Corrosion Initiation Mechanisms at the Nanometric/Atomic Scale

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Publications

Adsorption of 2-mercaptobenzothiazole organic inhibitor and its effects on copper anodic oxidation in alkaline environment

Author(s): Vishant Garg, Sagar B. Sharma, Sandrine Zanna, Antoine Seyeux, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Journal of the Electrochemical Society, Issue 170, 2023, Page(s) 071502, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ace33b

Adsorption and thermal stability of 2-mercaptobenzothiazole corrosion inhibitor on metallic and pre-oxidized Cu(1 1 1) model surfaces

Author(s): Xiaocui Wu, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Applied Surface Science, Issue 508, 2020, Page(s) 145132, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2019.145132

Vibratory polishing effects on passivity of 304L stainless steel surfaces

Author(s): S. Neupane, S. Zanna, A. Seyeux, V. Maurice, P. Marcus
Published in: Corrosion Engineering, Science and Technology, 2023, Page(s) 2264655, ISSN 1478-422X
Publisher: Maney Publishing
DOI: 10.1080/1478422x.2023.2264655

Molybdenum effects on the stability of passive films unraveled at the nanometer and atomic scales

Author(s): V. Maurice, P. Marcus
Published in: npj Materials Degradation, Issue 8, 2024, Page(s) 3, ISSN 2397-2106
Publisher: Nature Publishing Group
DOI: 10.1038/s41529-023-00418-6

DFT investigation of 2-mercaptobenzothiazole adsorption on model oxidized copper surfaces and relationship with corrosion inhibition

Author(s): Fatah Chiter, Dominique Costa, Vincent Maurice, Philippe Marcus
Published in: Applied Surface Science, Issue 537, 2021, Page(s) 147802, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2020.147802

Atomic Scale Insight into Corrosion Inhibition: DFT Study of 2-Mercaptobenzimidazole on Locally De-Passivated Copper Surfaces

Author(s): Fatah Chiter, Dominique Costa, Vincent Maurice, Philippe Marcus
Published in: Journal of the Electrochemical Society, Issue 168, 2021, Page(s) 121507, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ac405c

DFT-Based Cu(111)||Cu 2 O(111) Model for Copper Metal Covered by Ultrathin Copper Oxide: Structure, Electronic Properties, and Reactivity

Author(s): Fatah Chiter, Dominique Costa, Vincent Maurice, Philippe Marcus
Published in: The Journal of Physical Chemistry C, Issue 124/31, 2020, Page(s) 17048-17057, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.0c04453

Local Inhibition by 2-mercaptobenzothiazole of Early Stage Intergranular Corrosion of Copper

Author(s): Sagar B. Sharma, Vincent Maurice, Lorena H. Klein, Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 167/16, 2020, Page(s) 161504, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/abcc36

DFT study on Mo-stabilized passive films: Hydroxylation effects on chromium and iron oxide surfaces

Author(s): X. Huang, D. Costa, B. Diawara, V. Maurice, P. Marcus
Published in: Corrosion Science, Issue 233, 2024, Page(s) 112105, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2024.112105

Corrosion inhibition of locally de-passivated surfaces by DFT study of 2-mercaptobenzothiazole on copper

Author(s): Fatah Chiter, Dominique Costa, Vincent Maurice, Philippe Marcus
Published in: npj Materials Degradation, Issue 5, 2021, Page(s) 52, ISSN 2397-2106
Publisher: Springer
DOI: 10.1038/s41529-021-00198-x

Moiré Structure of the 2-Mercaptobenzothiazole Corrosion Inhibitor Adsorbed on a (111)-Oriented Copper Surface

Author(s): Xiaocui Wu, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: The Journal of Physical Chemistry C, Issue 124/29, 2020, Page(s) 15995-16001, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.0c04083

Insight on passivity of high entropy alloys: thermal stability and ion transport mechanisms in the passive oxide film on CoCrFeMnNi surfaces

Author(s): Luntao Wang; Antoine Seyeux; Loïc Perriere; Dimitri Mercier; Vincent Maurice; Philippe Marcus
Published in: Corrosion Science, Issue 188, 2021, Page(s) 109540, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2021.109540

XPS study of oxide nucleation and growth mechanisms on a model FeCrNiMo stainless steel surface

Author(s): Benjamin Lynch, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Applied Surface Science, Issue 575, 2021, Page(s) 151681, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2021.151681

