Late First-Row Transition Metal-Oxo Complexes for C–H Bond Activation

Project Information

HurdlingOxoWall

Grant agreement ID: 678202

DOI 10.3030/678202

Project closed

EC signature date 15 December 2015

Start date 1 March 2016

End date 28 February 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 499 865,00

EU contribution € 1 499 865,00

Coordinated by

THE PROVOST, FELLOWS, FOUNDATION SCHOLARS & THE OTHER MEMBERS OF BOARD, OF THE COLLEGE OF THE HOLY & UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN
Ireland

Publications

Peer reviewed articles (20)

High-Valent d 7 Ni III versus d 8 Cu III Oxidants in PCET

Author(s): Duenpen Unjaroen, Robert Gericke, Marta Lovisari, Daniel Nelis, Prasenjit Mondal, Paolo Pirovano, Brendan Twamley, Erik R. Farquhar, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 58/24, 2019, Page(s) 16838-16848, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b03101

Catechol oxidase activity of comparable dimanganese and dicopper complexes

Author(s): Adriana M. Magherusan, Daniel N. Nelis, Brendan Twamley, Aidan R. McDonald
Published in: Dalton Transactions, Issue 47/43, 2018, Page(s) 15555-15564, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt01378k

Reactivity Properties of Mixed- and High-Valent Bis(μ-Hydroxide)-Dinickel Complexes.

Author(s): Giuseppe Spedalotto; Marta Lovisari; Aidan R. McDonald
Published in: ACS Omega, Issue 1, 2021, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/acsomega.1c04225

Phenol Oxidation by a Nickel(III)–Fluoride Complex: Exploring the Influence of the Proton Accepting Ligand in PCET Oxidation

Author(s): Prasenjit Mondal, Aidan R. McDonald
Published in: Chemistry – A European Journal, Issue 26/44, 2020, Page(s) 10083-10089, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202002135

Rapid Iron(III)−Fluoride-Mediated Hydrogen Atom Transfer

Author(s): Dr. Chakadola Panda, Lorna M. Doyle, Dr. Robert Gericke, Dr. Aidan R. McDonald
Published in: Angewandte Chemie, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202112683

Fast Hydrocarbon Oxidation by a High‐Valent Nickel–Fluoride Complex

Author(s): Prasenjit Mondal, Marta Lovisari, Brendan Twamley, Aidan R. McDonald
Published in: Angewandte Chemie International Edition, Issue 59/31, 2020, Page(s) 13044-13050, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004639

Carboxamidate Ligand Noninnocence in Proton Coupled Electron Transfer

Author(s): Caitilín McManus, Prasenjit Mondal, Marta Lovisari, Brendan Twamley, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 58/7, 2019, Page(s) 4515-4523, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00055

Unexpected Intramolecular Phosphite-Mediated Amide Coupling To Yield 3,5-Dioxo-1-Piperazines

Author(s): Philipp Heim; Brendan Twamley; John E. O'Brien; Aidan R. McDonald
Published in: Chemistry Select, Issue 1, 2021, ISSN 2365-6549
Publisher: Wiley
DOI: 10.1002/slct.202102576

A Mn II Mn III ‐Peroxide Complex Capable of Aldehyde Deformylation

Author(s): Adriana M. Magherusan, Subhasree Kal, Daniel N. Nelis, Lorna M. Doyle, Erik R. Farquhar, Lawrence Que, Aidan R. McDonald
Published in: Angewandte Chemie International Edition, Issue 58/17, 2019, Page(s) 5718-5722, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201900717

Comparing Metal-Halide and -Oxygen Adducts in Oxidative C/O-H Activation: Au III-Cl versus Au III-OH

Author(s): Marta Lovisari; Robert Gericke; Brendan Twamley; Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 2, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c02222

Modulation of Nickel Pyridinedicarboxamidate Complexes to Explore the Properties of High-valent Oxidants

Author(s): Paolo Pirovano, Brendan Twamley, Aidan R. McDonald
Published in: Chemistry - A European Journal, Issue 24/20, 2018, Page(s) 5238-5245, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201704618

Indirect evidence for a Ni III –oxyl oxidant in the reaction of a Ni II complex with peracid

Author(s): Paolo Pirovano, Abigail R. Berry, Marcel Swart, Aidan R. McDonald
Published in: Dalton Transactions, Issue 47/1, 2018, Page(s) 246-250, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7DT03316H

Synthetic High-Valent M-O-X Oxidants

Author(s): Paolo Pirovano, Aidan R. McDonald
Published in: European Journal of Inorganic Chemistry, Issue 2018/5, 2018, Page(s) 547-560, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201701072

Hydrogen Atom Transfer by a High-Valent Nickel-Chloride Complex

Author(s): Prasenjit Mondal, Paolo Pirovano, Ankita Das, Erik R. Farquhar, Aidan R. McDonald
Published in: Journal of the American Chemical Society, Issue 140/5, 2018, Page(s) 1834-1841, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.7b11953

Tuning the Reactivity of Terminal Nickel(III)–Oxygen Adducts for C–H Bond Activation

Author(s): Paolo Pirovano, Erik R. Farquhar, Marcel Swart, and Aidan R. McDonald
Published in: Journal of the American Chemical Society, 2016, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6b08406

Synthesis and characterisation of a mesocyclic tripodal triamine ligand

Author(s): Andrew D. Ure, Isabel Abánades Lázaro, Michelle Cotter, Aidan R. McDonald
Published in: Organic and Biomolecular Chemistry, 2016, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C5OB01556A

Hydrogen Atom Transfer Oxidation by a Gold–Hydroxide Complex

Author(s): Marta Lovisari, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 59/6, 2020, Page(s) 3659-3665, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b03225

Mimicking Class I b Mn 2 -Ribonucleotide Reductase: A Mn II 2 Complex and Its Reaction with Superoxide

Author(s): Adriana M. Magherusan, Ang Zhou, Erik R. Farquhar, Max García-Melchor, Brendan Twamley, Lawrence Que, Aidan R. McDonald
Published in: Angewandte Chemie International Edition, Issue 57/4, 2018, Page(s) 918-922, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201709806

Preparation and Characterisation of a Bis‐μ‐Hydroxo‐Ni III 2 Complex

Author(s): Giuseppe Spedalotto, Robert Gericke, Marta Lovisari, Erik R. Farquhar, Brendan Twamley, Aidan R. McDonald
Published in: Chemistry – A European Journal, Issue 25/51, 2019, Page(s) 11983-11990, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201902812

Oxo-Free Hydrocarbon Oxidation by an Iron(III)-Isoporphyrin Complex

Author(s): Robert Gericke, Lorna M. Doyle, Erik R. Farquhar, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 59/19, 2020, Page(s) 13952-13961, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c01618