TUneable Multiferroics based on oxygen OCtahedral Structures

Livrables

WP7.3 deliverable

Progress report on non-scientific outreach actions

WP4.1 deliverable

Progress report on systematization and analysis of experimental data

WP8.3 deliverable

Annual Report

WP8.4 deliverable

Final Report

WP4.2 deliverable

Progress report on theoretical analysis and modelling

WP2.2 deliverable

Progress report on magnetic structure determination

WP6.3 deliverable

Progress report on microstructure/local properties measurements

WP7.5 deliverable

Progress report on non-scientific outreach actions

WP3.1 deliverable

Progress report on magnetic measurements of new BCOO materials

WP2.3 deliverable

Progress report on in situ synchrotron diffraction measurements

WP7.4 deliverable

Progress report on results of advertising activity

WP7.6 deliverable

Lists of publications and communications

WP3.2 deliverable

Progress report on dielectric studies on new BCOO materials

WP3.3 deliverable

Progress report on magnetoelectric measurements

WP4.3 deliverable

Progress report on optimization of compositions and preparation methods

WP2.1 deliverable

Progress report on crystal structure determination and refinement

WP7.2 deliverable

Lists of publications and communications

WP8.1 deliverable

Annual Report

WP2.4 deliverable

Progress report on in situ XRD and DSC measurement

WP7.1 deliverable

Progress report on trainings

WP6.1 deliverable

Progress report on study of field-induced effects in new BCOO films and layers

WP8.2 deliverable

Midterm Report

Publications

Electronic and magnetic properties of multiferroic ScFeO 3 available from diffraction experiments

Auteurs: S W Lovesey, D D Khalyavin
Publié dans: Journal of Physics: Condensed Matter, Numéro 29/45, 2017, Page(s) 455604, ISSN 0953-8984
Éditeur: Institute of Physics Publishing
DOI: 10.1088/1361-648X/aa860f

Magnetostriction-polarization coupling in multiferroic Mn2MnWO6

Auteurs: Man-Rong Li, Emma E. McCabe, Peter W. Stephens, Mark Croft, Liam Collins, Sergei V. Kalinin, Zheng Deng, Maria Retuerto, Arnab Sen Gupta, Haricharan Padmanabhan, Venkatraman Gopalan, Christoph P. Grams, Joachim Hemberger, Fabio Orlandi, Pascal Manuel, Wen-Min Li, Chang-Qing Jin, David Walker, Martha Greenblatt
Publié dans: Nature Communications, Numéro 8/1, 2017, Page(s) 2037(1-9), ISSN 2041-1723
Éditeur: Nature Publishing Group
DOI: 10.1038/s41467-017-02003-3

Bi-substituted Mg3Al–CO3 layered double hydroxides

Auteurs: Denis Sokol, Andrei N. Salak, Mário G. S. Ferreira, Aldona Beganskiene, Aivaras Kareiva
Publié dans: Journal of Sol-Gel Science and Technology, Numéro 85/1, 2018, Page(s) 221-230, ISSN 0928-0707
Éditeur: Kluwer Academic Publishers
DOI: 10.1007/s10971-017-4506-9

Temperature-Induced Reversible and Irreversible Transitions between Metastable Perovskite Phases in the BiFe1−yScyO3 Solid Solutions

Auteurs: Andrei Salak, Dmitry Khalyavin, Edwin Eardley, Nikolai Olekhnovich, Anatoli Pushkarev, Yury Radyush, Aleksandr Shilin, Vasili Rubanik
Publié dans: Crystals, Numéro 8/2, 2018, Page(s) 91, ISSN 2073-4352
Éditeur: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/cryst8020091

Sol-Gel Derived Lanthanide-Substituted Layered Double Hydroxides Mg 3 /Al 1-x Ln x

Auteurs: A. Smalenskaite, S. Şen, A.N. Salak, M.G.S. Ferreira, A. Beganskiene, A. Kareiva
Publié dans: Acta Physica Polonica A, Numéro 133/4, 2018, Page(s) 884-886, ISSN 0587-4246
Éditeur: Polska Akademia Nauk
DOI: 10.12693/APhysPolA.133.884

