The Extensive and Ubiquitous Role of Polycyclic Aromatic Hydrocarbons (PAHs) in Space

Informations projet

EUROPAH

N° de convention de subvention: 722346

DOI

10.3030/722346

Projet clôturé

Date de signature de la CE 31 Août 2016

Date de début 1 Octobre 2016

Date de fin 31 Mars 2021

Financé au titre de

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Coût total

€ 4 009 451,64

Contribution de l’UE

€ 4 009 451,64

Coordonné par

AARHUS UNIVERSITET
Denmark

CORDIS fournit des liens vers les livrables publics et les publications des projets HORIZON.

Les liens vers les livrables et les publications des projets du 7e PC, ainsi que les liens vers certains types de résultats spécifiques tels que les jeux de données et les logiciels, sont récupérés dynamiquement sur OpenAIRE .

Livrables

Documents, reports (29)

Conference: PAH meeting

PAH Meeting: An ESR organised and student attended conference (33)

Research: Electronic spectra

Electronic spectra of astrophysically relevant gas-phase PAH ions (42).

Research: Photooxidation rates

Photo-oxidation rates of PAHs in relevant aqueous environments (24)

Outreach: Travelling exposition ready

Outreach travelling exposition ready for delivery at, e.g., Researchers' Night (22)

Research: chemical kinetic model

Chemical kinetic model of PAH destruction in plasmas (42)

Research: Vib spectra

Vibrational spectra of astrophysically relevant PAH ions (36);

Website: Set up public outreach platform

Report on establishment of outreach subsection videos and articles presenting individual ESR projects uploaded on the network website 16

Research: Chemical evolution

Model for the chemical evolution of PAHs in aqueous environment of asteroids 12

Research: IR spectra

First vibrational spectra of gaseous PAH clusters (36)

Research: PAH fragmentation

Photochemistry and photophysics of acenes using OASIS apparatus (21);

Research: IR/UV spectra

First IR and VUV signatures of functionalized PAHs on grain surfaces (24);

Research: Binding energies (exp)

Experimental and theoretical binding energies of functionalized PAHs/acenes on/in (icy) grain surfaces (40)

Research: PAHs in plasmas

Analysis of species produced by PAH destruction in plasmas (24)

Research: Photophyscis of PAHs

Photo-fragmentation dynamics of large PAHs(30)

Research: PAHs and surfaces

PAH formation and structural evolution of PAHs on astrophysical grain surfaces (36)

Research: Photoreactivity (theo)

Photoreactivity of water cluster/ice or atomic hydrogen interacting with a PAH (24)

Research: Photo-processes (exp)

Identification of photon-induced release of simple species from functionalized PAHs (20)

Research: Binding energies (theo)

Calculated binding energies of functionalized PAHs on grain surfaces (24)

Research: Photochemical processing

Photochemical processing in an ice environment (16)

Research: A set of theoretical and methodological tools to appropriately conduct high quality ethnographic research into the processes of public engagement in the Europah project.

A set of theoretical and methodological tools to appropriately conduct high quality ethnographic research into the processes of public engagement in the Europah project. (21)

Admin: Evaluation report

A full evaluation report detailing the successes and otherwise of the network (48)

International PAH conference

International PAH meeting (40)

Research: Cross-sections

Crosssections for EleyRideal processes on functionalized PAHs 15

Outreach: Royal Society performance

Public performance of network's outreach package (22)

Outreach: Travelling exhibition displayed at 6 events

Report on the travelling exhibition displayed at 6 events.

Research: Functionalised PAHs

Identification of stable O, H and N functionalized PAH species (30)

Research: Photochemical evolution

Model for the photochemical evolution of PAHs in ices (36)

Admin: Progress Report

Progress report (13)

Research: Photocatalytic activity

Photocatalytic activity of PAHs measured (47)

Other (1)

Website: Set up website

Network website online (6)

Websites, patent fillings, videos etc. (1)

Website: archive of public outreach material

Post at least 40 short popular articles /videos on the website (48);

Open Research Data Pilot (1)

Admin: Data management plan

Data management plan (3)

Publications

Peer reviewed articles (39)

Hydrogen Arrangements on Defective Quasi-Molecular BN Fragments.

