Production, control and Demonstration of structured hybrid nanoporous materials for Industrial adsorption Applications

Livrables

Report on innovative and mature technologies for MOF shaping

A brief description of the shaping techniques developed in the projects, their main drawbacks and potentials

Conditions for optimal drying process for MOF synthesis by spray-drying

The report describe briefly the spray drying process forMOF synthesis, the conditions used and the main characteristica of the products formed

Description of shaping processes and shaped products

Brief report on the various shaping techniques developed in the project and the main characteristica of the shaped products

Optimization of spray-drying processes for high yield production of divalent MOFs

A document describing briefly the spray drying process and the ways to optimize this towards high yield and high quality of the product

NPMs specification sheets for production quality control and recommendation for use

The report describe how a specification sheet following the various NPM products can look like and which data is should contain

Report on the synthesis of second generation MOF in water and in solvent with recycling

A brief report describing the main results and material properties of NPMs produced in water and with solvent recycling

Public report on the performances on shaped materials at laboratory scale

Brief report on the performance and physical properties of a selection of the shaped bodies prepared in the project

Report on the quality control of production processes at kg-scale

A report that describes the various techniques used to obtain physical and performance information abount NPM products to check their quality

Conditions for supercritical CO2 washing

The report describes the supercritical washing technique, the conditions used and the characteristica of the wasing process as compared to conventional techniques

Dissemination workshop

A workshop will be arranged the third year

Delivery of a batch of 1st generation MOF (Fe-BTC) for shaping development (WP5) – 0.5kg

Physical proof that sample has been prepared incl main characterization data

Delivery of shaped products

Proof that shaped products have been produced and their main characteristica are provided

Delivery of up to 10kg of NPMs by spray-drying

Proof that the needed amount of NPMs have been påroduced and its characteristica are provided

Delivery of first samples for testing (WP1), post-synthesis treatments (WP2) and shaping development (WP5) – 0.1g-1kg scale

Proof that sample has been prepared incl main characterisation data

Delivery of up to 5 kg MOFs by batch synthesis

Proof that the needed amount of MOFs have been produced by batch synthesis and the product characteristica is provided

Delivery of first samples of porous aluminosilicate for testing in WP1

Proof that samples have been prapered and delivered for further processing

Delivery of up to 100kg of NPMs by mecanosynthesis

Proof that the needed amout of NPMs have been produced at the main characteristica is provided

Delivery of HKUST-1 for shaping development in WP5 – 0,5kg scale

Proof that sample has been prepared incl main characteristica.

Delivery of up to 0.5kg MOFs by batch synthesis

Proof that the needed amout of MOFs have been produced and its characteristics are provided

Report on performances of NPM for all applications

A report describing briefly the performance of all selected NPMs for the four applications chosen

Delivery of prototype integrating the cylinder containing MOFs

Proof that a prototype integrating the methane storage cylinder containg MOF is provided

Communication tools (project identity set, website)

Communication tools have been established and communicated

Publications

New synthetic routes towards MOF production at scale

Auteurs: Marta Rubio-Martinez, Ceren Avci-Camur, Aaron W. Thornton, Inhar Imaz, Daniel Maspoch, Matthew R. Hill
Publié dans: Chemical Society Reviews, Numéro 46/11, 2017, Page(s) 3453-3480, ISSN 0306-0012
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c7cs00109f

Cost-effective 17 O enrichment and NMR spectroscopy of mixed-metal terephthalate metal–organic frameworks

Auteurs: Giulia P. M. Bignami, Zachary H. Davis, Daniel M. Dawson, Samuel A. Morris, Samantha E. Russell, David McKay, Richard E. Parke, Dinu Iuga, Russell E. Morris, Sharon E. Ashbrook
Publié dans: Chemical Science, Numéro 9/4, 2018, Page(s) 850-859, ISSN 2041-6520
Éditeur: Royal Society of Chemistry
DOI: 10.1039/C7SC04649A

Study of the scale-up, formulation, ageing and ammonia adsorption capacity of MIL-100(Fe), Cu-BTC and CPO-27(Ni) for use in respiratory protection filters

Auteurs: S. Hindocha, S. Poulston
Publié dans: Faraday Discussions, Numéro 201, 2017, Page(s) 113-125, ISSN 1359-6640
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c7fd00090a