Sol-gel synthesis and characterization of hybrid inorganic-organic Tb(III)-terephthalate containing layered double hydroxides

Auteurs: A. Smalenskaite, A.N. Salak, M.G.S. Ferreira, R. Skaudzius, A. Kareiva
Publié dans: Optical Materials, Numéro 80, 2018, Page(s) 186-196, ISSN 0925-3467
Éditeur: Elsevier BV
DOI: 10.1016/j.optmat.2018.04.048

Unusual magnetic properties of the polar orthorhombic BiFe 0.5 Sc 0.5 O 3 perovskite

Auteurs: A.V. Fedorchenko, E.L. Fertman, A.N. Salak, V.A. Desnenko, E. Čižmár, A. Feher, A.I. Vaisburd, N.M. Olekhnovich, A.V. Pushkarev, Yu.V. Radyush, A. Zarkov, A. Kareiva
Publié dans: Journal of Magnetism and Magnetic Materials, Numéro 465, 2018, Page(s) 328-332, ISSN 0304-8853
Éditeur: Elsevier BV
DOI: 10.1016/j.jmmm.2018.06.015

Induced neodymium luminescence in sol–gel derived layered double hydroxides

Auteurs: Aurelija Smalenskaite, Andrei N. Salak, Aivaras Kareiva
Publié dans: Mendeleev Communications, Numéro 28/5, 2018, Page(s) 493-494, ISSN 0959-9436
Éditeur: Russian Academy of Sciences
DOI: 10.1016/j.mencom.2018.09.013

Spin and orbital ordering in TlMnO 3 : Neutron diffraction study

Auteurs: Dmitry D. Khalyavin, Pascal Manuel, Wei Yi, Alexei A. Belik
Publié dans: Physical Review B, Numéro 94/13, 2016, Page(s) 134412(1-7), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.94.134412

Magnetic ordering in pressure-induced phases with giant spin-driven ferroelectricity in multiferroic TbMnO 3

Auteurs: Noriki Terada, Dmitry D. Khalyavin, Pascal Manuel, Toyotaka Osakabe, Akiko Kikkawa, Hideaki Kitazawa
Publié dans: Physical Review B, Numéro 93/8, 2016, Page(s) 081104(1-5), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.93.081104

Magnetostriction-driven ground-state stabilization in 2H perovskites

Auteurs: D. G. Porter, M. S. Senn, D. D. Khalyavin, A. Cortese, N. Waterfield-Price, P. G. Radaelli, P. Manuel, H.-C. zur-Loye, C. Mazzoli, A. Bombardi
Publié dans: Physical Review B, Numéro 94/13, 2016, Page(s) 134404(1-11), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.94.134404

Impact of temperature dependent octahedra distortions on magnetic properties of Co-containing double layered hydroxides

Auteurs: R.Yu. Babkin, Yu.G. Pashkevich, A.V. Fedorchenko, E.L. Fertman, V.A. Desnenko, A.I. Prokhvatilov, N.N. Galtsov, D.E.L. Vieira, A.N. Salak
Publié dans: Journal of Magnetism and Magnetic Materials, Numéro 473, 2019, Page(s) 501-504, ISSN 0304-8853
Éditeur: Elsevier BV
DOI: 10.1016/j.jmmm.2018.10.077

Exchange bias effect in antiferromagnets containing ferromagnetic clusters

Auteurs: M. L. Pankratova, A. S. Kovalev
Publié dans: Low Temperature Physics, Numéro 44/11, 2018, Page(s) 1161-1167, ISSN 1063-777X
Éditeur: American Institute of Physics
DOI: 10.1063/1.5060970

Intrinsic Triple Order in A-site Columnar-Ordered Quadruple Perovskites: Proof of Concept

Auteurs: Alexei A. Belik, Dmitry D. Khalyavin, Lei Zhang, Yoshitaka Matsushita, Yoshio Katsuya, Masahiko Tanaka, Roger D. Johnson, Kazunari Yamaura
Publié dans: ChemPhysChem, Numéro 19/19, 2018, Page(s) 2449-2452, ISSN 1439-4235
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.201800593