Auteurs: Remedios Cortese; Dario Campisi; Dario Duca
Publié dans: ACS Omega, Numéro 6, 2019, ISSN 2470-1343
Éditeur: American Chemical Society
DOI: 10.1021/acsomega.9b01445

Photo-processing of astro-PAHs

Auteurs: C. Joblin, G. Wenzel, S. Rodriguez Castillo, A. Simon, H. Sabbah, A. Bonnamy, D. Toublanc, G. Mulas, M. Ji, A. Giuliani, L. Nahon
Publié dans: Journal of Physics: Conference Series, Numéro J. Phys.: Conf. Ser. 1412 062002 (2020), 2020, ISSN 1742-6588
Éditeur: Institute of Physics
DOI: 10.1088/1742-6596/1412/6/062002

Far-IR Absorption of Neutral Polycyclic Aromatic Hydrocarbons (PAHs): Light on the Mechanism of IR–UV Ion Dip Spectroscopy

Auteurs: Alexander K Lemmens, Daniël B Rap, Johannes MM Thunnissen, Sébastien Gruet, Amanda L Steber, Sanjana Panchagnula, Alexander GGM Tielens, Melanie Schnell, Wybren Jan Buma, Anouk M Rijs
Publié dans: J. Phys. Chem. Lett., 2020, ISSN 1948-7185
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpclett.0c02714

H 2 catalysis through superhydrogenation of interstellar polycyclic aromatic hydrocarbons

Auteurs: Frederik Doktor S. Simonsen, Pernille A. Jensen, Anders W. Skov, Rijutha Jaganathan, John D. Thrower, Liv Hornekær
Publié dans: Proceedings of the International Astronomical Union, Numéro 15/S350, 2019, Page(s) 264-266, ISSN 1743-9213
Éditeur: Cambridge University Press
DOI: 10.1017/s1743921320000034

Astrochemical relevance of VUV ionization of large PAH cations

Auteurs: G. Wenzel, C. Joblin, A. Giuliani, S. Rodriguez Castillo, G. Mulas, M. Ji, H. Sabbah, S. Quiroga, D. Peña, L. Nahon
Publié dans: Astronomy & Astrophysics, Numéro A&A, 641, A98 (2020), 2020, ISSN 0004-6361
Éditeur: Springer Verlag
DOI: 10.1051/0004-6361/202038139

Interstellar polycyclic aromatic hydrocarbons: Spectroscopy, photofragmentation and photoproducts

Auteurs: Jordy Bouwman, Jerry Kamer, Pablo Castellanos, Michał Bulak, Sanjana Panchagnula, Junfeng Zhen, Arjen de Haas, Jos Oomens, Harold Linnartz, Alexander Tielens
Publié dans: Proceedings of the International Astronomical Union, Numéro 15/S350, 2019, Page(s) 353-355, ISSN 1743-9213
Éditeur: Cambridge University Press
DOI: 10.1017/s174392131900752x

Structural Changes Induced by Quinones: High‐Resolution Microwave Study of 1, 4‐Naphthoquinone

Auteurs: Shefali Saxena, Sanjana Panchagnula, M Eugenia Sanz, Cristóbal Pérez, Luca Evangelisti, Brooks H Pate
Publié dans: Chem-PhysChem, 2020, ISSN 1439-4235
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.202000665

Plasma reforming of biomass gasification tars using mixed naphthalene and toluene as model compounds

Auteurs: D.H. Mei, Y.L. Wang, S.Y. Liu, M. Alliati, H.P. Yang, X. Tu
Publié dans: Energy Conversion and Management, 2019, ISSN 0196-8904
Éditeur: Pergamon Press Ltd.
DOI: 10.1016/j.enconman.2019.05.002

The Infrared Spectrum of Protonated C 70

Auteurs: Julianna Palotás, Jonathan Martens, Giel Berden, Jos Oomens
Publié dans: The Astrophysical Journal Letters, Numéro 909/2, 2021, Page(s) L17, ISSN 2041-8205
Éditeur: Institute of Physics Publishing
DOI: 10.3847/2041-8213/abe874

The infrared spectrum of protonated buckminsterfullerene C60H+

Auteurs: Julianna Palotás, Jonathan Martens, Giel Berden, Jos Oomens
Publié dans: Nature Astronomy, Numéro 4/3, 2020, Page(s) 240-245, ISSN 2397-3366
Éditeur: Nature
DOI: 10.1038/s41550-019-0941-6

Ionic Species in a Naphthalene Plasma: Understanding Fragmentation Patterns and Growth of PAHs

Auteurs: Martin Alliati, David Donaghy, Xin Tu, James W Bradley
Publié dans: The Journal of Physical Chemistry A, Numéro 123/10, 2019, Page(s) 2107-2113, ISSN 1089-5639
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpca.9b00100

