Chemical Engineering of Functional Stable Metal-Organic Frameworks: Porous Crystals and Thin Film Devices

Project Information

chem-fs-MOF

Grant agreement ID: 714122

DOI 10.3030/714122

Project closed

EC signature date 11 November 2016

Start date 1 January 2017

End date 31 December 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 527 351,26

EU contribution € 1 527 351,26

Coordinated by

UNIVERSITAT DE VALENCIA
Spain

Publications

Peer reviewed articles (41)

A Crystalline 1D Dynamic Covalent Polymer

Author(s): Elisabet De Bolòs, Marta Martínez-Abadía, Félix Hernández-Culebras, Alison Haymaker, Kyle Swain, Karol Strutyński, Benjamin L. Weare, Javier Castells-Gil, Natalia M. Padial, Carlos Martí-Gastaldo, Andrei N. Khlobystov, Akinori Saeki, Manuel Melle-Franco, Brent L. Nannenga, Aurelio Mateo-Alonso
Published in: Journal of the American Chemical Society, Issue 144/34, 2022, Page(s) 15443-15450, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c06446

Linker depletion for missing cluster defects in non-UiO metal–organic frameworks

Author(s): Isabel Abánades Lázaro, Neyvis Almora-Barrios, Sergio Tatay, Catalin Popescu, Carlos Martí-Gastaldo
Published in: Chemical Science, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc02408f

Surfactant-assisted synthesis of titanium nanoMOFs for thin film fabrication

Author(s): María Romero-Angel, Javier Castells-Gil, Víctor Rubio-Giménez, Rob Ameloot, Sergio Tatay, Carlos Martí-Gastaldo.
Published in: Chemical Communications, Issue 57, 2021, Page(s) 9040-9043, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc02828f

Heterometallic Titanium–Organic Frameworks by Metal-Induced Dynamic Topological Transformations

Author(s): Natalia M. Padial, Belén Lerma-Berlanga, Neyvis Almora-Barrios, Javier Castells-Gil, Iván da Silva, Marı́a de la Mata, Sergio I. Molina, Jesús Hernández-Saz, Ana E. Platero-Prats, Sergio Tatay, Carlos Martı́-Gastaldo
Published in: Journal of the American Chemical Society, Issue 142/14, 2020, Page(s) 6638-6648, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c00117

Selective Implantation of Diamines for Cooperative Catalysis in Isoreticular Heterometallic Titanium–Organic Frameworks

Author(s): Elena López-Maya, Natalia M. Padial, Javier Castells-Gil, Carolina R. Ganivet, Ana Rubio-Gaspar, Francisco G. Cirujano, Neyvis Almora-Barrios, Sergio Tatay, Sergio Navalón, Carlos Martí-Gastaldo.
Published in: Angewandte Chemie International Edition, Issue 60/21, 2021, Page(s) 11868-11873, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100176

Ultrathin Films of 2D Hofmann-Type Coordination Polymers: Influence of Pillaring Linkers on Structural Flexibility and Vertical Charge Transport

Author(s): Víctor Rubio-Giménez, Garin Escorcia-Ariza, Carlos Bartual-Murgui, Christian Sternemann, Marta Galbiati, Javier Castells-Gil, José Antonio Real, Sergio Tatay, Carlos Martí-Gastaldo
Published in: Chemistry of Materials, Issue 31/18, 2019, Page(s) 7277-7287, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b01634

Diffusion Control in Single-Site Zinc Reticular Amination Catalysts

Author(s): Francisco G. Cirujano, Elena López-Maya, Neyvis Almora-Barrios, Ana Rubio-Gaspar, Nuria Martín, Jorge A. R. Navarro, Carlos Martí-Gastaldo
Published in: Inorganic Chemistry, Issue 59/24, 2020, Page(s) 18168-18173, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.0c02624

Homochiral Metal–Organic Frameworks for Enantioselective Separations in Liquid Chromatography

