Development of Direct Dehydrogenative Couplings mediated by Dioxygen

Project Information

2O2ACTIVATION

Grant agreement ID: 716136

DOI 10.3030/716136

Project closed

EC signature date 21 October 2016

Start date 1 March 2017

End date 31 August 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 489 822,50

EU contribution € 1 489 822,50

Coordinated by

RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
Germany

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (33)

Electrochemical Dehydrogenative C−H Aminomethylation of Imidazopyridines and Related Heterocycles

Author(s): Raolin Huang, Frederic W. Patureau
Published in: Chemistry A European Journal, Issue 15213765, 2022, ISSN 1521-3765
Publisher: Wiley-VCH GmbH, Weinheim
DOI: 10.1002/chem.202202135

Cross-dehydrogenative N–N couplings

Author(s): Alexis Tabey, Pooja Y. Vemuri, Frederic W. Patureau
Published in: Chemical Science, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc03851f

Emerging unconventional organic solvents for C–H bond and related functionalization reactions

Author(s): Congjun Yu, Jesús Sanjosé-Orduna, Frederic W. Patureau, Mónica H. Pérez-Temprano
Published in: Chemical Society Reviews, Issue 49/6, 2020, Page(s) 1643-1652, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cs00883c

Benzophenothiazine and Its Cr(III)-Catalyzed Cross Dehydrogenative Couplings

Author(s): Christina L. Bub, Vinzenz Thönnißen, Frederic W. Patureau
Published in: Organic Letters, Issue 22/23, 2020, Page(s) 9196-9198, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.0c03354

Electro‐Oxidative Selective Esterification of Methylarenes and Benzaldehydes

Author(s): Congjun Yu, Bünyamin Özkaya, Frederic W. Patureau
Published in: Chemistry – A European Journal, Issue 27/11, 2021, Page(s) 3682-3687, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202005158

Electrochemical Dehydrogenative Acetalization Protection of Alcohols with Tetrahydrofuran

Author(s): Raolin Huang, Congjun Yu, Frederic W. Patureau
Published in: ChemElectroChem, 2021, ISSN 2196-0216
Publisher: Wiley-VCH
DOI: 10.1002/celc.202101155

Para -Selective Dehydrogenative Phenothiazination of Hydroquinolines and Indolines

Author(s): Pooja Y. Vemuri, Yongchao Wang, Frederic W. Patureau
Published in: Organic Letters, Issue 21/24, 2019, Page(s) 9856-9859, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.9b03729

HBF 4 - and AgBF 4 -Catalyzed ortho -Alkylation of Diarylamines and Phenols

Author(s): Christian K. Rank, Bünyamin Özkaya, Frederic W. Patureau
Published in: Organic Letters, Issue 21/17, 2019, Page(s) 6830-6834, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.9b02470

Tellurium(II)/Tellurium(III)‐Catalyzed Cross‐Dehydrogenative C−N Bond Formation

Author(s): Christopher Cremer, Monalisa Goswami, Christian K. Rank, Bas Bruin, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, Issue 60/12, 2021, Page(s) 6451-6456, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202015248

Leucomethylene blue probe detects a broad spectrum of reactive oxygen and nitrogen species

Author(s): Christopher Cremer, Jean Michel Merkes, Christina L. Bub, Dirk Rommel, Frederic W. Patureau, Srinivas Banala
Published in: RSC Advances, 2021, ISSN 2046-2069
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1ra06498c

Visible Light Induced Metal-Free Carbene N -Carbazolation

Author(s): Claire Empel, Frederic W. Patureau, Rene M. Koenigs
Published in: The Journal of Organic Chemistry, Issue 84/17, 2019, Page(s) 11316-11322, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.9b01753

Step and redox efficient nitroarene to indole synthesis

Author(s): Bünyamin Özkaya, Christina L. Bub, Frederic W. Patureau
Published in: Chemical Communications, Issue 56/86, 2020, Page(s) 13185-13188, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0cc03258a

Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone.

Author(s): Xingben Wang, Congjun Yu, Iuliana L. Atodiresei, Frederic W. Patureau
Published in: Organic Letters, 2022, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c04045

Enantioselective Aromatic Amination?

Author(s): Vinzenz Thönnißen, Frederic W. Patureau
Published in: Chemistry – A European Journal, Issue 27/25, 2021, Page(s) 7189-7192, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004151

Cross Dehydrogenative Coupling of Chloro- and Fluoroalkanes with Methylarenes

Author(s): Jiaxiang Xiang, Frederic W. Patureau
Published in: ChemPhotoChem, Issue 23670932, 2022, ISSN 2367-0932
Publisher: Wiley-VCH GmbH, Weinheim
DOI: 10.1002/cptc.202200130

O2-Mediated Dehydrogenative Phenoxazination of Phenols

Author(s): Rajaa Benchouaia, Shiny Nandi, Clemens Maurer, Frederic W. Patureau
Published in: Journal of Organic Chemistry, 2022, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.1c02827

