78-84, ISSN 0009-2509
Éditeur: Pergamon Press Ltd.
DOI: 10.1016/j.ces.2018.04.001

Continuous Flow Alcoholysis of Furfuryl Alcohol to Alkyl Levulinates Using Zeolites

Auteurs: Deyang Zhao, Pepijn Prinsen, Yantao Wang, Weiyi Ouyang, Frederic Delbecq, Christophe Len, Rafael Luque
Publié dans: ACS Sustainable Chemistry & Engineering, Numéro 6/5, 2018, Page(s) 6901-6909, ISSN 2168-0485
Éditeur: American Chemical Society
DOI: 10.1021/acssuschemeng.8b00726

Real-time reaction control for solar production of chemicals under fluctuating irradiance

Auteurs: Fang Zhao, Dario Cambié, Volker Hessel, Michael G. Debije, Timothy Noël
Publié dans: Green Chemistry, Numéro 20/11, 2018, Page(s) 2459-2464, ISSN 1463-9262
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c8gc00613j

Scale-up of a Luminescent Solar Concentrator-Based Photomicroreactor via Numbering-up

Auteurs: Fang Zhao, Dario Cambié, Jeroen Janse, Eric W. Wieland, Koen P. L. Kuijpers, Volker Hessel, Michael G. Debije, Timothy Noël
Publié dans: ACS Sustainable Chemistry & Engineering, Numéro 6/1, 2017, Page(s) 422-429, ISSN 2168-0485
Éditeur: American Chemical Society
DOI: 10.1021/acssuschemeng.7b02687

A Fully Automated Continuous-Flow Platform for Fluorescence Quenching Studies and Stern-Volmer Analysis

Auteurs: Koen P. L. Kuijpers, Cecilia Bottecchia, Dario Cambié, Koen Drummen, Niels J. König, Timothy Noël
Publié dans: Angewandte Chemie International Edition, Numéro 57/35, 2018, Page(s) 11278-11282, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201805632

Photoinduced Palladium-Catalyzed Negishi Cross-Couplings Enabled by the Visible-Light Absorption of Palladium-Zinc Complexes

Auteurs: Irini Abdiaj, Lena Huck, José Miguel Mateo, Antonio de la Hoz, M. Victoria Gomez, Angel Díaz-Ortiz, Jesús Alcázar
Publié dans: Angewandte Chemie International Edition, Numéro 57/40, 2018, Page(s) 13231-13236, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808654

Liquid phase oxidation chemistry in continuous-flow microreactors

Auteurs: Hannes P. L. Gemoets, Yuanhai Su, Minjing Shang, Volker Hessel, Rafael Luque, Timothy Noël
Publié dans: Chem. Soc. Rev., Numéro 45/1, 2016, Page(s) 83-117, ISSN 0306-0012
Éditeur: Royal Society of Chemistry
DOI: 10.1039/C5CS00447K

Mild ultrasound-assisted synthesis of TiO2 supported on magnetic nanocomposites for selective photo-oxidation of benzyl alcohol

Auteurs: Juan C. Colmenares, Weiyi Ouyang, Manuel Ojeda, Ewelina Kuna, Olga Chernyayeva, Dmytro Lisovytskiy, Sudipta De, Rafael Luque, Alina M. Balu
Publié dans: Applied Catalysis B: Environmental, Numéro 183, 2016, Page(s) 107-112, ISSN 0926-3373
Éditeur: Elsevier BV
DOI: 10.1016/j.apcatb.2015.10.034

Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment

Auteurs: Dario Cambié, Cecilia Bottecchia, Natan J. W. Straathof, Volker Hessel, Timothy Noël
Publié dans: Chemical Reviews, Numéro 116/17, 2016, Page(s) 10276-10341, ISSN 0009-2665
Éditeur: American Chemical Society
DOI: 10.1021/acs.chemrev.5b00707

Revealing Complexity of Nanoparticle Synthesis in Solution by in Situ Hard X-ray Spectroscopy—Today and Beyond

Auteurs: Dorota Koziej
Publié dans: Chemistry of Materials, Numéro 28/8, 2016, Page(s) 2478-2490, ISSN 0897-4756
Éditeur: American Chemical Society
DOI: 10.1021/acs.chemmater.6b00486