Author(s): M. Nieves Corella-Ochoa, Jesús B. Tapia, Heather N. Rubin, Vanesa Lillo, Jesús González-Cobos, José Luis Núñez-Rico, Salvador R.G. Balestra, Neyvis Almora-Barrios, Marina Lledós, Arnau Güell-Bara, Juanjo Cabezas-Giménez, Eduardo C. Escudero-Adán, Anton Vidal-Ferran, Sofía Calero, Melissa Reynolds, Carlos Martí-Gastaldo, José Ramón Galán-Mascarós
Published in: Journal of the American Chemical Society, Issue 141/36, 2019, Page(s) 14306-14316, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b06500

Effect of Linker Distribution in the Photocatalytic Activity of Multivariate Mesoporous Crystals

Author(s): Belén Lerma-Berlanga, Carolina R. Ganivet, Neyvis Almora-Barrios, Sergio Tatay, Yong Peng, Josep Albero, Oscar Fabelo, Javier González-Platas, Hermenegildo García, Natalia M. Padial, Carlos Martí-Gastaldo
Published in: Journal of the American Chemical Society, Issue 143/4, 2021, Page(s) 1798-1806, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c09015

Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale

Author(s): Víctor Rubio-Giménez, Sergio Tatay, Carlos Martí-Gastaldo
Published in: Chemical Society Reviews, Issue 49/15, 2020, Page(s) 5601-5638, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cs00594c

Unlocking mixed oxides with unprecedented stoichiometries from heterometallic metal-organic frameworks for the catalytic hydrogenation of CO2

Author(s): Javier Castells-Gil, Samy Ould-Chikh, Adrian Ramírez, Rafia Ahmad, Gonzalo Prieto, Alberto Rodríguez Gómez, Luis Garzón-Tovar, Selvedin Telalovic, Lingmei Liu, Alessandro Genovese , Natalia M. Padial, Antonio Aguilar-Tapia, Pierre Bordet, Luigi Cavallo, Carlos Martí-Gastaldo, Jorge Gascon.
Published in: Chem Catalysis, Issue 2, 2021, Page(s) 364-382, ISSN 2667-1093
Publisher: Cell Press
DOI: 10.1016/j.checat.2021.03.010

Metal Node Control of Brønsted Acidity in Heterobimetallic Titanium–Organic Frameworks

Author(s): Ana Rubio-Gaspar, Sergio Navalón, Sergio Tatay, Francisco G. Cirujano, Carmen Fernández-Conde, Natalia M. Padial, Carlos Martí-Gastaldo
Published in: Journal of the American Chemical Society, Issue 145/7, 2023, Page(s) 3855-3860, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c12718

Understanding charge transport in wavy 2D covalent organic frameworks.

Author(s): Marta Martínez-Abadía, Karol Strutyński, Craig T. Stoppiello, Belén Lerma Berlanga, Carlos Martí-Gastaldo, Andrei N. Khlobystov, Akinori Saeki, Manuel Melle-Franco, Aurelio Mateo-Alonso
Published in: Nanoscale, Issue 13, 2021, Page(s) 6829-6833, ISSN 2040-3372
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0nr08962a

Heterometallic Titanium-Organic Frameworks as Dual-Metal Catalysts for Synergistic Non-buffered Hydrolysis of Nerve Agent Simulants

Author(s): Javier Castells-Gil, Natalia M. Padial, Neyvis Almora-Barrios, Rodrigo Gil-San-Millán, María Romero-Ángel, Virginia Torres, Iván da Silva, Bruno C.J. Vieira, Joao C. Waerenborgh, Jaciek Jagiello, Jorge A.R. Navarro, Sergio Tatay, Carlos Martí-Gastaldo
Published in: Chem, Issue 6/11, 2020, Page(s) 3118-3131, ISSN 2451-9294
Publisher: Cell Press
DOI: 10.1016/j.chempr.2020.09.002

Guest induced reversible on–off switching of elastic frustration in a 3D spin crossover coordination polymer with room temperature hysteretic behaviour