Plasma activation of CO2 in a dielectric barrier discharge: A chemical kinetic model from the microdischarge to the reactor scales

Auteurs: Martin Alliati, Danhua Mei, Xin Tu
Publié dans: Journal of CO2 Utilization, Numéro 27, 2018, Page(s) 308-319, ISSN 2212-9820
Éditeur: Elsevier BV
DOI: 10.1016/j.jcou.2018.07.018

Plasma reforming of toluene as a model tar compound from biomass gasification: effect of CO2 and steam

Auteurs: Shiyun Liu, Danhua Mei, Yaolin Wang, Yichen Ma, Xin Tu
Publié dans: Waste Disposal & Sustainable Energy, Numéro 1/2, 2019, Page(s) 133-141, ISSN 2524-7980
Éditeur: Springer
DOI: 10.1007/s42768-019-00011-1

Integrated gasification and non-thermal plasma-catalysis system for cleaner syngas production from cellulose

Auteurs: M. Craven, Y.L. Wang, H.P. Yang, C.F. Wu, X. Tu
Publié dans: IOP SciNotes, 2020, ISSN 2633-1357
Éditeur: IOPscience
DOI: 10.1088/2633-1357/aba7f6

Citizen science with colour blindness: A case study on the Forel-Ule scale

Auteurs: Olivier Burggraaff, Sanjana Panchagnula, Frans Snik
Publié dans: PLOS ONE, Numéro 16/4, 2021, Page(s) e0249755, ISSN 1932-6203
Éditeur: Public Library of Science
DOI: 10.1371/journal.pone.0249755

Structural investigation of doubly-dehydrogenated pyrene cations

Auteurs: Sanjana Panchagnula, Jordy Bouwman, Daniël B. Rap, Pablo Castellanos, Alessandra Candian, Cameron Mackie, Shreyak Banhatti, Sandra Brünken, Harold Linnartz, Alexander G. G. M. Tielens
Publié dans: Physical Chemistry Chemical Physics, Numéro 22/38, 2020, Page(s) 21651-21663, ISSN 1463-9076
Éditeur: Royal Society of Chemistry
DOI: 10.1039/d0cp02272a

The Sequence of Coronene Hydrogenation Revealed by Gas-phase IR Spectroscopy

Auteurs: Stephanie Cazaux, Yann Arribard, Dmitrii Egorov, Julianna Palotás, Ronnie Hoekstra, Giel Berden, Jos Oomens, Thomas Schlathölter
Publié dans: The Astrophysical Journal, Numéro 875/1, 2019, Page(s) 27, ISSN 1538-4357
Éditeur: IOP Publishing for the American Astronomical Society
DOI: 10.3847/1538-4357/ab0e01

CO 2 Hydrogenation at Atmospheric Pressure and Low Temperature Using Plasma-Enhanced Catalysis over Supported Cobalt Oxide Catalysts

Auteurs: Maria Ronda-Lloret, Yaolin Wang, Paula Oulego, Gadi Rothenberg, Xin Tu, N. Raveendran Shiju
Publié dans: ACS Sustainable Chemistry & Engineering, Numéro 8/47, 2020, Page(s) 17397-17407, ISSN 2168-0485
Éditeur: American Chemical Society
DOI: 10.1021/acssuschemeng.0c05565

Theoretical investigation of the electronic relaxation in highly excited chrysene and tetracene: The effect of armchair versus zigzag edge

Auteurs: E. Posenitskiy, M. Rapacioli, D. Lemoine, F. Spiegelman
Publié dans: The Journal of Chemical Physics, Numéro 152, 074306, 2020, 2020, ISSN 0021-9606
Éditeur: American Institute of Physics
DOI: 10.1063/1.5135369

Do defects in PAHs promote catalytic activity in space? Stone–Wales pyrene as a test case

Auteurs: Dario Campisi, Alessandra Candian
Publié dans: Physical Chemistry Chemical Physics, Numéro 22/12, 2020, Page(s) 6738-6748, ISSN 1463-9076
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9cp06523g

Non-adiabatic molecular dynamics investigation of the size dependence of the electronic relaxation in polyacenes

Auteurs: Evgeny Posenitskiy, Mathias Rapacioli, Bruno Lepetit, Didier Lemoine, Fernand Spiegelman
Publié dans: Physical Chemistry Chemical Physics, Numéro 21/23, 2019, Page(s) 12139-12149, ISSN 1463-9076
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9cp00603f

Gas-phase infrared spectroscopy of the rubicene cation (C 26 H 14 •+ )

