Radical Solutions for Hysteresis in Single-Molecule Magnets

Project Information

RadMag

Grant agreement ID: 646740

DOI

10.3030/646740

Project closed

EC signature date 20 May 2015

Start date 1 September 2015

End date 28 February 2021

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 584 202,30

EU contribution

€ 1 584 202,30

Coordinated by

THE UNIVERSITY OF SUSSEX
United Kingdom

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (21)

Double Ligand Activation in Silyl-Substituted Rare-Earth Cyclobutadienyl Complexes

Author(s): Anindita Chakraborty, Benjamin M. Day, James P. Durrant, Mian He, Jinkui Tang, Richard A. Layfield
Published in: Organometallics, Issue 39/1, 2019, Page(s) 8-12, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.9b00763

Coupling of Nitric Oxide and Release of Nitrous Oxide from Rare-Earth-Dinitrosyliron Complexes

Author(s): Arun Kumar Bar, María José Heras Ojea, Jinkui Tang, Richard A. Layfield
Published in: Journal of the American Chemical Society, Issue 142/9, 2020, Page(s) 4104-4107, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b13571

Carbonyl Back-Bonding Influencing the Rate of Quantum Tunnelling in a Dysprosium Metallocene Single-Molecule Magnet

Author(s): Richard Collins, María José Heras Ojea, Akseli Mansikkamäki, Jinkui Tang, Richard A. Layfield
Published in: Inorganic Chemistry, Issue 59/1, 2019, Page(s) 642-647, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b02895

Enhanced single-molecule magnetism in dysprosium complexes of a pristine cyclobutadienyl ligand

Author(s): James P. Durrant, Jinkui Tang, Akseli Mansikkamäki, Richard A. Layfield
Published in: Chemical Communications, Issue 56/34, 2020, Page(s) 4708-4711, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc01722a

Activation of C–H bonds by rare-earth metallocene-butyl complexes

Author(s): Richard Grindell, Benjamin M. Day, Fu-Sheng Guo, Thomas Pugh, Richard A. Layfield
Published in: Chemical Communications, Issue 53/72, 2017, Page(s) 9990-9993, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7cc05597h

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling

Author(s): Thomas Pugh, Nicholas F. Chilton, Richard A. Layfield
Published in: Chem. Sci., Issue 8/3, 2017, Page(s) 2073-2080, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6SC04465D

A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

Author(s): Thomas Pugh, Nicholas F. Chilton, Richard A. Layfield
Published in: Angewandte Chemie International Edition, Issue 55/37, 2016, Page(s) 11082-11085, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201604346

Magnetic frustration in a hexaazatrinaphthylene-bridged trimetallic dysprosium single-molecule magnet

Author(s): Richard Grindell, Veacheslav Vieru, Thomas Pugh, Liviu F. Chibotaru, Richard A. Layfield
Published in: Dalton Trans., Issue 45/42, 2016, Page(s) 16556-16560, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6DT01763K

Strong Exchange Coupling in a Trimetallic Radical-Bridged Cobalt(II)-Hexaazatrinaphthylene Complex

Author(s): Jani O. Moilanen, Nicholas F. Chilton, Benjamin M. Day, Thomas Pugh, Richard A. Layfield
Published in: Angewandte Chemie International Edition, Issue 55/18, 2016, Page(s) 5521-5525, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201600694

Strong direct exchange coupling and single-molecule magnetism in indigo-bridged lanthanide dimers

Author(s): Fu-Sheng Guo, Richard A. Layfield
Published in: Chem. Commun., Issue 53/21, 2017, Page(s) 3130-3133, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7CC01046J

Single-molecule magnet properties of a monometallic dysprosium pentalene complex

Author(s): Alexander F. R. Kilpatrick, Fu-Sheng Guo, Benjamin M. Day, Akseli Mansikkamäki, Richard A. Layfield, F. Geoffrey N. Cloke
Published in: Chemical Communications, Issue 54/51, 2018, Page(s) 7085-7088, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc03516d

Cyclopentadienyl Ligands in Lanthanide Single-Molecule Magnets: One Ring To Rule Them All?