Author(s): Lucía Piñeiro-López, Francisco-Javier Valverde-Muñoz, Elzbieta Trzop, M. Carmen Muñoz, Maksym Seredyuk, Javier Castells-Gil, Iván da Silva, Carlos Martí-Gastaldo, Eric Collet, José Antonio Real
Published in: Chemical Science, Issue 12/4, 2021, Page(s) 1317-1326, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc04420b

Permanent Porosity in Hydroxamate Titanium–Organic Polyhedra

Author(s): Belén Lerma-Berlanga, Javier Castells-Gil, Carolina R. Ganivet, Neyvis Almora-Barrios, Javier González-Platas, Oscar Fabelo, Natalia M. Padial, Carlos Martí-Gastaldo
Published in: Journal of the American Chemical Society, Issue 143/50, 2021, Page(s) 21195-21199, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c09278

Epitaxial Thin-Film vs Single Crystal Growth of 2D Hofmann-Type Iron(II) Materials: A Comparative Assessment of their Bi-Stable Spin Crossover Properties

Author(s): Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real
Published in: ACS Applied Materials & Interfaces, 2020, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.0c05733

Hydroxamate Titanium–Organic Frameworks and the Effect of Siderophore-Type Linkers over Their Photocatalytic Activity

Author(s): Natalia M. Padial, Javier Castells-Gil, Neyvis Almora-Barrios, María Romero-Angel, Iván da Silva, Mariam Barawi, Alba García-Sánchez, Víctor A. de la Peña O’Shea, Carlos Martí-Gastaldo
Published in: Journal of the American Chemical Society, Issue 141/33, 2019, Page(s) 13124-13133, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b04915

Surface Functionalization of Metal–Organic Framework Crystals with Catechol Coatings for Enhanced Moisture Tolerance

Author(s): Javier Castells-Gil, Fernando Novio, Natalia M. Padial, Sergio Tatay, Daniel Ruíz-Molina, Carlos Martí-Gastaldo
Published in: ACS Applied Materials & Interfaces, Issue 9/51, 2017, Page(s) 44641-44648, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.7b15564

Chemical Engineering of Photoactivity in Heterometallic Titanium-Organic Frameworks by Metal Doping

Author(s): Javier Castells-Gil, Natalia M. Padial, Neyvis Almora-Barrios, Josep Albero, A. Rabdel Ruiz-Salvador, Javier González-Platas, Hermenegildo García, Carlos Martí-Gastaldo
Published in: Angewandte Chemie International Edition, Issue 57/28, 2018, Page(s) 8453-8457, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201802089

Peptide Metal–Organic Frameworks for Enantioselective Separation of Chiral Drugs

Author(s): José Navarro-Sánchez, Ana I. Argente-García, Yolanda Moliner-Martínez, Daniel Roca-Sanjuán, Dmytro Antypov, Pilar Campíns-Falcó, Matthew J. Rosseinsky, Carlos Martí-Gastaldo
Published in: Journal of the American Chemical Society, Issue 139/12, 2017, Page(s) 4294-4297, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.7b00280

Prussian Blue@MoS 2 Layer Composites as Highly Efficient Cathodes for Sodium- and Potassium-Ion Batteries

Author(s): Marc Morant-Giner, Roger Sanchis-Gual, Jorge Romero, Antonio Alberola, Leticia García-Cruz, Said Agouram, Marta Galbiati, Natalia M. Padial, João C. Waerenborgh, Carlos Martí-Gastaldo, Sergio Tatay, Alicia Forment-Aliaga, Eugenio Coronado
Published in: Advanced Functional Materials, Issue 28/27, 2018, Page(s) 1706125, ISSN 1616-301X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.201706125

Bottom-Up Fabrication of Semiconductive Metal-Organic Framework Ultrathin Films

Author(s): Víctor Rubio-Giménez, Marta Galbiati, Javier Castells-Gil, Neyvis Almora-Barrios, José Navarro-Sánchez, Garin Escorcia-Ariza, Michele Mattera, Thomas Arnold, Jonathan Rawle, Sergio Tatay, Eugenio Coronado, Carlos Martí-Gastaldo
Published in: Advanced Materials, Issue 30/10, 2018, Page(s) 1704291, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.201704291