The Strong β−CF 3 Shielding Effect in Hexafluoroisopropanol and 100 Other Organic Solvents Revisited with 17 O NMR Spectroscopy

Author(s): Annika Bernhardt, Harald Kelm, Frederic W. Patureau
Published in: ChemCatChem, Issue 10/7, 2018, Page(s) 1547-1551, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201701721

Accelerated Ru-Cu Trinuclear Cooperative C−H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation

Author(s): Alexander W. Jones, Christian K. Rank, Yanik Becker, Christian Malchau, Ignacio Funes-Ardoiz, Feliu Maseras, Frederic W. Patureau
Published in: Chemistry - A European Journal, 2018, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201802886

Phenothiazinimides: Atom-Efficient Electrophilic Amination Reagents

Author(s): Rongwei Jin, Christina L. Bub, Frederic W. Patureau
Published in: Organic Letters, Issue 20/10, 2018, Page(s) 2884-2887, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.8b00914

Mechanism of the Dehydrogenative Phenothiazination of Phenols

Author(s): Monalisa Goswami, Alexander Konkel, Maryam Rahimi, Marie-Laure Louillat-Habermeyer, Harald Kelm, Rongwei Jin, Bas de Bruin, Frederic W. Patureau
Published in: Chemistry - A European Journal, Issue 24/46, 2018, Page(s) 11936-11943, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201800730

The cumene/O 2 system: a very simple tool for the radical chain oxidation of some functional groups

Author(s): A. Malekafzali, K. Malinovska, F. W. Patureau
Published in: New Journal of Chemistry, Issue 41/15, 2017, Page(s) 6981-6985, ISSN 1144-0546
Publisher: Royal Society of Chemistry
DOI: 10.1039/C7NJ01666B

Cu-Catalyzed Cross-Dehydrogenative ortho -Aminomethylation of Phenols

Author(s): Congjun Yu, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, Issue 57/36, 2018, Page(s) 11807-11811, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201804829

The Phenol-Phenothiazine Coupling: an Oxidative Click Concept

Author(s): Frederic W. Patureau
Published in: ChemCatChem, 2019, ISSN 1867-3880
Publisher: Wiley - VCH Verlag GmbH & CO. KGaA
DOI: 10.1002/cctc.201900152

An intermolecular C–H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines

Author(s): Christian K. Rank, Alexander W. Jones, Tatjana Wall, Patrick Di Martino-Fumo, Sarah Schröck, Markus Gerhards, Frederic W. Patureau
Published in: Chemical Communications, 2019, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc05240b

Regioselective Oxidative Arylation of Fluorophenols

Author(s): Congjun Yu, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, 2019, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910352

Photochemical (Hetero-)Arylation of Aryl Sulfonium Salts

Author(s): Yue Zhao, Congjun Yu, Wenjing Liang, Frederic W. Patureau
Published in: Organic Letters, 2021, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c01904

O₂-Mediated Te(II)-Redox Catalysis for the Cross-Dehydrogenative Coupling of Indoles

Author(s): Christopher Cremer; Frederic W. Patureau
Published in: JACSau, Issue 26913704, 2022, ISSN 2691-3704
Publisher: Amercian Chemical Society
DOI: 10.1021/jacsau.2c00193

Cross-Dehydrogenative N–N Coupling of Aromatic and Aliphatic Methoxyamides with Benzotriazoles

Author(s): Pooja Y. Vemuri, Frederic W. Patureau
Published in: Organic Letters, 2021, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c01034

Dehydrogenative C–H Phenochalcogenazination

Author(s): Christopher Cremer, M. Alexander Eltester, Hicham Bourakhouadar, Iuliana L. Atodiresei, Frederic W. Patureau
Published in: Organic Letters, Issue 23/9, 2021, Page(s) 3243-3247, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.1c00573

TEMPO-mediated late stage photochemical hydroxylation of biaryl sulfonium salts

Author(s): Yue Zhao, Congjun Yu, Wenjing Liang, Iuliana L. Atodiresei, Frederic W. Patureau
Published in: Chemical Communications, 2022, ISSN 0022-4936
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc07057f

Direct Dehydrogenative Access to Unsymmetrical Phenones

Author(s): Congjun Yu, Raolin Huang, Frederic W. Patureau
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202201142

Effects of the Chalcogenide Identity in <i>N</i> ‐Aryl Phenochalcogenazine Photoredox Catalysts

Author(s): Daniel A. Corbin; Christopher Cremer; Katherine O. Puffer; Brian S. Newell; Frederic W. Patureau; Garret M. Miyake
Published in: ChemCatChem, Issue 18673899, 2022, ISSN 1867-3899
Publisher: Wiley-VCH GmbH, Weinheim
DOI: 10.1002/cctc.202200485

Te(II)-Catalyzed Cross-Dehydrogenative Phenothiazination of Anilines

Author(s): Pooja Y. Vemuri, Christopher Cremer, Frederic W. Patureau
Published in: Organic Letters, 2022, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.2c00125