Author(s): Benjamin M. Day, Fu-Sheng Guo, Richard A. Layfield
Published in: Accounts of Chemical Research, Issue 51/8, 2018, Page(s) 1880-1889, ISSN 0001-4842
Publisher: American Chemical Society
DOI: 10.1021/acs.accounts.8b00270

Rare-Earth Cyclobutadienyl Sandwich Complexes: Synthesis, Structure and Dynamic Magnetic Properties

Author(s): Benjamin M. Day, Fu-Sheng Guo, Sean R. Giblin, Akira Sekiguchi, Akseli Mansikkamäki, Richard A. Layfield
Published in: Chemistry - A European Journal, Issue 24/63, 2018, Page(s) 16779-16782, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201804776

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

Author(s): Fu-Sheng Guo, Benjamin M. Day, Yan-Cong Chen, Ming-Liang Tong, Akseli Mansikkamäki, Richard A. Layfield
Published in: Science, Issue 362/6421, 2018, Page(s) 1400-1403, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aav0652

From double-shelled grids to supramolecular frameworks

Author(s): Jianfeng Wu, Mei Guo, Xiao-Lei Li, Lang Zhao, Qing-Fu Sun, Richard A. Layfield, Jinkui Tang
Published in: Chemical Communications, Issue 54/85, 2018, Page(s) 12097-12100, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc06411c

Main Group Chemistry at the Interface with Molecular Magnetism

Author(s): Fu-Sheng Guo, Arun Kumar Bar, Richard A. Layfield
Published in: Chemical Reviews, Issue 119/14, 2019, Page(s) 8479-8505, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.9b00103

Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes

Author(s): Jani O. Moilanen, Akseli Mansikkamäki, Manu Lahtinen, Fu-Sheng Guo, Elina Kalenius, Richard A. Layfield, Liviu F. Chibotaru
Published in: Dalton Trans., Issue 46/39, 2017, Page(s) 13582-13589, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7dt02565c

Isolation of a Perfectly Linear Uranium(II) Metallocene

Author(s): Fu‐Sheng Guo, Nikolaos Tsoureas, Guo‐Zhang Huang, Ming‐Liang Tong, Akseli Mansikkamäki, Richard A. Layfield
Published in: Angewandte Chemie International Edition, Issue 59/6, 2020, Page(s) 2299-2303, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201912663

Uranium( iv ) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

Author(s): Nikolaos Tsoureas, Akseli Mansikkamäki, Richard A. Layfield
Published in: Chemical Communications, Issue 56/6, 2020, Page(s) 944-947, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc09018e

Fulvalene as a platform for the synthesis of a dimetallic dysprosocenium single-molecule magnet

Author(s): Mian He, Fu-Sheng Guo, Jinkui Tang, Akseli Mansikkamäki, Richard A. Layfield
Published in: Chemical Science, Issue 11/22, 2020, Page(s) 5745-5752, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc02033h

Uranocenium: Synthesis, Structure, and Chemical Bonding

Author(s): Fu‐Sheng Guo, Yan‐Cong Chen, Ming‐Liang Tong, Akseli Mansikkamäki, Richard A. Layfield
Published in: Angewandte Chemie International Edition, Issue 58/30, 2019, Page(s) 10163-10167, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201903681

Book chapters (2)

Lanthanide Organometallics as Single-Molecule Magnets

Author(s): María José Heras Ojea, Lewis C. H. Maddock, Richard A. Layfield
Published in: Organometallic Magnets, Issue 64, 2019, Page(s) 253-280, ISBN 978-3-030-26008-8
Publisher: Springer International Publishing
DOI: 10.1007/3418_2019_26

Electronic structure and magnetic properties of rare-earth organometallic sandwich compounds

Author(s): Richard Collins, James P. Durrant, Mian He, Richard A. Layfield
Published in: Including Actinides, Issue 55, 2019, Page(s) 89-121, ISBN 9780-444642974
Publisher: Elsevier
DOI: 10.1016/bs.hpcre.2019.05.002