An XPS and ToF-SIMS study of the passive film formed on a model FeCrNiMo stainless steel surface in aqueous media after thermal pre-oxidation at ultra-low oxygen pressure

Author(s): Benjamin Lynch, Shova Neupane, Frédéric Wiame, Antoine Seyeux, Vincent Maurice, Philippe Marcus
Published in: Applied Surface Science, Issue 554, 2021, Page(s) 149435, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2021.149435

Ion Transport Mechanisms in the Oxide Film Formed on 316L Stainless Steel Surfaces Studied by ToF-SIMS with 18 O 2 Isotopic Tracer

Author(s): Luntao Wang, Antoine Seyeux, Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 167/10, 2020, Page(s) 101511, ISSN 1945-7111
Publisher: IOP Science
DOI: 10.1149/1945-7111/ab9c87

Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMS

Author(s): Luntao Wang, Dimitri Mercier, Sandrine Zanna, Antoine Seyeux, Mathilde Laurent-Brocq, Loïc Perrière, Ivan Guillot, Philippe Marcus
Published in: Corrosion Science, Issue 167, 2020, Page(s) 108507, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2020.108507

Protection of Stainless Steels by Mo against Cl Attack: A DFT Study

Author(s): Xian Huang, Dominique Costa, Boubakar Diawara, Vincent Maurice, Philippe Marcus
Published in: The Journal of Physical Chemistry C, Issue 129, 2025, Page(s) 3913-3919, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.4c08056

Atomistic insights on enhanced passivity: DFT study of substitutional Mo on Cr2O3 and Fe2O3 surfaces

Author(s): X. Huang, D. Costa, B. Diawara, V. Maurice, P. Marcus
Published in: Corrosion Science, Issue 224, 2023, Page(s) 111543, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2023.111543

Inhibition of the initial stages of corrosion by 2-mercaptobenzothiazole adsorption and the effects of interfacial oxides on copper in neutral chloride conditions

Author(s): V. Garg, S. Zanna, A. Seyeux, F. Wiame, V. Maurice, P. Marcus
Published in: Corrosion Science, Issue 225, 2023, Page(s) 111596, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2023.111596

Enhanced passivity of Cr-Fe-Co-Ni-Mo multi-component single-phase face-centred cubic alloys: design, production and corrosion behaviour

Author(s): Xueying Wang, Dimitri Mercier, Yolaine Danard, Thomas Rieger, Loïc Perrière, Mathilde Laurent-Brocq, Ivan Guillot, Vincent Maurice, Philippe Marcus
Published in: Corrosion Science, Issue 200, 2022, Page(s) 110233, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2022.110233

Enhanced corrosion inhibition of copper in acidic environment by cathodic control of interface formation with 2-mercaptobenzothiazole

Author(s): Vishant Garg, Sagar B. Sharma, Sandrine Zanna, Antoine Seyeux, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Electrochimica Acta, Issue 447, 2023, Page(s) 142162, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2023.142162

Passivation-Induced Cr and Mo Enrichments of 316L Stainless Steel Surfaces and Effects of Controlled Pre-Oxidation

Author(s): Benjamin Lynch, Zuocheng Wang, Li Ma, Eirini-Maria Paschalidou, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 167/14, 2020, Page(s) 141509, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/abc727

Effects of Chloride Ions on Passive Oxide Films Formed on Cr-Fe-Co-Ni(-Mo) Multi-Principal Element Alloy Surfaces

Author(s): Wang, Xueying; Mercier, Dimitri; Zanna, Sandrine; Seyeux, Antoine; Perriere, Loïc; Laurent-Brocq, Mathilde; Guillot, Ivan; Maurice, Vincent; Marcus, Philippe
Published in: Journal of the Electrochemical Society, Issue 170, 2023, Page(s) 041506, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/accb10

Passivation mechanisms and pre-oxidation effects on model surfaces of FeCrNi austenitic stainless steel

Author(s): Li Ma, Eirini-Maria Pascalidou, Frédéric Wiame, Sandrine Zanna, Vincent Maurice, Philippe Marcus
Published in: Corrosion Science, Issue 167, 2020, Page(s) 108483, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2020.108483

Thermal stability of the passive film formed on 316L stainless steel surface studied by ToF-SIMS

Author(s): Luntao Wang, Antoine Seyeux, Philippe Marcus
Published in: Corrosion Science, Issue 165, 2020, Page(s) 108395, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2019.108395

XPS study of the thermal stability of passivated NiCrFeCoMo multi‐principal element alloy surfaces