Auteurs: J. Bouwman, C. Boersma, M. Bulak, J. Kamer, P. Castellanos, A. G. G. M. Tielens, H. Linnartz
Publié dans: Astronomy & Astrophysics, Numéro 636, 2020, Page(s) A57, ISSN 0004-6361
Éditeur: Springer Verlag
DOI: 10.1051/0004-6361/201937013

Identification of the fragment of the 1-methylpyrene cation by mid-IR spectroscopy

Auteurs: Pavol Jusko, Aude Simon, Gabi Wenzel, Sandra Brünken, Stephan Schlemmer, Christine Joblin
Publié dans: Chemical Physics Letters, Numéro 698, 2018, Page(s) 206-210, ISSN 0009-2614
Éditeur: Elsevier BV
DOI: 10.1016/j.cplett.2018.03.028

Direct Evidence of the Benzylium and Tropylium Cations as the two long-lived Isomers of C7H7+

Auteurs: Pavol Jusko, Aude Simon, Shreyak Banhatti, Sandra Brünken, Christine Joblin
Publié dans: ChemPhysChem, 2018, ISSN 1439-4235
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.201800744

Effect of molecular structure on the infrared signatures of astronomically relevant PAHs

Auteurs: J. Bouwman, P. Castellanos, M. Bulak, J. Terwisscha van Scheltinga, J. Cami, H. Linnartz, A. G. G. M. Tielens
Publié dans: Astronomy & Astrophysics, Numéro 621, 2019, Page(s) A80, ISSN 0004-6361
Éditeur: Springer Verlag
DOI: 10.1051/0004-6361/201834130

Superhydrogenation of pentacene: the reactivity of zigzag-edges

Auteurs: Dario Campisi, Frederik Doktor S. Simonsen, John D. Thrower, Rijutha Jaganathan, Liv Hornekær, Rocco Martinazzo, Alexander G. G. M. Tielens
Publié dans: Physical Chemistry Chemical Physics, Numéro 22/3, 2020, Page(s) 1557-1565, ISSN 1463-9076
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9cp05440e

Enhanced reforming of mixed biomass tar model compounds using a hybrid gliding arc plasma catalytic process

Auteurs: D.H. Mei, S.Y. Liu, Y.L. Wang, H.P. Yang, Z. Bo, X. Tu
Publié dans: Catalysis Today, 2019, ISSN 0920-5861
Éditeur: Elsevier BV
DOI: 10.1016/j.cattod.2019.05.046

Photofragmentation of coronene cations

Auteurs: Sanjana Panchagnula, Jordy Bouwman, Jerry Kamer, Harold Linnartz, Alexander Tielens
Publié dans: Proceedings of the International Astronomical Union, Numéro 15/S350, 2019, Page(s) 402-403, ISSN 1743-9213
Éditeur: Cambridge University Press
DOI: 10.1017/s1743921319008068

Infrared action spectroscopy of doubly charged PAHs and their contribution to the aromatic infrared bands

Auteurs: S. Banhatti, J. Palotás, P. Jusko, B. Redlich, J. Oomens, S. Schlemmer, S. Brünken
Publié dans: Astronomy & Astrophysics, Numéro 648, 2021, Page(s) A61, ISSN 0004-6361
Éditeur: Springer Verlag
DOI: 10.1051/0004-6361/202039744

Solar-Enhanced Plasma-Catalytic Oxidation of Toluene over a Bifunctional Graphene Fin Foam Decorated with Nanofin-like MnO 2

Auteurs: Zheng Bo, Shiling Yang, Jing Kong, Jinhui Zhu, Yaolin Wang, Huachao Yang, Xiaodong Li, Jianhua Yan, Kefa Cen, Xin Tu
Publié dans: ACS Catalysis, Numéro 10/7, 2020, Page(s) 4420-4432, ISSN 2155-5435
Éditeur: American Chemical Society
DOI: 10.1021/acscatal.9b04844

Chemically-resolved determination of hydrogenated graphene–substrate interaction

Auteurs: Anders L. Jørgensen, David A. Duncan, Claus F. P. Kastorp, Line Kyhl, Zeyuan Tang, Albert Bruix, Mie Andersen, Bjørk Hammer, Tien-Lin Lee, Liv Hornekær, Richard Balog
Publié dans: Physical Chemistry Chemical Physics, Numéro 21/25, 2019, Page(s) 13462-13466, ISSN 1463-9076
Éditeur: Royal Society of Chemistry
DOI: 10.1039/c9cp02059d

