Dynamic Nuclear Polarization at ultra-fast sample spinning and ultra-low temperature

Project Information

ULT-MAS-DNP

Grant agreement ID: 682895

DOI 10.3030/682895

Project closed

EC signature date 27 June 2016

Start date 1 July 2016

End date 30 June 2021

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 999 805,42

EU contribution € 1 999 805,42

Coordinated by

COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
France

Publications

Peer reviewed articles (15)

Disclosing Interfaces of ZnO Nanocrystals Using Dynamic Nuclear Polarization: Sol‐Gel versus Organometallic Approach

Author(s): Daniel Lee, Małgorzata Wolska‐Pietkiewicz, Saumya Badoni, Agnieszka Grala, Janusz Lewiński, Gaël De Paëpe
Published in: Angewandte Chemie, Issue 131/48, 2019, Page(s) 17323-17328, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201906726

Targeted DNP for biomolecular solid-state NMR

Author(s): Diego Gauto, Ons Dakhlaoui, Ildefonso Marin-Montesinos, Sabine Hediger, Gaël De Paëpe
Published in: Chemical Science, Issue 12/18, 2021, Page(s) 6223-6237, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc06959k

Welcoming natural isotopic abundance in solid-state NMR: probing π-stacking and supramolecular structure of organic nanoassemblies using DNP

Author(s): Katharina Märker, Subhradip Paul, Carlos Fernández-de-Alba, Daniel Lee, Jean-Marie Mouesca, Sabine Hediger, Gaël De Paëpe
Published in: Chemical Science, Issue 8/2, 2017, Page(s) 974-987, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c6sc02709a

Efficient cross-effect dynamic nuclear polarization without depolarization in high-resolution MAS NMR

Author(s): Frédéric Mentink-Vigier, Guinevere Mathies, Yangping Liu, Anne-Laure Barra, Marc A. Caporini, Daniel Lee, Sabine Hediger, Robert G. Griffin, Gaël De Paëpe
Published in: Chemical Science, Issue 8/12, 2017, Page(s) 8150-8163, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7SC02199B

Efficient 2D double-quantum solid-state NMR spectroscopy with large spectral widths

Author(s): Katharina Märker, Sabine Hediger, Gaël De Paëpe
Published in: Chemical Communications, Issue 53/65, 2017, Page(s) 9155-9158, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7CC04890D

Fast and accurate MAS–DNP simulations of large spin ensembles

Author(s): Frédéric Mentink-Vigier, Shimon Vega, Gaël De Paëpe
Published in: Physical Chemistry Chemical Physics, Issue 19/5, 2017, Page(s) 3506-3522, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/C6CP07881H

Computationally Assisted Design of Polarizing Agents for Dynamic Nuclear Polarization Enhanced NMR: The AsymPol Family

Author(s): Frédéric Mentink-Vigier, Ildefonso Marin-Montesinos, Anil P. Jagtap, Thomas Halbritter, Johan van Tol, Sabine Hediger, Daniel Lee, Snorri Th. Sigurdsson, Gaël De Paëpe
Published in: Journal of the American Chemical Society, Issue 140/35, 2018, Page(s) 11013-11019, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b04911

De novo prediction of cross-effect efficiency for magic angle spinning dynamic nuclear polarization

Author(s): Frédéric Mentink-Vigier, Anne-Laure Barra, Johan van Tol, Sabine Hediger, Daniel Lee, Gaël De Paëpe
Published in: Physical Chemistry Chemical Physics, Issue 21/4, 2019, Page(s) 2166-2176, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cp06819d

Structural Fingerprinting of Protein Aggregates by Dynamic Nuclear Polarization-Enhanced Solid-State NMR at Natural Isotopic Abundance

Author(s): Adam N. Smith, Katharina Märker, Talia Piretra, Jennifer C. Boatz, Irina Matlahov, Ravindra Kodali, Sabine Hediger, Patrick C. A. van der Wel, Gaël De Paëpe
Published in: Journal of the American Chemical Society, Issue 140/44, 2018, Page(s) 14576-14580, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b09002

Solvent signal suppression for high-resolution MAS-DNP

Author(s): Daniel Lee, Sachin R. Chaudhari, Gaël De Paëpe
Published in: Journal of Magnetic Resonance, Issue 278, 2017, Page(s) 60-66, ISSN 1090-7807
Publisher: Academic Press
DOI: 10.1016/j.jmr.2017.03.012

Sparsely Pillared Graphene Materials for High-Performance Supercapacitors: Improving Ion Transport and Storage Capacity

Author(s): Harish Banda, Sandy Périé, Barbara Daffos, Pierre-Louis Taberna, Lionel Dubois, Olivier Crosnier, Patrice Simon, Daniel Lee, Gaël De Paëpe, Florence Duclairoir
Published in: ACS Nano, 2019, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.8b07102

Selective High-resolution DNP-enhanced NMR of Biomolecular Binding Sites

Author(s): Ildefonso Marin-Montesinos, David Goyard, Emilie Gillon, Olivier Renaudet, Anne Imberty, Sabine Hediger, Gaël De Paëpe
Published in: Chemical Science, 2019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc05696j

Interfacial Ca2+ environments in nanocrystalline apatites revealed by dynamic nuclear polarization enhanced 43Ca NMR spectroscopy

Author(s): Daniel Lee, César Leroy, Charlène Crevant, Laure Bonhomme-Coury, Florence Babonneau, Danielle Laurencin, Christian Bonhomme, Gaël De Paëpe
Published in: Nature Communications, Issue 8, 2017, Page(s) 14104, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/ncomms14104

Natural Isotopic Abundance 13 C and 15 N Multidimensional Solid-State NMR Enabled by Dynamic Nuclear Polarization

Author(s): Adam N. Smith, Katharina Märker, Sabine Hediger, Gaël De Paëpe
Published in: The Journal of Physical Chemistry Letters, Issue 10/16, 2019, Page(s) 4652-4662, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.8b03874

The surface chemistry of a nanocellulose drug carrier unravelled by MAS-DNP

Author(s): Akshay Kumar, Hippolyte Durand, Elisa Zeno, Cyril Balsollier, Bastien Watbled, Cecile Sillard, Sébastien Fort, Isabelle Baussanne, Naceur Belgacem, Daniel Lee, Sabine Hediger, Martine Demeunynck, Julien Bras, Gaël De Paëpe
Published in: Chemical Science, Issue 11/15, 2020, Page(s) 3868-3877, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc06312a

Book chapters (1)

High-Field Solid-State NMR with Dynamic Nuclear Polarization

Author(s): Daniel Lee, Sabine Hediger, Gaël De Paëpe
Published in: Modern Magnetic Resonance, 2017, Page(s) 1-17, ISBN 978-3-319-28275-6
Publisher: Springer International Publishing
DOI: 10.1007/978-3-319-28275-6_73-1