Magneto-orbital texture in the perovskite modification of Mn 2 O 3

Auteurs: Dmitry D. Khalyavin, Roger D. Johnson, Pascal Manuel, Alexander A. Tsirlin, Artem M. Abakumov, Denis P. Kozlenko, Young Sun, Leonid Dubrovinsky, Sergey V. Ovsyannikov
Publié dans: Physical Review B, Numéro 98/1, 2018, Page(s) 014426(1-9), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.98.014426

Unraveling the complex magnetic structure of multiferroic pyroxene NaFeGe 2 O 6 : A combined experimental and theoretical study

Auteurs: Lei Ding, Pascal Manuel, Dmitry D. Khalyavin, Fabio Orlandi, Alexander A. Tsirlin
Publié dans: Physical Review B, Numéro 98/9, 2018, Page(s) 094416(1-10), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.98.094416

High-Pressure Synthesis, Structures, and Properties of Trivalent A-Site-Ordered Quadruple Perovskites RMn 7 O 12 (R = Sm, Eu, Gd, and Tb)

Auteurs: Lei Zhang, Noriki Terada, Roger D. Johnson, Dmitry D. Khalyavin, Pascal Manuel, Yoshio Katsuya, Masahiko Tanaka, Yoshitaka Matsushita, Kazunari Yamaura, Alexei A. Belik
Publié dans: Inorganic Chemistry, Numéro 57/10, 2018, Page(s) 5987-5998, ISSN 0020-1669
Éditeur: American Chemical Society
DOI: 10.1021/acs.inorgchem.8b00479

Phase formation in the (1-y)BiFeO3-yBiScO3 system under ambient and high pressure

Auteurs: A.N. Salak, D.D. Khalyavin, A.V. Pushkarev, Yu.V. Radyush, N.M. Olekhnovich, A.D. Shilin, V.V. Rubanik
Publié dans: Journal of Solid State Chemistry, Numéro 247, 2017, Page(s) 90-96, ISSN 0022-4596
Éditeur: Academic Press
DOI: 10.1016/j.jssc.2016.12.029

Multiferroic Bi0.65La0.35Fe0.5Sc0.5O3 perovskite: Magnetic and thermodynamic properties

Auteurs: E.L. Fertman, A.V. Fedorchenko, D.D. Khalyavin, A.N. Salak, A. Baran, V.A. Desnenko, O.V. Kotlyar, E. Čižmár, A. Feher, E.S. Syrkin, A.I. Vaisburd, N.M. Olekhnovich, A.V. Pushkarev, Yu.V. Radyush, A. Stanulis, A. Kareiva
Publié dans: Journal of Magnetism and Magnetic Materials, Numéro 429, 2017, Page(s) 177-181, ISSN 0304-8853
Éditeur: Elsevier BV
DOI: 10.1016/j.jmmm.2017.01.037

The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

Auteurs: Dmitry D. Khalyavin, Andrei N. Salak, Elena L. Fertman, Oleksandr V. Kotlyar, Edwin Eardley, Nikolai M. Olekhnovich, Anatoli V. Pushkarev, Yury V. Radyush, Alexey V. Fedorchenko, Vladimir A. Desnenko, Pascal Manuel, Lei Ding, Erik Čižmár, Alexander Feher
Publié dans: Chemical Communications, Numéro 55/32, 2019, Page(s) 4683-4686, ISSN 1359-7345
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9cc00472f

Lanthanide substitution effects in iron containing garnets

Auteurs: Olga Opuchovic, Andrei N. Salak, Jean-Luc Rehspringer, Aivaras Kareiva
Publié dans: Journal of Sol-Gel Science and Technology, Numéro 90/2, 2019, Page(s) 209-213, ISSN 0928-0707
Éditeur: Kluwer Academic Publishers
DOI: 10.1007/s10971-019-04962-z

Sonication accelerated formation of Mg-Al-phosphate layered double hydroxide via sol-gel prepared mixed metal oxides

