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C-H Acids for Organic Synthesis

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Publications

Homologation of the Fischer Indolization: A Quinoline Synthesis via Homo‐Diaza‐Cope Rearrangement

Author(s): Gabriela Guillermina Gerosa, Sebastian Armin Schwengers, Rajat Maji, Chandra Kanta De, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 59/46, 2020, Page(s) 20485-20488, ISSN 1433-7851
DOI: 10.1002/anie.202005798

Catalytic Asymmetric Synthesis of Unprotected β 2 -Amino Acids

Author(s): Chendan Zhu, Francesca Mandrelli, Hui Zhou, Rajat Maji, Benjamin List
Published in: Journal of the American Chemical Society, Issue 143/9, 2021, Page(s) 3312-3317, ISSN 0002-7863
DOI: 10.1021/jacs.1c00249

The Smelling Principle of Vetiver Oil, Unveiled by Chemical Synthesis

Author(s): Jie Ouyang, Hanyong Bae, Samuel Jordi, Quang Minh Dao, Sandro Dossenbach, Stefanie Dehn, Julia B. Lingnau, Chandra Kanta De, Philip Kraft, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 60/11, 2021, Page(s) 5666-5672, ISSN 1433-7851
DOI: 10.1002/anie.202014609

Catalytic Asymmetric Intramolecular [4+2] Cycloaddition of In Situ Generated ortho -Quinone Methides

Author(s): Youwei Xie, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 56/18, 2017, Page(s) 4936-4940, ISSN 1433-7851
DOI: 10.1002/anie.201612149

High Lithium Transference Number Electrolytes Containing Tetratriflylpropene’s Lithium Salt

Author(s): J. Popovic, D. Höfler, J. P. Melchior, A. Münchinger, B. List, J. Maier
Published in: The Journal of Physical Chemistry Letters, Issue 9/17, 2018, Page(s) 5116-5120, ISSN 1948-7185
DOI: 10.1021/acs.jpclett.8b01846

Approaching sub-ppm-level asymmetric organocatalysis of a highly challenging and scalable carbon–carbon bond forming reaction

Author(s): Han Yong Bae, Denis Höfler, Philip S. J. Kaib, Pinar Kasaplar, Chandra Kanta De, Arno Döhring, Sunggi Lee, Karl Kaupmees, Ivo Leito, Benjamin List
Published in: Nature Chemistry, Issue 10/8, 2018, Page(s) 888-894, ISSN 1755-4330
DOI: 10.1038/s41557-018-0065-0

A Dendralenic C–H Acid

Author(s): Denis Höfler, Richard Goddard, Nils Nöthling, Benjamin List
Published in: Synlett, Issue 30/04, 2019, Page(s) 433-436, ISSN 0936-5214
DOI: 10.1055/s-0037-1612246

Triflimide: An Overlooked High-Performance Catalyst of the Mukaiyama Aldol Reaction of Silyl Ketene Acetals with Ketones

Author(s): Han Yong Bae, Benjamin List
Published in: Chemistry - A European Journal, Issue 24/52, 2018, Page(s) 13767-13772, ISSN 0947-6539
DOI: 10.1002/chem.201803142

A multi-substrate screening approach for the identification of a broadly applicable Diels–Alder catalyst

Author(s): Hyejin Kim, Gabriela Gerosa, Jonas Aronow, Pinar Kasaplar, Jie Ouyang, Julia B. Lingnau, Paul Guerry, Christophe Farès, Benjamin List
Published in: Nature Communications, Issue 10/1, 2019, Page(s) 770, ISSN 2041-1723
DOI: 10.1038/s41467-019-08374-z

Scalable and Highly Diastereo- and Enantioselective Catalytic Diels–Alder Reaction of α,β-Unsaturated Methyl Esters

Author(s): Tim Gatzenmeier, Mathias Turberg, Diana Yepes, Youwei Xie, Frank Neese, Giovanni Bistoni, Benjamin List
Published in: Journal of the American Chemical Society, Issue 140/40, 2018, Page(s) 12671-12676, ISSN 0002-7863
DOI: 10.1021/jacs.8b07092

Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates

Author(s): Lucas Schreyer, Philip S. J. Kaib, Vijay N. Wakchaure, Carla Obradors, Roberta Properzi, Sunggi Lee, Benjamin List
Published in: Science, Issue 362/6411, 2018, Page(s) 216-219, ISSN 0036-8075
DOI: 10.1126/science.aau0817

Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones

Author(s): Jie Ouyang, Jennifer L. Kennemur, Chandra Kanta De, Christophe Farès, Benjamin List
Published in: Journal of the American Chemical Society, Issue 141/8, 2019, Page(s) 3414-3418, ISSN 0002-7863
DOI: 10.1021/jacs.8b13899

Can a Ketone Be More Reactive than an Aldehyde? Catalytic Asymmetric Synthesis of Substituted Tetrahydrofurans

Author(s): Sunggi Lee, Han Yong Bae, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 57/37, 2018, Page(s) 12162-12166, ISSN 1433-7851
DOI: 10.1002/anie.201806312