Author(s): Xueying Wang; Dimitri Mercier; Sandrine Zanna; Antoine Seyeux; Loïc Perriere; Mathilde Laurent‐Brocq; Ivan Guillot; Vincent Maurice; Philippe Marcus
Published in: Surface Interface Analysis, Issue 2, 2023, Page(s) 1-9, ISSN 1096-9918
Publisher: Wiley
DOI: 10.1002/sia.7193

Current developments of nanoscale insight into corrosion protection by passive oxide films

Author(s): Vincent Maurice, Philippe Marcus
Published in: Current Opinion in Solid State and Materials Science, Issue 22/4, 2018, Page(s) 156-167, ISSN 1359-0286
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.cossms.2018.05.004

Nanoscale Intergranular Corrosion and Relation with Grain Boundary Character as Studied In Situ on Copper

Author(s): Mohamed Bettayeb, Vincent Maurice, Lorena H. Klein, Linsey Lapeire, Kim Verbeken, Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 165/11, 2018, Page(s) C835-C841, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/2.1341811jes

New insight on early oxidation stages of austenitic stainless steel from in situ XPS analysis on single-crystalline Fe–18Cr–13Ni

Author(s): Li Ma, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Corrosion Science, Issue 140, 2018, Page(s) 205-216, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2018.06.001

Combined in situ microstructural study of the relationships between local grain boundary structure and passivation on microcrystalline copper

Author(s): Mohamed Bettayeb, Vincent Maurice, Lorena H. Klein, Linsey Lapeire, Kim Verbeken, Philippe Marcus
Published in: Electrochimica Acta, Issue 305, 2019, Page(s) 240-246, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2019.03.054

Passivation-Induced Physicochemical Alterations of the Native Surface Oxide Film on 316L Austenitic Stainless Steel

Author(s): Zuocheng Wang, Francesco Di-Franco, Antoine Seyeux, Sandrine Zanna, Vincent Maurice, Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 166/11, 2019, Page(s) C3376-C3388, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/2.0321911jes

Stainless steel surface structure and initial oxidation at nanometric and atomic scales

Author(s): Li Ma, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Applied Surface Science, Issue 494, 2019, Page(s) 8-12, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2019.07.166

Origin of nanoscale heterogeneity in the surface oxide film protecting stainless steel against corrosion

Author(s): Li Ma, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: npj Materials Degradation, Issue 3/1, 2019, Page(s) 29, ISSN 2397-2106
Publisher: Springer Nature
DOI: 10.1038/s41529-019-0091-4

Mechanisms of Cr and Mo Enrichments in the Passive Oxide Film on 316L Austenitic Stainless Steel

Author(s): Zuocheng Wang, Eirini-Maria Paschalidou, Antoine Seyeux, Sandrine Zanna, Vincent Maurice, Philippe Marcus
Published in: Frontiers in Materials, Issue 6, 2019, Page(s) Article 232, ISSN 2296-8016
Publisher: Frontiers
DOI: 10.3389/fmats.2019.00232

Chloride-induced alterations of the passive film on 316L stainless steel and blocking effect of pre-passivation

Author(s): Zuocheng Wang, Antoine Seyeux, Sandrine Zanna, Vincent Maurice, Philippe Marcus
Published in: Electrochimica Acta, Issue 329, 2020, Page(s) 135159, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2019.135159

2-Mercaptobenzimidazole films formed at ultra-low pressure on copper: adsorption, thermal stability and corrosion inhibition performance

Author(s): Xiaocui Wu, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Applied Surface Science, Issue 527, 2020, Page(s) 146814, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2020.146814

Can We Enhance Passivity with a Surface Finish? Spectroscopic and Electrochemical Analysis on 316L Stainless Steel

Author(s): Shova Neupane, Sandrine Zanna, Antoine Seyeux, Lorena H. Klein, Vincent Maurice, Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 169, 2022, Page(s) 011505, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ac4bf7

Chemical interaction, self-ordering and corrosion inhibition properties of 2-mercaptobenzothiazole monolayers: DFT atomistic modelling on metallic copper

Author(s): Fatah Chiter; Dominique Costa; Vincent Maurice; Philippe Marcus
Published in: Corrosion Science, Issue 209, 2022, Page(s) 110658, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2022.110658

Adsorption of 2-mercaptobenzimidazole Corrosion Inhibitor on Copper: DFT Study on Model Oxidized Interfaces