Spontaneous Magnetization in Heterometallic NiFe-MOF-74 Microporous Magnets by Controlled Iron Doping

Author(s): Víctor Rubio-Giménez, Joao C. Waerenborgh, Juan M. Clemente-Juan, Carlos Martí-Gastaldo
Published in: Chemistry of Materials, Issue 29/15, 2017, Page(s) 6181-6185, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.7b01601

Structural reorganization in a hydrogen-bonded organic framework

Author(s): Javier Castells-Gil, Natalia M. Padial, Carlos Martí-Gastaldo
Published in: New Journal of Chemistry, Issue 42/19, 2018, Page(s) 16138-16143, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8nj02738b

Peptide metal–organic frameworks under pressure: flexible linkers for cooperative compression

Author(s): José Navarro-Sánchez, Ismael Mullor-Ruíz, Catalin Popescu, David Santamaría-Pérez, Alfredo Segura, Daniel Errandonea, Javier González-Platas, Carlos Martí-Gastaldo
Published in: Dalton Transactions, Issue 47/31, 2018, Page(s) 10654-10659, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt01765d

Three dimensional nanoscale analysis reveals aperiodic mesopores in a covalent organic framework and conjugated microporous polymer

Author(s): Craig T. Stoppiello, Helena Isla, Marta Martínez-Abadía, Michael W. Fay, Christopher D. J. Parmenter, Martin J. Roe, Belén Lerma-Berlanga, Carlos Martí-Gastaldo, Aurelio Mateo-Alonso, Andrei N. Khlobystov
Published in: Nanoscale, Issue 11/6, 2019, Page(s) 2848-2854, ISSN 2040-3364
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8nr10086a

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Author(s): Javier Castells-Gil, Fernando Novio, Natalia M. Padial, Sergio Tatay, Daniel Ruíz-Molina, Carlos Martí-Gastaldo
Published in: Journal of Visualized Experiments, Issue 139, 2018, Page(s) e58052, ISSN 1940-087X
Publisher: MYJoVE Corporation
DOI: 10.3791/58052

Origin of the Chemiresistive Response of Ultrathin Films of Conductive Metal-Organic Frameworks

Author(s): Víctor Rubio-Giménez, Neyvis Almora-Barrios, Garin Escorcia-Ariza, Marta Galbiati, Michele Sessolo, Sergio Tatay, Carlos Martí-Gastaldo
Published in: Angewandte Chemie International Edition, Issue 57/46, 2018, Page(s) 15086-15090, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808242

Implementation of slow magnetic relaxation in a SIM-MOF through a structural rearrangement

Author(s): Javier Castells-Gil, José J. Baldoví, Carlos Martí-Gastaldo, Guillermo Mínguez Espallargas
Published in: Dalton Transactions, Issue 47/41, 2018, Page(s) 14734-14740, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8dt03421d

De novo synthesis of mesoporous photoactive titanium( iv )–organic frameworks with MIL-100 topology

Author(s): Javier Castells-Gil, Natalia M. Padial, Neyvis Almora-Barrios, Ivan da Silva, Diego Mateo, Josep Albero, Hermenegildo García, Carlos Martí-Gastaldo
Published in: Chemical Science, Issue 10/15, 2019, Page(s) 4313-4321, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc05218b

Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films

Author(s): Víctor Rubio-Giménez, Carlos Bartual-Murgui, Marta Galbiati, Alejandro Núñez-López, Javier Castells-Gil, Benoit Quinard, Pierre Seneor, Edwige Otero, Philippe Ohresser, Andrés Cantarero, Eugenio Coronado, José Antonio Real, Richard Mattana, Sergio Tatay, Carlos Martí-Gastaldo
Published in: Chemical Science, Issue 10/14, 2019, Page(s) 4038-4047, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc04935a

Direct Visualization of Pyrrole Reactivity upon Confinement within a Cyclodextrin Metal-Organic Framework