Comment on “Water harvesting from air with metal-organic frameworks powered by natural sunlight”

Auteurs: Francis Meunier
Publié dans: Science, Numéro 358/6366, 2017, Page(s) eaao0361, ISSN 0036-8075
Éditeur: American Association for the Advancement of Science
DOI: 10.1126/science.aao0361

Unravelling ammonia adsorption mechanisms of adsorbents in humid conditions

Auteurs: Yoldes Khabzina, David Farrusseng
Publié dans: Microporous and Mesoporous Materials, Numéro 265, 2018, Page(s) 143-148, ISSN 1387-1811
Éditeur: Elsevier BV
DOI: 10.1016/j.micromeso.2018.02.011

Synthesis and Shaping Scale-up Study of Functionalized UiO-66 MOF for Ammonia Air Purification Filters

Auteurs: Yoldes Khabzina, Jeremy Dhainaut, Matthias Ahlhelm, Hans-Juergen Richter, Helge Reinsch, Norbert Stock, David Farrusseng
Publié dans: Industrial & Engineering Chemistry Research, Numéro 57/24, 2018, Page(s) 8200-8208, ISSN 0888-5885
Éditeur: American Chemical Society
DOI: 10.1021/acs.iecr.8b00808

Aqueous production of spherical Zr-MOF beads via continuous-flow spray-drying

Auteurs: Ceren Avci-Camur, Javier Troyano, Javier Pérez-Carvajal, Alexandre Legrand, David Farrusseng, Inhar Imaz, Daniel Maspoch
Publié dans: Green Chemistry, Numéro 20/4, 2018, Page(s) 873-878, ISSN 1463-9262
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c7gc03132g

Effect of Benzoic Acid as a Modulator in the Structure of UiO-66: An Experimental and Computational Study

Auteurs: Cesare Atzori, Greig C. Shearer, Lorenzo Maschio, Bartolomeo Civalleri, Francesca Bonino, Carlo Lamberti, Stian Svelle, Karl Petter Lillerud, Silvia Bordiga
Publié dans: The Journal of Physical Chemistry C, 2017, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.7b00483

Enhanced Ligand-Based Luminescence in Metal-Organic Framework Sensor

Auteurs: Alexandre Legrand, Anton Pastushenko, Vladimir Lysenko, Alain Geloen, Elsje Alessandra Quadrelli, Jerome Canivet, David Farrusseng
Publié dans: ChemNanoMat, Numéro 2/9, 2016, Page(s) 866-872, ISSN 2199-692X
Éditeur: Wiley-VCH Verlag GmbH & Co
DOI: 10.1002/cnma.201600124

Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

Auteurs: J. Dhainaut, C. Avci-Camur, J. Troyano, A. Legrand, J. Canivet, I. Imaz, D. Maspoch, H. Reinsch, D. Farrusseng
Publié dans: CrystEngComm, 2017, ISSN 1466-8033
Éditeur: Royal Society of Chemistry
DOI: 10.1039/C7CE00338B

Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal−Organic Frameworks

Auteurs: Luis Garzón-Tovar, Sabina Rodríguez-Hermida, Inhar Imaz and Daniel Maspoch
Publié dans: J. Am. Chem. soc, 2017, ISSN 0002-7863
Éditeur: American Chemical Society
DOI: 10.1021/jacs.6b11240

Composite Salt in Porous Metal-Organic Frameworks for Adsorption Heat Transformation

Auteurs: Luis Garzón-Tovar, Javier Pérez-Carvajal, Inhar Imaz, Daniel Maspoch
Publié dans: Advanced Functional Materials, Numéro 27/21, 2017, Page(s) 1606424, ISSN 1616-301X
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.201606424

Continuous One-Step Synthesis of Porous M-XF 6 -Based Metal-Organic and Hydrogen-Bonded Frameworks

Auteurs: Vincent Guillerm, Luis Garzón-Tovar, Amirali Yazdi, Inhar Imaz, Jordi Juanhuix, Daniel Maspoch
Publié dans: Chemistry - A European Journal, Numéro 23/28, 2017, Page(s) 6829-6835, ISSN 0947-6539
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201605507

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