Mechanical Chirality: Synthesis, Properties and Applications at a New Horizon in Supramolecular Stereochemistry

Project Information

MechaniChiral

Grant agreement ID: 724987

DOI

10.3030/724987

Project closed

EC signature date 21 March 2017

Start date 1 April 2017

End date 30 September 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 998 927,50

EU contribution

€ 1 998 927,50

Coordinated by

UNIVERSITY OF SOUTHAMPTON
United Kingdom

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (24)

Using the Mechanical Bond to Tune the Performance of a Thermally Activated Delayed Fluorescence Emitter

Author(s): Pachaiyappan Rajamalli; Pachaiyappan Rajamalli; Federica Rizzi; Wenbo Li; Michael A. Jinks; Abhishek Gupta; Beth Laidlaw; Ifor D. W. Samuel; Thomas J. Penfold; Stephen M. Goldup; Eli Zysman-Colman
Published in: Angewandte Chemie (International Ed. in English), Issue 7, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202101870

Mechanically axially chiral catenanes and noncanonical mechanically axially chiral rotaxanes

Author(s): John R.J. Maynard, Peter Gallagher, David Lozano, Patrick Butler, and Stephen M. Goldup
Published in: Nature Chemistry, 2022, Page(s) 1038–1044, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-022-00973-6

A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes

Author(s): Alberto de Juan; David Lozano; Andrew W. Heard; Michael A. Jinks; Jorge Meijide Suarez; Graham J. Tizzard; Stephen M. Goldup
Published in: Nature Chemistry, Issue 1, 2022, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-021-00825-9

Vibrational circular dichroism spectroscopy for probing the expression of chirality in mechanically planar chiral rotaxanes.

Author(s): Mark A. J. Koenis; C. S. Chibueze; Michael A. Jinks; Valentin P. Nicu; Lucas Visscher; Stephen M. Goldup; Wybren Jan Buma; Wybren Jan Buma
Published in: Chemical Science, Issue 4, 2020, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc02485f

Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra

Author(s): Lorenzo Gualandi; Paola Franchi; Elisabetta Mezzina; Stephen M. Goldup; Marco Lucarini
Published in: Chemical Science, Issue 3, 2021, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.26434/chemrxiv.14247224.v1

Rotaxane CoII Complexes as Field-Induced Single-Ion Magnets

Author(s): Martina Cirulli; Enrico Salvadori; Zhihui Zhang; Michael Dommett; Floriana Tuna; Heiko Bamberger; James E. M. Lewis; James E. M. Lewis; Amanpreet Kaur; Graham J. Tizzard; Joris van Slageren; Rachel Crespo-Otero; Stephen M. Goldup; Maxie M. Roessler
Published in: Angewandte Chemie International Edition, Issue 4, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202103596

A co-conformationally “topologically” chiral catenane

Author(s): Arnau Rodríguez-Rubio; Andrea Savoini; Florian Modicom; Patrick Butler; Stephen M. Goldup
Published in: Journal of the American Chemical Society, 2022, Page(s) 11927–11932, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c02029

Anion-π Catalysis Enabled by the Mechanical Bond

Author(s): John R. J. Maynard; Bartomeu Galmés; Athanasios D. Stergiou; Mark D. Symes; Antonio Frontera; Steve Goldup
Published in: Angewandte Chemie International Edition, Issue 2, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.26434/chemrxiv-2021-r591n

Chelating Rotaxane Ligands as Fluorescent Sensors for Metal Ions

Author(s): Mathieu Denis, Jessica Pancholi, Kajally Jobe, Michael Watkinson, Stephen M. Goldup
Published in: Angewandte Chemie International Edition, Issue 57/19, 2018, Page(s) 5310-5314, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201712931

Porphyrinoid rotaxanes: building a mechanical picket fence

Author(s): T. H. Ngo, J. Labuta, G. N. Lim, W. A. Webre, F. D'Souza, P. A. Karr, J. E. M. Lewis, J. P. Hill, K. Ariga, S. M. Goldup
Published in: Chemical Science, Issue 8/9, 2017, Page(s) 6679-6685, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7sc03165c

Chirality in rotaxanes and catenanes

Author(s): E. M. G. Jamieson, F. Modicom, S. M. Goldup
Published in: Chemical Society Reviews, Issue 47/14, 2018, Page(s) 5266-5311, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cs00097b

A Fluorescent Ditopic Rotaxane Ion-Pair Host

Author(s): Mathieu Denis, Lei Qin, Peter Turner, Katrina A. Jolliffe, Stephen M. Goldup
Published in: Angewandte Chemie International Edition, Issue 57/19, 2018, Page(s) 5315-5319, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201713105