Author(s): Alejandro Nuñez-Lopez, Marta Galbiati, Natalia M. Padial, Carolina R. Ganivet, Sergio Tatay, Emilio Pardo, Donatella Armentano, Carlos Martí-Gastaldo
Published in: Angewandte Chemie International Edition, 2019, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201904890

Translocation of Enzymes into a Mesoporous MOF for Enhanced Catalytic Activity Under Extreme Conditions

Author(s): Jose Navarro, Neyvis Almora Barrios, Belén Lerma Berlanga, J. Javier Ruiz-Pernía, Victor Armando Lorenz Fonfria, Iñaki Tuñón, Carlos Martí-Gastaldo
Published in: Chemical Science, 2019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc00082h

Tetrazine Linkers as Plug-and-Play Tags for General Metal-Organic Framework Functionalization and C60 Conjugation

Author(s): Belén Lerma-Berlanga, Carolina R. Ganivet, Neyvis Almora-Barrios, Rebecca Vismara, Jorge A. R. Navarro, Sergio Tatay, Natalia M. Padial, Carlos Martí-Gastaldo
Published in: Angewandte Chemie International Edition, Issue 61/41, 2022, Page(s) e2022081, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202208139

An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons

Author(s): Alberto Riaño, Karol Strutyński, Meng Liu, Craig T. Stoppiello, Belén Lerma-Berlanga, Akinori Saeki, Carlos Martí-Gastaldo, Andrei N. Khlobystov, Giovanni Valenti, Francesco Paolucci, Manuel Melle-Franco, Aurelio Mateo-Alonso.
Published in: Angewandte Chemie International Edition, Issue 61/2, 2021, Page(s) e202113657, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202113657

Integrated Cleanroom Process for the Vapor-Phase Deposition of Large-Area Zeolitic Imidazolate Framework Thin Films

Author(s): Alexander John Cruz, Ivo Stassen, Mikhail Krishtab, Kristof Marcoen, Timothée Stassin, Sabina Rodríguez-Hermida, Joan Teyssandier, Sven Pletincx, Rhea Verbeke, Víctor Rubio-Giménez, Sergio Tatay, Carlos Martí-Gastaldo, Johan Meersschaut, Philippe M. Vereecken, Steven De Feyter, Tom Hauffman, Rob Ameloot
Published in: Chemistry of Materials, Issue 31/22, 2019, Page(s) 9462-9471, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b03435

Growing and Shaping Metal–Organic Framework Single Crystals at the Millimeter Scale

Author(s): Alessandro Sorrenti, Lewis Jones, Semih Sevim, Xiaobao Cao, Andrew J. deMello, Carlos Martí-Gastaldo, Josep Puigmartí-Luis
Published in: Journal of the American Chemical Society, Issue 142/20, 2020, Page(s) 9372-9381, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c01935

Effect of modulator connectivity on promoting defectivity in titanium–organic frameworks

Author(s): Isabel Abánades Lázaro, Neyvis Almora-Barrios, Sergio Tatay, Carlos Martí-Gastaldo
Published in: Chemical Science, Issue 12/7, 2021, Page(s) 2586-2593, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc06105k

A Wavy Two-Dimensional Covalent Organic Framework from Core-Twisted Polycyclic Aromatic Hydrocarbons

Author(s): Marta Martínez-Abadía, Craig T. Stoppiello, Karol Strutynski, Belén Lerma-Berlanga, Carlos Martí-Gastaldo, Akinori Saeki, Manuel Melle-Franco, Andrei N. Khlobystov, Aurelio Mateo-Alonso
Published in: Journal of the American Chemical Society, Issue 141/36, 2019, Page(s) 14403-14410, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b07383

Reversible guest-induced gate-opening with multiplex spin crossover responses in two-dimensional Hofmann clathrates

Author(s): Rubén Turo-Cortés, Carlos Bartual-Murgui, Javier Castells-Gil, M. Carmen Muñoz, Carlos Martí-Gastaldo, José Antonio Real
Published in: Chemical Science, Issue 11/41, 2020, Page(s) 11224-11234, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc04246c