Author(s): Fatah Chiter; Dominique Costa; Vincent Maurice; Philippe Marcus
Published in: Journal of the Electrochemical Society, Issue 167, 2020, Page(s) 161506, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/abcd4f

Effects of water vapour on 2-mercaptobenzothiazole corrosion inhibitor films deposited on copper

Author(s): Xiaocui Wu, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Corrosion Science, Issue 189, 2021, Page(s) 109565, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2021.109565

Early-stage surface oxidation of the equiatomic CoCrFeMnNi high entropy alloy studied in situ by XPS

Author(s): Wang, Luntao; Zanna, Sandrine; Mercier, Dilitri; Maurice, Vincent; Marcus, Philippe
Published in: Corrosion Science, Issue 220, 2023, Page(s) 111310, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2023.111310

Nanoscale early oxidation mechanisms of model FeCrNi austenitic stainless steel surfaces at room temperature

Author(s): Li Ma, Benjamin Lynch, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Corrosion Science, Issue 190, 2021, Page(s) 109653, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2021.109653

Hydroxyl transport mechanisms upon passivation of Cr-Fe-Co-Ni-Mo multi-principal element alloy surfaces investigated by isotopic labelling

Author(s): X. Wang, D. Mercier, S. Zanna, A. Seyeux, L. Perriere, M. Laurent-Brocq, I. Guillot, V. Maurice, P. Marcus
Published in: Applied Surface Science, Issue 655, 2024, Page(s) 159558, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2024.159558

Ion transport mechanisms in the passive film formed on 304L stainless steel studied by ToF-SIMS with 18O isotopic tracer

Author(s): Luntao Wang, Svetlana Voyshnis, Antoine Seyeux, Philippe Marcus
Published in: Corrosion Science, Issue 173, 2020, Page(s) 108779, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2020.108779

Local Effects of Organic Inhibitor Molecules on Passivation of Grain Boundaries Studied In Situ on Copper

Author(s): Sagar B. Sharma; Vincent Maurice; Lorena H. Klein; Philippe Marcus
Published in: Journal of The Electrochemical Society, Issue 168, 2021, Page(s) 061501, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ac0308

Corrosion inhibition at emergent grain boundaries: atomic scale DFT study of 2-mercaptobenzothiazole on bi-crystalline copper

Author(s): Fatah Chiter, Dominique Costa, Vincent Maurice, Philippe Marcus
Published in: npj Materials Degradation, Issue 7, 2023, Page(s) 5, ISSN 2397-2106
Publisher: Nature Publishing Group
DOI: 10.1038/s41529-022-00314-5

Origin of enhanced passivity of Cr–Fe–Co–Ni–Mo multi-principal element alloy surfaces

Author(s): Wang, Xueying; Mercier, Dimitri; Zanna, Sandrine; Seyeux, Antoine; Perriere, Loïc; Laurent-Brocq, Mathilde; Guillot, Ivan; Maurice, Vincent; Marcus, Philippe
Published in: npj Materials Degradation, Issue 7, 2023, Page(s) 13, ISSN 2397-2106
Publisher: Nature Publishing Group
DOI: 10.1038/s41529-023-00330-z

Molecular scale insights into interaction mechanisms between organic inhibitor film and copper

Author(s): Xiaocui Wu, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: npj Materials Degradation, Issue 5/1, 2021, Page(s) 22, ISSN 2397-2106
Publisher: Nature Research
DOI: 10.1038/s41529-021-00168-3

In situ scanning tunneling microscopy study of 2-mercaptobenzimidazole local inhibition effects on copper corrosion at grain boundary surface terminations

Author(s): Sagar B. Sharma, Vincent Maurice, Lorena H. Klein, Philippe Marcus
Published in: Electrochimica Acta, Issue 378, 2021, Page(s) 138150, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2021.138150

2-Mercaptobenzothiazole corrosion inhibitor deposited at ultra-low pressure on model copper surfaces

Author(s): Xiaocui Wu, Frédéric Wiame, Vincent Maurice, Philippe Marcus
Published in: Corrosion Science, Issue 166, 2020, Page(s) 108464, ISSN 0010-938X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.corsci.2020.108464

Interfacial bonding and corrosion inhibition of 2-mercaptobenzimidazole organic films formed on copper surfaces under electrochemical control in acidic chloride solution

Author(s): V. Garg, S. Zanna, A. Seyeux, F. Wiame, V. Maurice, P. Marcus
Published in: Electrochimica Acta, Issue 484, 2024, Page(s) 144114, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2024.144114

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