Design and Synthesis of Enantiopure Tetrakis(pentafluorophenyl) Borate Analogues for Asymmetric Counteranion Directed Catalysis

Author(s): Benjamin List, Chandra De, Raja Mitra
Published in: Synlett, Issue 28/18, 2017, Page(s) 2435-2438, ISSN 0936-5214
DOI: 10.1055/s-0036-1590903

Activation of olefins via asymmetric Brønsted acid catalysis

Author(s): Nobuya Tsuji, Jennifer L. Kennemur, Thomas Buyck, Sunggi Lee, Sébastien Prévost, Philip S. J. Kaib, Dmytro Bykov, Christophe Farès, Benjamin List
Published in: Science, Issue 359/6383, 2018, Page(s) 1501-1505, ISSN 0036-8075
DOI: 10.1126/science.aaq0445

A Purely Organic Tricarbanion

Author(s): Denis Höfler, Richard Goddard, Julia B. Lingnau, Nils Nöthling, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 57/27, 2018, Page(s) 8326-8329, ISSN 1433-7851
DOI: 10.1002/anie.201803647

N-Triflylphosphorimidoyl Trichloride: A Versatile Reagent for the Synthesis of Strong Chiral Brønsted Acids

Author(s): Benjamin List, Sunggi Lee, Philip Kaib
Published in: Synlett, Issue 28/12, 2017, Page(s) 1478-1480, ISSN 0936-5214
DOI: 10.1055/s-0036-1588782

1,1,3,3-Tetratriflylpropene (TTP): A Strong, Allylic C-H Acid for Brønsted and Lewis Acid Catalysis

Author(s): Denis Höfler, Manuel van Gemmeren, Petra Wedemann, Karl Kaupmees, Ivo Leito, Markus Leutzsch, Julia B. Lingnau, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 56/5, 2017, Page(s) 1411-1415, ISSN 1433-7851
DOI: 10.1002/anie.201609923

Asymmetric Catalysis of the Carbonyl-Amine Condensation: Kinetic Resolution of Primary Amines

Author(s): Sayantani Das, Nilanjana Majumdar, Chandra Kanta De, Dipti Sankar Kundu, Arno Döhring, Anika Garczynski, Benjamin List
Published in: Journal of the American Chemical Society, Issue 139/4, 2017, Page(s) 1357-1359, ISSN 0002-7863
DOI: 10.1021/jacs.6b12176

The Catalytic Asymmetric Mukaiyama-Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

Author(s): Tim Gatzenmeier, Philip S. J. Kaib, Julia B. Lingnau, Richard Goddard, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 57/9, 2018, Page(s) 2464-2468, ISSN 1433-7851
DOI: 10.1002/anie.201712088

Asymmetric Catalysis via Cyclic, Aliphatic Oxocarbenium Ions

Author(s): Sunggi Lee, Philip S. J. Kaib, Benjamin List
Published in: Journal of the American Chemical Society, Issue 139/6, 2017, Page(s) 2156-2159, ISSN 0002-7863
DOI: 10.1021/jacs.6b11993

Catalytic Asymmetric [4+2]-Cycloaddition of Dienes with Aldehydes

Author(s): Luping Liu, Hyejin Kim, Youwei Xie, Christophe Farès, Philip S. J. Kaib, Richard Goddard, Benjamin List
Published in: Journal of the American Chemical Society, Issue 139/39, 2017, Page(s) 13656-13659, ISSN 0002-7863
DOI: 10.1021/jacs.7b08357

Deracemizing α-Branched Carboxylic Acids by Catalytic Asymmetric Protonation of Bis-Silyl Ketene Acetals with Water or Methanol

Author(s): Francesca Mandrelli, Aurélie Blond, Thomas James, Hyejin Kim, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 58/33, 2019, Page(s) 11479-11482, ISSN 1433-7851
DOI: 10.1002/anie.201905623

Strong and Confined Acids Catalyze Asymmetric Intramolecular Hydroarylations of Unactivated Olefins with Indoles

Author(s): Pinglu Zhang, Nobuya Tsuji, Jie Ouyang, Benjamin List
Published in: Journal of the American Chemical Society, Issue 143/2, 2021, Page(s) 675-680, ISSN 0002-7863
DOI: 10.1021/jacs.0c12042

The Silicon–Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes

Author(s): Hui Zhou, Han Yong Bae, Markus Leutzsch, Jennifer L. Kennemur, Diane Bécart, Benjamin List
Published in: Journal of the American Chemical Society, Issue 142/32, 2020, Page(s) 13695-13700, ISSN 0002-7863
DOI: 10.1021/jacs.0c06677

Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene

Author(s): Santanu Ghosh, Sayantani Das, Chandra Kanta De, Diana Yepes, Frank Neese, Giovanni Bistoni, Markus Leutzsch, Benjamin List
Published in: Angewandte Chemie International Edition, Issue 59/30, 2020, Page(s) 12347-12351, ISSN 1433-7851
DOI: 10.1002/anie.202000307