Development of Direct Dehydrogenative Couplings mediated by Dioxygen

Project Information

2O2ACTIVATION

Grant agreement ID: 716136

DOI

10.3030/716136

Project closed

EC signature date 21 October 2016

Start date 1 March 2017

End date 31 August 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 489 822,50

EU contribution

€ 1 489 822,50

Coordinated by

RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (33)

Electrochemical Dehydrogenative C−H Aminomethylation of Imidazopyridines and Related Heterocycles

Author(s): Raolin Huang, Frederic W. Patureau
Published in: Chemistry A European Journal, 2022, ISSN 1521-3765
Publisher: Wiley-VCH GmbH, Weinheim
DOI: 10.1002/chem.202202135

Cross-dehydrogenative N–N couplings

Author(s): Alexis Tabey, Pooja Y. Vemuri, Frederic W. Patureau
Published in: Chemical Science, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc03851f

Emerging unconventional organic solvents for C–H bond and related functionalization reactions

Author(s): Congjun Yu, Jesús Sanjosé-Orduna, Frederic W. Patureau, Mónica H. Pérez-Temprano
Published in: Chemical Society Reviews, Issue 49/6, 2020, Page(s) 1643-1652, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cs00883c

Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings

Author(s): Christina L. Bub, Vinzenz Thönnißen, Frederic W. Patureau
Published in: Organic Letters, Issue 22/23, 2020, Page(s) 9196-9198, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.0c03354

Electro‐Oxidative Selective Esterification of Methylarenes and Benzaldehydes

Author(s): Congjun Yu, Bünyamin Özkaya, Frederic W. Patureau
Published in: Chemistry – A European Journal, Issue 27/11, 2021, Page(s) 3682-3687, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202005158

Electrochemical Dehydrogenative Acetalization Protection of Alcohols with Tetrahydrofuran

Author(s): Raolin Huang, Congjun Yu, Frederic W. Patureau
Published in: ChemElectroChem, 2021, ISSN 2196-0216
Publisher: Wiley-VCH
DOI: 10.1002/celc.202101155

Para -Selective Dehydrogenative Phenothiazination of Hydroquinolines and Indolines

Author(s): Pooja Y. Vemuri, Yongchao Wang, Frederic W. Patureau
Published in: Organic Letters, Issue 21/24, 2019, Page(s) 9856-9859, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.9b03729

HBF 4 - and AgBF 4 -Catalyzed ortho -Alkylation of Diarylamines and Phenols

Author(s): Christian K. Rank, Bünyamin Özkaya, Frederic W. Patureau
Published in: Organic Letters, Issue 21/17, 2019, Page(s) 6830-6834, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.9b02470

Tellurium(II)/Tellurium(III)‐Catalyzed Cross‐Dehydrogenative C−N Bond Formation

Author(s): Christopher Cremer, Monalisa Goswami, Christian K. Rank, Bas Bruin, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, Issue 60/12, 2021, Page(s) 6451-6456, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015248

Leucomethylene blue probe detects a broad spectrum of reactive oxygen and nitrogen species

Author(s): Christopher Cremer, Jean Michel Merkes, Christina L. Bub, Dirk Rommel, Frederic W. Patureau, Srinivas Banala
Published in: RSC Advances, 2021, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1ra06498c

Visible Light Induced Metal-Free Carbene N -Carbazolation

Author(s): Claire Empel, Frederic W. Patureau, Rene M. Koenigs
Published in: The Journal of Organic Chemistry, Issue 84/17, 2019, Page(s) 11316-11322, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.9b01753

Step and redox efficient nitroarene to indole synthesis

Author(s): Bünyamin Özkaya, Christina L. Bub, Frederic W. Patureau
Published in: Chemical Communications, Issue 56/86, 2020, Page(s) 13185-13188, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc03258a

Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone.

Author(s): Xingben Wang, Congjun Yu, Iuliana L. Atodiresei, Frederic W. Patureau
Published in: Organic Letters, 2022, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c04045

Enantioselective Aromatic Amination?

Author(s): Vinzenz Thönnißen, Frederic W. Patureau
Published in: Chemistry – A European Journal, Issue 27/25, 2021, Page(s) 7189-7192, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004151

Cross Dehydrogenative Coupling of Chloro- and Fluoroalkanes with Methylarenes

Author(s): Jiaxiang Xiang, Frederic W. Patureau
Published in: ChemPhotoChem, Issue 23670932, 2022, ISSN 2367-0932
Publisher: Wiley-VCH GmbH, Weinheim
DOI: 10.1002/cptc.202200130

O2-Mediated Dehydrogenative Phenoxazination of Phenols

Author(s): Rajaa Benchouaia, Shiny Nandi, Clemens Maurer, Frederic W. Patureau
Published in: Journal of Organic Chemistry, 2022, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.1c02827