Auteurs: Denis Sokol, Daniel E. L. Vieira, Aleksej Zarkov, Mário G. S. Ferreira, Aldona Beganskiene, Vasili V. Rubanik, Aleksandr D. Shilin, Aivaras Kareiva, Andrei N. Salak
Publié dans: Scientific Reports, Numéro 9/1, 2019, Page(s) 10419(1-9), ISSN 2045-2322
Éditeur: Nature Publishing Group
DOI: 10.1038/s41598-019-46910-5

High-temperature electrical conductivity of the xNBT–(1-x)LMT ceramics: verification of Meyer-Neldel rule

Auteurs: Saulius Rudys, Maksim Ivanov, Robertas Grigalaitis, Kazimieras Glemza, Juras Banys, Vasili V. Rubanik, Aleksandr D. Shilin, Andrei N. Salak
Publié dans: Integrated Ferroelectrics, Numéro 196/1, 2019, Page(s) 47-51, ISSN 1058-4587
Éditeur: Gordon and Breach Science Publishers
DOI: 10.1080/10584587.2019.1591986

High-Power Ultrasonic Synthesis and Magnetic-Field-Assisted Arrangement of Nanosized Crystallites of Cobalt-Containing Layered Double Hydroxides

Auteurs: Salak, Vieira, Lukienko, Shapovalov, Fedorchenko, Fertman, Pashkevich, Babkin, Shilin, Rubanik, Ferreira, Vieira
Publié dans: ChemEngineering, Numéro 3/3, 2019, Page(s) 62, ISSN 2305-7084
Éditeur: MDPI AG
DOI: 10.3390/chemengineering3030062

Evidence of Kittel type behaviour of the permittivity of a nanostructured high sensitivity piezoelectric

Auteurs: Sergejus Balčiūnas, Maksim Ivanov, Robertas Grigalaitis, Juras Banys, Harvey Amorín, Alicia Castro, Miguel Algueró
Publié dans: Journal of Applied Physics, Numéro 123/20, 2018, Page(s) 204103, ISSN 0021-8979
Éditeur: American Institute of Physics
DOI: 10.1063/1.5006011

Dielectric properties of Bi-substituted LDHs synthesized by co-precipitation and sol-gel methods

Auteurs: Denis Sokol, Maksim Ivanov, Andrei N. Salak, Robertas Grigalaitis, Juras Banys, Aivaras Kareiva
Publié dans: Materials Science-Poland, Numéro 37/2, 2019, Page(s) 190-195, ISSN 2083-134X
Éditeur: Sciendo
DOI: 10.2478/msp-2019-0035

Temperature-Induced Structural Transformations in Undoped and Eu 3+ -Doped Ruddlesden–Popper Phases Sr 2 SnO 4 and Sr 3 Sn 2 O 7 : Relation to the Impedance and Luminescence Behaviors

Auteurs: Andrius Stanulis, Arturas Katelnikovas, Andrei N. Salak, Povilas Seibutas, Maksim Ivanov, Robertas Grigalaitis, Juras Banys, Aivaras Kareiva, Rimantas Ramanauskas, Andrew R. Barron
Publié dans: Inorganic Chemistry, Numéro 58/17, 2019, Page(s) 11410-11419, ISSN 0020-1669
Éditeur: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00958

A comparative study of co-precipitation and sol-gel synthetic approaches to fabricate cerium-substituted Mg Al layered double hydroxides with luminescence properties

Auteurs: A. Smalenskaite, D.E.L. Vieira, A.N. Salak, M.G.S. Ferreira, A. Katelnikovas, A. Kareiva
Publié dans: Applied Clay Science, Numéro 143, 2017, Page(s) 175-183, ISSN 0169-1317
Éditeur: Elsevier BV
DOI: 10.1016/j.clay.2017.03.036

Sol-Gel Synthesis and Characterization of Non-Substituted and Europium- Substituted Layered Double Hydroxides Mg3/Al1-xEux