Efficient Multicomponent Active Template Synthesis of Catenanes

Author(s): James E. M. Lewis, Florian Modicom, Stephen M. Goldup
Published in: Journal of the American Chemical Society, Issue 140/14, 2018, Page(s) 4787-4791, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b01602

Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes

Author(s): Michael A. Jinks, Alberto de Juan, Mathieu Denis, Catherine J. Fletcher, Marzia Galli, Ellen M. G. Jamieson, Florian Modicom, Zhihui Zhang, Stephen M. Goldup
Published in: Angewandte Chemie International Edition, Issue 57/45, 2018, Page(s) 14806-14810, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201808990

Chelating Rotaxane Ligands as Fluorescent Sensors for Metal Ions

Author(s): Mathieu Denis, Jessica Pancholi, Kajally Jobe, Michael Watkinson, Stephen M. Goldup
Published in: Angewandte Chemie, Issue 130/19, 2018, Page(s) 5408-5412, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.201712931

Synthesis and Characterisation of a Paramagnetic [2]Rotaxane Based on a Crown Ether-Like Wheel Incorporating a Nitroxide Motif

Author(s): Valentina Bleve, Paola Franchi, Evangelia Konstanteli, Lorenzo Gualandi, Stephen M. Goldup, Elisabetta Mezzina, Marco Lucarini
Published in: Chemistry - A European Journal, Issue 24/5, 2018, Page(s) 1198-1203, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201704969

An Auxiliary Approach for the Stereoselective Synthesis of Topologically Chiral Catenanes

Author(s): Mathieu Denis, James E.M. Lewis, Florian Modicom, Stephen M. Goldup
Published in: Chem, Issue 5/6, 2019, Page(s) 1512-1520, ISSN 2451-9294
Publisher: Elsevier
DOI: 10.1016/j.chempr.2019.03.008

Rotaxane-Based Transition Metal Complexes: Effect of the Mechanical Bond on Structure and Electronic Properties

Author(s): Martina Cirulli, Amanpreet Kaur, James E. M. Lewis, Zhihui Zhang, Jonathan A. Kitchen, Stephen M. Goldup, Maxie M. Roessler
Published in: Journal of the American Chemical Society, Issue 141/2, 2019, Page(s) 879-889, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b09715

Chemical Consequences of the Mechanical Bond: A Tandem Active Template-Rearrangement Reaction

Author(s): Florian Modicom, Ellen M. G. Jamieson, Elise Rochette, Stephen M. Goldup
Published in: Angewandte Chemie International Edition, Issue 58/12, 2019, Page(s) 3875-3879, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201813950

Synthesis of a Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis

Author(s): Andrew W. Heard, Stephen M. Goldup
Published in: Chem, Issue 6/4, 2020, Page(s) 994-1006, ISSN 2451-9294
Publisher: Elsevier
DOI: 10.1016/j.chempr.2020.02.006

Simplicity in the Design, Operation, and Applications of Mechanically Interlocked Molecular Machines

Author(s): Andrew W. Heard, Stephen M. Goldup
Published in: ACS Central Science, Issue 6/2, 2020, Page(s) 117-128, ISSN 2374-7943
Publisher: American Chemical Society
DOI: 10.1021/acscentsci.9b01185

AT-CuAAC Synthesis of Mechanically Interlocked Oligonucleotides

Author(s): Amanda Acevedo-Jake, Andrew T. Ball, Marzia Galli, Mikiembo Kukwikila, Mathieu Denis, Daniel G. Singleton, Ali Tavassoli, Stephen M. Goldup
Published in: Journal of the American Chemical Society, Issue 142/13, 2020, Page(s) 5985-5990, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c01670

Rotaxane Pt II -complexes: mechanical bonding for chemically robust luminophores and stimuli responsive behaviour

Author(s): Zhihui Zhang, Graham J. Tizzard, J. A. Gareth Williams, Stephen M. Goldup
Published in: Chemical Science, Issue 11/7, 2020, Page(s) 1839-1847, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc05507j

Metal ions in the synthesis of interlocked molecules and materials

Author(s): Lewis, James E. M.; Beer, Paul D.; Loeb, Stephen J.; Goldup, Stephen M.
Published in: Chemical Society Reviews, Issue 2, 2017, ISSN 0306-0012
Publisher: Royal Society of Chemistry
DOI: 10.1039/c7cs00199a

Non-peer reviewed articles (2)

A [3]Rotaxane Host Selects Between Stereoisomers

Author(s): Mathieu Denis, Stephen Michael Goldup
Published in: Angewandte Chemie International Edition, Issue 57/17, 2018, Page(s) 4462-4464, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201800665

Chirality makes a move

Author(s): Ellen M. G. Jamieson, Stephen M. Goldup
Published in: Nature Chemistry, Issue 11/9, 2019, Page(s) 765-767, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-019-0320-z