Unconventional Bifunctional Catalysts

Project Information

UNBICAT

Grant agreement ID: 647550

DOI

10.3030/647550

Project closed

EC signature date 12 May 2015

Start date 1 September 2015

End date 31 August 2021

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 987 750,00

EU contribution

€ 1 987 750,00

Coordinated by

UNIVERSIDAD AUTONOMA DE MADRID
Spain

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (20)

Organocatalytic Strategies for the Development of the Enantioselective Inverse‐electron‐demand Hetero‐Diels‐Alder Reaction

Author(s): Víctor Laina‐Martín, Jose A. Fernández‐Salas, José Alemán
Published in: Chemistry – A European Journal, Issue 27/49, 2021, Page(s) 12509-12520, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202101696

Visible Light Photocatalytic Synthesis of Tetrahydroquinolines Under Batch and Flow Conditions

Author(s): Daniel González‐Muñoz, José Luis Nova‐Fernández, Ada Martinelli, Gustavo Pascual‐Coca, Silvia Cabrera, José Alemán
Published in: European Journal of Organic Chemistry, Issue 2020/37, 2020, Page(s) 5995-5999, ISSN 1434-193X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejoc.202001018

Asymmetric [2+2] photocycloaddition via charge transfer complex for the synthesis of tricyclic chiral ethers

Author(s): Ana M. Martínez-Gualda, Pablo Domingo-Legarda, Thomas Rigotti, Sergio Díaz-Tendero, Alberto Fraile, José Alemán
Published in: Chemical Communications, Issue 57/24, 2021, Page(s) 3046-3049, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc00035g

Metal-free visible light-promoted synthesis of isothiazoles: a catalytic approach for N–S bond formation from iminyl radicals under batch and flow conditions

Author(s): María Jesús Cabrera-Afonso, Sara Cembellín, Adnane Halima-Salem, Mateo Berton, Leyre Marzo, Abdellah Miloudi, M. Carmen Maestro, José Alemán
Published in: Green Chemistry, Issue 22/20, 2020, Page(s) 6792-6797, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0gc02618b

Enhancing Visible-Light Photocatalysis via Endohedral Functionalization of Single-Walled Carbon Nanotubes with Organic Dyes

Author(s): Daniel González-Muñoz, Ana Martín-Somer, Klara Strobl, Silvia Cabrera, Pedro J. De Pablo, Sergio Díaz-Tendero, Matías Blanco, José Alemán
Published in: ACS Applied Materials & Interfaces, Issue 13/21, 2021, Page(s) 24877-24886, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.1c04679

Thiol–ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides

Author(s): Andrea Guerrero-Corella, Ana María Martinez-Gualda, Fereshteh Ahmadi, Enrique Ming, Alberto Fraile, José Alemán
Published in: Chemical Communications, Issue 53/75, 2017, Page(s) 10463-10466, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7CC05672A

Intramolecular Hydrogen Bond Activation: Thiourea-Organocatalyzed Enantioselective 1,3-Dipolar Cycloaddition of Salicylaldehyde-Derived Azomethine Ylides with Nitroalkenes

Author(s): Francisco Esteban, Wioleta Cieślik, Enrique M. Arpa, Andrea Guerrero-Corella, Sergio Díaz-Tendero, Josefina Perles, José A. Fernández-Salas, Alberto Fraile, José Alemán
Published in: ACS Catalysis, Issue 8/3, 2018, Page(s) 1884-1890, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.7b03553

Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions

Author(s): Alberto F. Garrido-Castro, Houcine Choubane, Mortada Daaou, M. Carmen Maestro, José Alemán
Published in: Chemical Communications, Issue 53/55, 2017, Page(s) 7764-7767, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7CC03724D

Visible-Light Photocatalytic Intramolecular Cyclopropane Ring Expansion

Author(s): Javier Luis-Barrera, Víctor Laina-Martín, Thomas Rigotti, Francesca Peccati, Xavier Solans-Monfort, Mariona Sodupe, Rubén Mas-Ballesté, Marta Liras, José Alemán
Published in: Angewandte Chemie International Edition, Issue 56/27, 2017, Page(s) 7826-7830, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201703334