Auteurs: A. Smalenskaite, S. Sen, A. N. Salak, M G.S. Ferreira, R. Skaudzius, A. Katelnikovas, A. Kareiva
Publié dans: Current Inorganic Chemistry, Numéro 6/3, 2017, Page(s) 149-154, ISSN 1877-9441
Éditeur: Bentham Science Publishers
DOI: 10.2174/1877944107666170208154647

Reconstruction Effects on Surface Properties of Co/Mg/Al Layered Double Hydroxide

Auteurs: Denis SOKOL, Kristina KLEMKAITE-RAMANAUSKE, Aleksander KHINSKY, Kestutis BALTAKYS, Aldona BEGANSKIENE, Arunas BALTUSNIKAS, Jiri PINKAS, Aivaras KAREIVA
Publié dans: Materials Science, Numéro 23/2, 2017, Page(s) 144-149, ISSN 1392-1320
Éditeur: Kaunas University of Technology
DOI: 10.5755/j01.ms.23.2.15184

Magnetic Properties of the Bi 0.65 La 0.35 Fe 0.5 Sc 0.5 O 3 Perovskite

Auteurs: A.V. Fedorchenko, E.L. Fertman, V.A. Desnenko, O.V. Kotlyar, E. Čižmár, V.V. Shvartsman, D.C. Lupascu, S. Salamon, H. Wende, A.N. Salak, D.D. Khalyavin, N.M. Olekhnovich, A.V. Pushkarev, Yu.V. Radyush, A. Feher
Publié dans: Acta Physica Polonica A, Numéro 131/4, 2017, Page(s) 1069-1071, ISSN 0587-4246
Éditeur: Polska Akademia Nauk
DOI: 10.12693/APhysPolA.131.1069

Antisymmetric exchange in La-substituted BiFe0.5Sc0.5O3 system: symmetry adapted distortion modes approach

Auteurs: Dmitry D. Khalyavin, Andrei N. Salak, Pascal Manuel, Nikolai M. Olekhnovich, Anatoly V. Pushkarev, Yury V. Radysh, Alexey V. Fedorchenko, Elena L. Fertman, Vladimir A. Desnenko, Mário G.S. Ferreira
Publié dans: Zeitschrift für Kristallographie - Crystalline Materials, Numéro 230/12, 2015, Page(s) 767-774, ISSN 2196-7105
Éditeur: WALTER DE GRUYTER GMBH
DOI: 10.1515/zkri-2015-1873

Magnetic ordering and ferroelectricity in multiferroic 2 H − AgFeO 2 : Comparison between hexagonal and rhombohedral polytypes

Auteurs: Noriki Terada, Dmitry D. Khalyavin, Pascal Manuel, Yoshihiro Tsujimoto, Alexei A. Belik
Publié dans: Physical Review B, Numéro 91/9, 2015, Page(s) 094434(1-7), ISSN 1098-0121
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.91.094434

Ferroelectricity induced by ferriaxial crystal rotation and spin helicity in a B -site-ordered double-perovskite multiferroic In 2 NiMnO 6

Auteurs: Noriki Terada, Dmitry D. Khalyavin, Pascal Manuel, Wei Yi, Hiroyuki S. Suzuki, Naohito Tsujii, Yasutaka Imanaka, Alexei A. Belik
Publié dans: Physical Review B, Numéro 91/10, 2015, Page(s) 104413(1-6), ISSN 1098-0121
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.91.104413

Exchange bias phenomenon in (Nd1−xYx)2/3Ca1/3MnO3 (x = 0, 0.1) perovskites

Auteurs: E. L. Fertman, A. V. Fedorchenko, A. V. Kotlyar, V. A. Desnenko, E. Čižmár, A. Baran, D. D. Khalyavin, A. N. Salak, V. V. Shvartsman, A. Feher
Publié dans: Low Temperature Physics, Numéro 41/12, 2015, Page(s) 1001-1005, ISSN 1063-777X
Éditeur: American Institute of Physics
DOI: 10.1063/1.4936671