Visible Light-Induced Trifluoromethylation and Perfluoroalkylation of Cysteine Residues in Batch and Continuous Flow

Auteurs: Cecilia Bottecchia, Xiao-Jing Wei, Koen P. L. Kuijpers, Volker Hessel, Timothy Noël
Publié dans: The Journal of Organic Chemistry, Numéro 81/16, 2016, Page(s) 7301-7307, ISSN 0022-3263
Éditeur: American Chemical Society
DOI: 10.1021/acs.joc.6b01031

Wheat bran valorisation: Towards photocatalytic nanomaterials for benzyl alcohol photo-oxidation

Auteurs: Weiyi Ouyang, Jose M. Reina, Ewelina Kuna, Alfonso Yepez, Alina M. Balu, Antonio A. Romero, Juan Carlos Colmenares, Rafael Luque
Publié dans: Journal of Environmental Management, 2016, ISSN 0301-4797
Éditeur: Academic Press
DOI: 10.1016/j.jenvman.2016.07.013

Mechanochemical Synthesis of TiO2 Nanocomposites as Photocatalysts for Benzyl Alcohol Photo-Oxidation

Auteurs: Weiyi Ouyang, Ewelina Kuna, Alfonso Yepez, Alina Balu, Antonio Romero, Juan Colmenares, Rafael Luque
Publié dans: Nanomaterials, Numéro 6/5, 2016, Page(s) 93, ISSN 2079-4991
Éditeur: Multidisciplinary Digital Publishing Institute (MDPI) AG
DOI: 10.3390/nano6050093

Batch and Flow Synthesis of Disulfides by Visible-Light-Induced TiO 2 Photocatalysis

Auteurs: Cecilia Bottecchia, Nico Erdmann, Patricia M. A. Tijssen, Lech-Gustav Milroy, Luc Brunsveld, Volker Hessel, Timothy Noël
Publié dans: ChemSusChem, Numéro 9/14, 2016, Page(s) 1781-1785, ISSN 1864-5631
Éditeur: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.201600602

"Improving the throughput of batch photochemical reactions using flow: Dual photoredox and nickel catalysis in flow for C(sp2)<mml:math altimg=""si1.gif"" overflow=""scroll"" xmlns:xocs=""http://www.elsevier.com/xml/xocs/dtd"" xmlns:xs=""http://www.w3.org/2001/XMLSchema"" xmlns:xsi=""http://www.w3.org/2001/XMLSchema-instance"" xmlns=""http://www.elsevier.com/xml/ja/dtd"" xmlns:ja=""http://www.elsevier.com/xml/j"

Auteurs: Irini Abdiaj, Jesús Alcázar
Publié dans: Bioorganic & Medicinal Chemistry, 2016, ISSN 0968-0896
Éditeur: Pergamon Press Ltd.
DOI: 10.1016/j.bmc.2016.12.041

Disulfide-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bonds and Evidence of an Olefin-Disulfide Charge-Transfer Complex

Auteurs: Yuchao Deng, Xiao-Jing Wei, Hui Wang, Yuhan Sun, Timothy Noël, Xiao Wang
Publié dans: Angewandte Chemie International Edition, Numéro 56/3, 2017, Page(s) 832-836, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201607948

A Leaf-Inspired Luminescent Solar Concentrator for Energy-Efficient Continuous-Flow Photochemistry

Auteurs: Dario Cambié, Fang Zhao, Volker Hessel, Michael G. Debije, Timothy Noël
Publié dans: Angewandte Chemie International Edition, Numéro 56/4, 2017, Page(s) 1050-1054, ISSN 1433-7851
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201611101

Book chapters (1)

Modeling of photochemical processes in continuous‐flow reactors`

Auteurs: Anca Roibu, Simon Kuhn
Publié dans: Photochemical Processes in Continuous-Flow Reactors: From Engineering Principles to Chemical Applications, 2017
Éditeur: World Scientific Publishing

Monographic books (1)

Photochemical Processes in Continuous-Flow Reactors - From Engineering Principles to Chemical Applications

Auteurs: Anca Roibu and Simon Kuhn
Publié dans: 2016, ISBN 978-1-78634-219-5
Éditeur: World Scientific
DOI: 10.1142/q0065