Photoprocessing of large PAH cations

Auteurs: Gabi Wenzel, Sarah Rodriguez Castillo, Giacomo Mulas, Ming-Chao Ji, Anthony Bonnamy, Hassan Sabbah, Alexandre Giuliani, Laurent Nahon, Christine Joblin
Publié dans: Proceedings of the International Astronomical Union, Numéro 15/S350, 2019, Page(s) 388-389, ISSN 1743-9213
Éditeur: Cambridge University Press
DOI: 10.1017/s1743921319007063

Photolysis of acetonitrile in a water-rich ice as a source of complex organic molecules: CH 3 CN and H 2 O:CH 3 CN ices

Auteurs: M. Bulak, D. M. Paardekooper, G. Fedoseev, H. Linnartz
Publié dans: Astronomy & Astrophysics, Numéro 647, 2021, Page(s) A82, ISSN 0004-6361
Éditeur: Springer Verlag
DOI: 10.1051/0004-6361/202039695

Novel approach to distinguish between vacuum UV-induced ice photodesorption and photoconversion

Auteurs: M. Bulak, D. M. Paardekooper, G. Fedoseev, H. Linnartz
Publié dans: Astronomy & Astrophysics, Numéro 636, 2020, Page(s) A32, ISSN 0004-6361
Éditeur: Springer Verlag
DOI: 10.1051/0004-6361/201937298

The Interaction of Aromatic Molecules with Forsterite: Accuracy of Periodic DFT-D4 Method

Auteurs: Dario Campisi, Thanja Lamberts, Nelson Y. Dzade, Rocco Martinazzo, Inge Loes ten Kate, and Alexander G. G. M. Tielens
Publié dans: Journal of Physical Chemistry A, 2021, ISSN 1089-5639
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpca.1c02326

Plasma reforming of naphthalene as a tar model compound of biomass gasification

Auteurs: Yaoling Wang, Haiping Yang, Xin Tu
Publié dans: Energy Conversion and Management, Numéro 187, 2019, Page(s) 593-604, ISSN 0196-8904
Éditeur: Pergamon Press Ltd.
DOI: 10.1016/j.enconman.2019.02.075

Density-functional tight-binding: basic concepts and applications to molecules and clusters

Auteurs: Fernand Spiegelman, Nathalie Tarrat, Jérôme Cuny, Leo Dontot, Evgeny Posenitskiy, Carles Martí, Aude Simon, Mathias Rapacioli
Publié dans: Advances in Physics: X, Numéro 5/1, 2020, Page(s) 1710252, ISSN 2374-6149
Éditeur: Taylor & Francis
DOI: 10.1080/23746149.2019.1710252

Laboratory evidence for the formation of hydrogenated fullerene molecules

Auteurs: J. D. Thrower, G. Pantazidis, M. Scheffler, F. D. S. Simonsen, P. A. Jensen, L. Hornekær
Publié dans: Proceedings of the International Astronomical Union, Numéro 15/S350, 2019, Page(s) 144-147, ISSN 1743-9213
Éditeur: Cambridge University Press
DOI: 10.1017/s1743921319007567

Laboratory IR spectroscopy of protonated hexa-peri-hexabenzocoronene and dicoronylene

Auteurs: Julianna Palotás, Jonathan Martens, Giel Berden, Jos Oomens
Publié dans: Journal of Molecular Spectroscopy, Numéro 378, 2021, Page(s) 111474, ISSN 0022-2852
Éditeur: Academic Press
DOI: 10.1016/j.jms.2021.111474

Conference proceedings (2)

ISOLATED 1,4-NAPHTHOQUINONE AND ITS STEP-WISE MICROSOLVATION IN THE GAS PHASE: STRUCTURE AND BINDING BY ROTATIONAL SPECTROSCOPY

Auteurs: SHEFALI SAXENA, SANJANA PANCHAGNULA, M. EUGENIA SANZ, CRISTOBAL PEREZ, LUCA EVANGELISTI, CHANNING WEST, BROOKS PATE,
Publié dans: Abstracts & Presentations - 2020 International Symposium on Molecular Spectroscopy, Numéro 2020, 2020
Éditeur: International Symposium on Molecular Spectroscopy

Deuteration of C60 on a highly oriented pyrolytic graphite surface

Auteurs: G. Pantazidis, M. Scheffler, F. D. S. Simonsen, A. Cassidy, P. A. Jensen L. Hornekær and J. D. Thrower
Publié dans: Proceedings of the International Astronomical Union, 2019
Éditeur: Cambridge University Press
DOI: 10.1017/s1743921320000344