Charge ordering in Nd2/3Ca1/3MnO3: ESR and magnetometry study

Auteurs: D.M. Polishchuk, A.I. Tovstolytkin, E.L. Fertman, V.A. Desnenko, O. Kravchyna, D.D. Khalyavin, A.N. Salak, A.G. Anders, A. Feher
Publié dans: Journal of Magnetism and Magnetic Materials, Numéro 410, 2016, Page(s) 109-115, ISSN 0304-8853
Éditeur: Elsevier BV
DOI: 10.1016/j.jmmm.2016.03.022

Magnetic structure of an incommensurate phase of La-doped BiFe 0.5 Sc 0.5 O

Auteurs: D. D. Khalyavin, A. N. Salak, A. B. Lopes, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, E. L. Fertman, V. A. Desnenko, A. V. Fedorchenko, P. Manuel, A. Feher, J. M. Vieira, M. G. S. Ferreira
Publié dans: Physical Review B, Numéro 92/22, 2015, Page(s) 224428(1-7), ISSN 1098-0121
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.92.224428

Intermediate structural state in Bi1−x Pr x FeO3 ceramics at the rhombohedral–orthorhombic phase boundary

Auteurs: D. V. Karpinsky, I. O. Troyanchuk, M. Willinger, V. A. Khomchenko, A. N. Salak, V. Sikolenko, M. V. Silibin
Publié dans: Journal of Materials Science, Numéro 52/16, 2017, Page(s) 9355-9362, ISSN 0022-2461
Éditeur: Kluwer Academic Publishers
DOI: 10.1007/s10853-017-1152-0

Metastable perovskite Bi 1- x La x Fe 0.5 Sc 0.5 O 3 phases in the range of the compositional crossover

Auteurs: A. N. Salak, D. D. Khalyavin, I. Zamaraite, A. Stanulis, A. Kareiva, A. D. Shilin, V. V. Rubanik, Yu. V. Radyush, A. V. Pushkarev, N. M. Olekhnovich, M. Starykevich, R. Grigalaitis, M. Ivanov, J. Banys
Publié dans: Phase Transitions, Numéro 90/9, 2017, Page(s) 1-9, ISSN 0141-1594
Éditeur: Taylor & Francis
DOI: 10.1080/01411594.2017.1290802

Unusual magnetic structure of the high-pressure synthesized perovskites A CrO 3 ( A = Sc , In, Tl)

Auteurs: Lei Ding, Pascal Manuel, Dmitry D. Khalyavin, Fabio Orlandi, Yu Kumagai, Fumiyasu Oba, Wei Yi, Alexei A. Belik
Publié dans: Physical Review B, Numéro 95/5, 2017, Page(s) 054432(1-7), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.95.054432

Rich magnetoelectric phase diagrams of multiferroic single-crystal α − NaFeO 2

Auteurs: Noriki Terada, Yuta Ikedo, Hirohiko Sato, Dmitry D. Khalyavin, Pascal Manuel, Atsushi Miyake, Akira Matsuo, Masashi Tokunaga, Koichi Kindo
Publié dans: Physical Review B, Numéro 96/3, 2017, Page(s) 035128(1-14), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.96.035128

Temperature-induced phase transition from cycloidal to collinear antiferromagnetism in multiferroic Bi 0.9 Sm 0.1

Auteurs: R. D. Johnson, P. A. McClarty, D. D. Khalyavin, P. Manuel, P. Svedlindh, C. S. Knee
Publié dans: Physical Review B, Numéro 95/5, 2017, Page(s) 054420(1-7), ISSN 2469-9950
Éditeur: American Physical Society
DOI: 10.1103/PhysRevB.95.054420

Magnetic phenomena in Co-containing layered double hydroxides

Auteurs: Daniel E. L. Vieira, Andrei N. Salak, Alexey V. Fedorchenko, Yurii G. Pashkevich, Elena L. Fertman, Vladimir A. Desnenko, Roman Yu. Babkin, Erik Čižmár, Alexander Feher, Augusto B. Lopes, Mário G. S. Ferreira
Publié dans: Low Temperature Physics, Numéro 43/8, 2017, Page(s) 977-981, ISSN 1063-777X
Éditeur: American Institute of Physics
DOI: 10.1063/1.5001299

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