2-Hydroxybenzophenone as Chemical Auxiliary for the Activation of Ketiminoesters in the Highly Enantioselective Addition to Nitroalkenes under Bifunctional Catalysis

Author(s): José Alemán, Alberto Fraile, Andrea Guerrero, Francisco Esteban, Mario Parra, Manuel Iniesta, Ana Somer, Sergio Diaz-Tendero
Published in: Angewandte Chemie International Edition, 2018, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201800435

Old tricks, new dogs: organocatalytic dienamine activation of α,β-unsaturated aldehydes

Author(s): Vanesa Marcos, José Alemán
Published in: Chem. Soc. Rev., Issue 45/24, 2016, Page(s) 6812-6832, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6CS00438E

Asymmetric Synthesis of Rauhut–Currier type Products by a Regioselective Mukaiyama Reaction under Bifunctional Catalysis

Author(s): María Frias, Rubén Mas-Ballesté, Saira Arias, Cuauhtemoc Alvarado, José Alemán
Published in: Journal of the American Chemical Society, Issue 139/2, 2017, Page(s) 672-679, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6b07851

Pt( ii ) coordination complexes as visible light photocatalysts for the oxidation of sulfides using batch and flow processes

Author(s): Antonio Casado-Sánchez, Rocío Gómez-Ballesteros, Francisco Tato, Francisco J. Soriano, Gustavo Pascual-Coca, Silvia Cabrera, José Alemán
Published in: Chem. Commun., Issue 52/58, 2016, Page(s) 9137-9140, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6CC02452A

A Bifunctional Photoaminocatalyst for the Alkylation of Aldehydes: Design, Analysis, and Mechanistic Studies

Author(s): Thomas Rigotti, Antonio Casado-Sánchez, Silvia Cabrera, Raúl Pérez-Ruiz, Marta Liras, Víctor A. de la Peña O’Shea, José Alemán
Published in: ACS Catalysis, Issue 8/7, 2018, Page(s) 5928-5940, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.8b01331

Asymmetric synthesis of Rauhut–Currier-type esters via Mukaiyama–Michael reaction to acylphosphonates under bifunctional catalysis

Author(s): Víctor Laina-Martín, Roberto del Río-Rodríguez, Sergio Díaz-Tendero, Jose A. Fernández-Salas, José Alemán
Published in: Chemical Communications, Issue 54/99, 2018, Page(s) 13941-13944, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc07561a

Asymmetric induction in photocatalysis – Discovering a new side to light-driven chemistry

Author(s): Alberto F. Garrido-Castro, M. Carmen Maestro, José Alemán
Published in: Tetrahedron Letters, Issue 59/14, 2018, Page(s) 1286-1294, ISSN 0040-4039
Publisher: Elsevier BV
DOI: 10.1016/j.tetlet.2018.02.040

Unlocking the direct photocatalytic difluoromethylation of CN bonds

Author(s): Alberto F. Garrido-Castro, Andrea Gini, M. Carmen Maestro, José Alemán
Published in: Chemical Communications, Issue 56/26, 2020, Page(s) 3769-3772, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc01353f

Metal–Organic Frameworks (MOFs) and Covalent Organic Frameworks (COFs) Applied to Photocatalytic Organic Transformations

Author(s): Alberto López-Magano, Alicia Jiménez-Almarza, Jose Alemán, Rubén Mas-Ballesté
Published in: Catalysts, Issue 10/7, 2020, Page(s) 720, ISSN 2073-4344
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal10070720

Intramolecular Homolytic Substitution Enabled by Photoredox Catalysis: Sulfur, Phosphorus, and Silicon Heterocycle Synthesis from Aryl Halides

Author(s): Alberto F. Garrido-Castro, Noelia Salaverri, M. Carmen Maestro, José Alemán
Published in: Organic Letters, Issue 21/13, 2019, Page(s) 5295-5300, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.9b01911

Enantioselective Aminocatalytic [2 + 2] Cycloaddition through Visible Light Excitation

Author(s): Thomas Rigotti, Rubén Mas-Ballesté, José Alemán
Published in: ACS Catalysis, Issue 10/9, 2020, Page(s) 5335-5346, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.0c01413