Late First-Row Transition Metal-Oxo Complexes for C–H Bond Activation

Project Information

HurdlingOxoWall

Grant agreement ID: 678202

DOI

10.3030/678202

Project closed

EC signature date 15 December 2015

Start date 1 March 2016

End date 28 February 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 499 865,00

EU contribution

€ 1 499 865,00

Coordinated by

THE PROVOST, FELLOWS, FOUNDATION SCHOLARS & THE OTHER MEMBERS OF BOARD, OF THE COLLEGE OF THE HOLY & UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN
Ireland

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (20)

High-Valent d 7 Ni III versus d 8 Cu III Oxidants in PCET

Author(s): Duenpen Unjaroen, Robert Gericke, Marta Lovisari, Daniel Nelis, Prasenjit Mondal, Paolo Pirovano, Brendan Twamley, Erik R. Farquhar, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 58/24, 2019, Page(s) 16838-16848, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b03101

Catechol oxidase activity of comparable dimanganese and dicopper complexes

Author(s): Adriana M. Magherusan, Daniel N. Nelis, Brendan Twamley, Aidan R. McDonald
Published in: Dalton Transactions, Issue 47/43, 2018, Page(s) 15555-15564, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt01378k

Reactivity Properties of Mixed- and High-Valent Bis(μ-Hydroxide)-Dinickel Complexes.

Author(s): Giuseppe Spedalotto; Marta Lovisari; Aidan R. McDonald
Published in: ACS Omega, Issue 1, 2021, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/acsomega.1c04225

Phenol Oxidation by a Nickel(III)–Fluoride Complex: Exploring the Influence of the Proton Accepting Ligand in PCET Oxidation

Author(s): Prasenjit Mondal, Aidan R. McDonald
Published in: Chemistry – A European Journal, Issue 26/44, 2020, Page(s) 10083-10089, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202002135

Rapid Iron(III)−Fluoride-Mediated Hydrogen Atom Transfer

Author(s): Dr. Chakadola Panda, Lorna M. Doyle, Dr. Robert Gericke, Dr. Aidan R. McDonald
Published in: Angewandte Chemie, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202112683

Fast Hydrocarbon Oxidation by a High‐Valent Nickel–Fluoride Complex

Author(s): Prasenjit Mondal, Marta Lovisari, Brendan Twamley, Aidan R. McDonald
Published in: Angewandte Chemie International Edition, Issue 59/31, 2020, Page(s) 13044-13050, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202004639

Carboxamidate Ligand Noninnocence in Proton Coupled Electron Transfer

Author(s): Caitilín McManus, Prasenjit Mondal, Marta Lovisari, Brendan Twamley, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 58/7, 2019, Page(s) 4515-4523, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b00055

Unexpected Intramolecular Phosphite-Mediated Amide Coupling To Yield 3,5-Dioxo-1-Piperazines

Author(s): Philipp Heim; Brendan Twamley; John E. O'Brien; Aidan R. McDonald
Published in: Chemistry Select, Issue 1, 2021, ISSN 2365-6549
Publisher: Wiley
DOI: 10.1002/slct.202102576

A Mn II Mn III ‐Peroxide Complex Capable of Aldehyde Deformylation

Author(s): Adriana M. Magherusan, Subhasree Kal, Daniel N. Nelis, Lorna M. Doyle, Erik R. Farquhar, Lawrence Que, Aidan R. McDonald
Published in: Angewandte Chemie International Edition, Issue 58/17, 2019, Page(s) 5718-5722, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201900717

Comparing Metal-Halide and -Oxygen Adducts in Oxidative C/O-H Activation: Au III-Cl versus Au III-OH

Author(s): Marta Lovisari; Robert Gericke; Brendan Twamley; Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 2, 2021, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c02222

Modulation of Nickel Pyridinedicarboxamidate Complexes to Explore the Properties of High-valent Oxidants

Author(s): Paolo Pirovano, Brendan Twamley, Aidan R. McDonald
Published in: Chemistry - A European Journal, Issue 24/20, 2018, Page(s) 5238-5245, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201704618

Indirect evidence for a Ni III –oxyl oxidant in the reaction of a Ni II complex with peracid

Author(s): Paolo Pirovano, Abigail R. Berry, Marcel Swart, Aidan R. McDonald
Published in: Dalton Transactions, Issue 47/1, 2018, Page(s) 246-250, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7DT03316H

Synthetic High-Valent M-O-X Oxidants

Author(s): Paolo Pirovano, Aidan R. McDonald
Published in: European Journal of Inorganic Chemistry, Issue 2018/5, 2018, Page(s) 547-560, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.201701072

Hydrogen Atom Transfer by a High-Valent Nickel-Chloride Complex

Author(s): Prasenjit Mondal, Paolo Pirovano, Ankita Das, Erik R. Farquhar, Aidan R. McDonald
Published in: Journal of the American Chemical Society, Issue 140/5, 2018, Page(s) 1834-1841, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.7b11953

Tuning the Reactivity of Terminal Nickel(III)–Oxygen Adducts for C–H Bond Activation

Author(s): Paolo Pirovano, Erik R. Farquhar, Marcel Swart, and Aidan R. McDonald
Published in: Journal of the American Chemical Society, 2016, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6b08406

Synthesis and characterisation of a mesocyclic tripodal triamine ligand

Author(s): Andrew D. Ure, Isabel Abánades Lázaro, Michelle Cotter, Aidan R. McDonald
Published in: Organic and Biomolecular Chemistry, 2016, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C5OB01556A

Hydrogen Atom Transfer Oxidation by a Gold–Hydroxide Complex

Author(s): Marta Lovisari, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 59/6, 2020, Page(s) 3659-3665, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.9b03225

Mimicking Class I b Mn 2 -Ribonucleotide Reductase: A Mn II 2 Complex and Its Reaction with Superoxide

Author(s): Adriana M. Magherusan, Ang Zhou, Erik R. Farquhar, Max García-Melchor, Brendan Twamley, Lawrence Que, Aidan R. McDonald
Published in: Angewandte Chemie International Edition, Issue 57/4, 2018, Page(s) 918-922, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201709806

Preparation and Characterisation of a Bis‐μ‐Hydroxo‐Ni III 2 Complex

Author(s): Giuseppe Spedalotto, Robert Gericke, Marta Lovisari, Erik R. Farquhar, Brendan Twamley, Aidan R. McDonald
Published in: Chemistry – A European Journal, Issue 25/51, 2019, Page(s) 11983-11990, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201902812

Oxo-Free Hydrocarbon Oxidation by an Iron(III)-Isoporphyrin Complex

Author(s): Robert Gericke, Lorna M. Doyle, Erik R. Farquhar, Aidan R. McDonald
Published in: Inorganic Chemistry, Issue 59/19, 2020, Page(s) 13952-13961, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c01618