The Strong β−CF 3 Shielding Effect in Hexafluoroisopropanol and 100 Other Organic Solvents Revisited with 17 O NMR Spectroscopy

Author(s): Annika Bernhardt, Harald Kelm, Frederic W. Patureau
Published in: ChemCatChem, Issue 10/7, 2018, Page(s) 1547-1551, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201701721

Accelerated Ru-Cu Trinuclear Cooperative C−H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation

Author(s): Alexander W. Jones, Christian K. Rank, Yanik Becker, Christian Malchau, Ignacio Funes-Ardoiz, Feliu Maseras, Frederic W. Patureau
Published in: Chemistry - A European Journal, 2018, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201802886

Phenothiazinimides: Atom-Efficient Electrophilic Amination Reagents

Author(s): Rongwei Jin, Christina L. Bub, Frederic W. Patureau
Published in: Organic Letters, Issue 20/10, 2018, Page(s) 2884-2887, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.8b00914

Mechanism of the Dehydrogenative Phenothiazination of Phenols

Author(s): Monalisa Goswami, Alexander Konkel, Maryam Rahimi, Marie-Laure Louillat-Habermeyer, Harald Kelm, Rongwei Jin, Bas de Bruin, Frederic W. Patureau
Published in: Chemistry - A European Journal, Issue 24/46, 2018, Page(s) 11936-11943, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201800730

The cumene/O 2 system: a very simple tool for the radical chain oxidation of some functional groups

Author(s): A. Malekafzali, K. Malinovska, F. W. Patureau
Published in: New Journal of Chemistry, Issue 41/15, 2017, Page(s) 6981-6985, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7NJ01666B

Cu-Catalyzed Cross-Dehydrogenative ortho -Aminomethylation of Phenols

Author(s): Congjun Yu, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, Issue 57/36, 2018, Page(s) 11807-11811, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201804829

The Phenol-Phenothiazine Coupling: an Oxidative Click Concept

Author(s): Frederic W. Patureau
Published in: ChemCatChem, 2019, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201900152

An intermolecular C–H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines

Author(s): Christian K. Rank, Alexander W. Jones, Tatjana Wall, Patrick Di Martino-Fumo, Sarah Schröck, Markus Gerhards, Frederic W. Patureau
Published in: Chemical Communications, 2019, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc05240b

Regioselective Oxidative Arylation of Fluorophenols

Author(s): Congjun Yu, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, 2019, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910352

Photochemical (Hetero-)Arylation of Aryl Sulfonium Salts

Author(s): Yue Zhao, Congjun Yu, Wenjing Liang, Frederic W. Patureau
Published in: Organic Letters, 2021, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c01904

O₂-Mediated Te(II)-Redox Catalysis for the Cross-Dehydrogenative Coupling of Indoles

Author(s): Christopher Cremer; Frederic W. Patureau
Published in: JACSau, Issue 26913704, 2022, ISSN 2691-3704
Publisher: Amercian Chemical Society
DOI: 10.1021/jacsau.2c00193

Cross-Dehydrogenative N–N Coupling of Aromatic and Aliphatic Methoxyamides with Benzotriazoles

Author(s): Pooja Y. Vemuri, Frederic W. Patureau
Published in: Organic Letters, 2021, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c01034

Dehydrogenative C–H Phenochalcogenazination

Author(s): Christopher Cremer, M. Alexander Eltester, Hicham Bourakhouadar, Iuliana L. Atodiresei, Frederic W. Patureau
Published in: Organic Letters, Issue 23/9, 2021, Page(s) 3243-3247, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c00573

TEMPO-mediated late stage photochemical hydroxylation of biaryl sulfonium salts

Author(s): Yue Zhao, Congjun Yu, Wenjing Liang, Iuliana L. Atodiresei, Frederic W. Patureau
Published in: Chemical Communications, 2022, ISSN 0022-4936
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc07057f

Direct Dehydrogenative Access to Unsymmetrical Phenones

Author(s): Congjun Yu, Raolin Huang, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202201142

Effects of the Chalcogenide Identity in <i>N</i> ‐Aryl Phenochalcogenazine Photoredox Catalysts

Author(s): Daniel A. Corbin; Christopher Cremer; Katherine O. Puffer; Brian S. Newell; Frederic W. Patureau; Garret M. Miyake
Published in: ChemCatChem, Issue 1, 2022, ISSN 1867-3899
Publisher: Wiley-VCH GmbH, Weinheim
DOI: 10.1002/cctc.202200485

Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines

Author(s): Pooja Y. Vemuri, Christopher Cremer, Frederic W. Patureau
Published in: Organic Letters, 2022, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.2c00125